Determination of sulfa antibiotic residues in river and particulate matter by field-amplified sample injection-capillary zone electrophoresis

In the present research, field-amplified sample injection–CZE (FASI–CZE) coupled with a diode array detector was established to determine trace level sulfa antibiotic. Sulfathiazole, sulfadiazine, sulfamethazine, sulfadimethoxine, sulfamethoxazole, and sulfisoxazole were selected as analytes for the experiments. The background electrolyte solution consisted of 70.0 mmol/L borax and 60.0 mmol/L boric acid (including 10% methanol, pH 9.1). The plug was 2.5 mmol/L borax, which was injected into the capillary at a pressure of 0.5 psi for 5 s. Then the sample was injected into the capillary at an injection voltage of –10 kV for 20 s. The electrophoretic separation was carried out under a voltage of +19 kV. The capillary temperature was maintained at 20˚C throughout the analysis, and six sulfonamides were completely separated within 35 min. Compared with pressure injection-CZE, the sensitivity of FASI-CZE was increased by 6.25–10.0 times, and the LODs were reduced from 0.2–0.5 to 0.02–0.05 μg/mL. The method was applied to the determination of sulfonamides in river water and particulate matter samples. The recoveries were 78.59–106.59%. The intraday and interday precisions were 2.89–7.35% and 2.77–7.09%, respectively. This provides a simpler and faster method for the analysis of sulfa antibiotic residues in environmental samples.     

钙钛矿型Sr_（1－x）Bi_xFeO_（3－y）系列物的结构、电性及铁氧化态研究

在１１００℃制备了钙钛矿型非计量系列物Ｓｒ_（１－ｘ）Ｂｉ_ｘＦｅＯ_（３－ｙ），与文献相比，明显具有温度低、时间短、能耗少的特点。用化学分析方法测得其化学式及Ｆｅ离子的平均价态，用ＸＲＤ、交流阻抗、ＩＲ、Ｍｏｓｓｂａｕｅｒ谱等方法研究了其结构与性质，该类化合物具有Ｐｍ３ｍ对称性和半导体性质，铁离子会产生电荷歧化现象。     

激光等离子体2660紫外探针及干涉系统

成功地在六路高功率Nd玻璃激光装置上建立了2660紫外激光探针和适合紫外波段的Normaski干涉仪,首次将可见波长的连续激光应用于紫外干涉仪中靶成像调整和光路准直。利用该紫外光干涉仪,在铜柱状靶(φ500μm)上测量了厚等离子体中高达0.6n。的电子密度。     

半导体带电粒子探测器的研制及其在空间物理中的应用

阐述了空间辐射环境监测的意义,描述了半导体带电粒子探测器的研制及由其组成的望远镜系统在空间物理中的应用,并给出了用此探测器在卫星上进行地球辐射环境监测、太阳质子事件和地磁暴探测的部分结果.     

毛细管电色谱中进样时间对柱效的影响

毛细管电色谱是近年发展起来的一种新型微分离技术，它结合了高效液相色谱和毛细管电泳的物点，具有高效、快速，高选择性，其有关理论研究和应用越来越深入，本文从色谱动力学角度讨论了毛细管电色谱中进样时间对柱的影响。     

Liquid phase oxidation of p-chlorotoluene to p-chlorobenzaldehyde over cobalt-doped mesoporous titania with a crystalline framework

Cobalt-doped mesoporous titania with a crystalline framework synthesized by surfactant templating method presented highly selective (99%) and reasonable conversion rate (49%) of catalytic oxidation of para-chlorotoluene to para-chlorobenzaldehyde in acetic acid using aqueous hydrogen peroxide as oxidant for the first time. Recycling of the catalyst indicates that the catalyst can be used a number of times without losing its activity to a greater extent. By contrast, cobalt-doped mesoporous titania without a crystalline structure and cobalt doped the commercial titania, Degussa P25 prepared by impregnation method with the similar concentration of cobalt were found inactive. The effects of catalyst concentration, reaction time, reaction temperature, and solvents on the performance of the catalyst were also investigated.     

高压沿面放电烟气脱硫技术动态实验研究

本文针对高压沿面放电活化气体的烟气脱硫技术,在静态实验研究的基础上进行了实验室冷态动态的实验研究。设计了便于反应和测量的动态实验装置。实验解释了电子束法脱硫技术中导致氨气泄漏的部分原因,验证了高压沿面放电脱硫技术可以在较低的运行电压下,达到提高脱硫效率,减少氨气泄漏的作用。     

Barrier Li Quantum Dots in Magnetic Fields

The methods for the few-body system are introduced to investigate the states of the barrier Li quantumdots (QDs) in an arbitrary strength of magnetic field. The configuration, which consists of a positive ion located on thez-axis at a distance d from the two-dimensional QD plane (the x-y plane) and three electrons in the dot plane boundby the positive ion, is called a barrier Li center. The system, which consists of three electrons in the dot plane bound bythe ion, is called a barrier Li QD. The dependence of energy of the state of the barrier Li QD on an external magneticfield B and the distance d is obtained. The angular momentum L of the ground states is found to jump not only withthe variation of B but also with d.     

超重核266Hs形成截面的入射道依赖

计算和比较了²⁶Mg+²⁴⁴Cm, ²⁷Al+²⁴³Am和³²S+²³⁸U3个反应系统的俘获截面和复合核²⁷⁰Hs形成截面. 在俘获截面计算中, 考虑了靶核形变效应. 穿越库仑势垒后, 反应系统由熔合谷进入不对称裂变谷. 只有越过不对称裂变谷中的条件鞍点的事件才进入复合核组态. 我们用考虑中子流动和径向运动的二参量Smoluchowski扩散方程来处理中间阶段的动力学过程. 此外, 还计算了经4n蒸发形成超重核²⁶⁶Hs的截面. 研究表明, 入射道的势垒分布, 中间阶段的条件鞍点高度对俘获截面, 复合核形成几率, 以及最终的超重核形成截面有显著影响.     

双电子原子系统内电子云的变化

本文主要通过对形状密度的分析,研究了双电子原子系统的内电子云如何随外电子的运动而变化,考虑了外电子远离内电子云和靠近内电子云的情况。探讨了氦原子具有不同K-量子数的¹S^e态的几何特征和内部运动特征,探讨了能量转移机制和径-径(radial-radial)关联的细节。发现内电子云作为一个整体的运动和外电子的运动之间有强烈的关联。