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排序方式: 共有966条查询结果,搜索用时 31 毫秒
1.
Molecular Diversity - The antifungals that are in current clinical practice have a high occurrence of a side effect and multidrug resistance (MDR). Researchers across the globe are trying to... 相似文献
2.
Composite optical thin-film materials have received a significant amount of interest in order to relieve the material constraints on refractive indices as well as reducing the number of layers required in optical coating design. Amongst others binary zirconia-silica composite thin films have attracted considerable attentions due to their several favorable opto-mechanical properties. In the present studies such a composite system under certain compositional mixings displayed both refractive index and band gap supremacy over pure zirconia films violating the most popular Moss rule. This unexpected evolution has several practical applications one of which can be directly employed in extending the range of tunability of the refractive index. Besides, the probing of such a novel evolution through the analysis of ellipsometric refractive index modeling and morphological correlation functions has revealed several novel as well as superior microstructural properties in the composite thin film systems. All these characterization and analysis techniques distinctly indicate a strong interrelation between the microstructural ordering and superior optical properties of the present zirconia-silica codeposited composites. 相似文献
3.
The occurrence of charge on recoil56Mn produced by the (n,γ) reaction in polycrystalline potassium permanganate has been examined using the ‘charge plate technique’.
From considerations of capture gamma ray decay schemes and internal conversion it appears that, in a condensed medium, the
recoil atom develops charge after losing much of its initial kinetic energy which allows collection on charged electrodes.
Preliminary findings were presented at the International Symposium on Radiochemistry and Radiation Chemistry, RC-41 BARC,
Bombay, Feb. 4–6 (1991). 相似文献
4.
The present paper deals with the study of a Durrmeyer-type integral modification of certain modified Baskakov operators. Here
we study simultaneous approximation properties for these operators by using the iterative combinations. We obtain an asymptotic
formula and an error estimation in terms of higher order modulus of continuity for these operators.
相似文献
5.
S. Sarkar A. D. Thakur C. V. Tomy G. Balakrishnan D. McK Paul S. Ramakrishnan A. K. Grover 《Pramana》2006,66(1):193-207
New experimental data are presented on the scan rate dependence of the magnetization hysteresis width ΔM(H) (∞ critical current densityJ
c(H)) in isothermalMH scans in a weakly pinned single crystal of Ca3Rh4Sn13, which displays second magnetization peak (SMP) anomaly as distinct from the peak effect (PE). We observe an interesting
modulation in the field dependence of a parameter which purports to measure the dynamical annealing of the disordered bundles
of vortices injected through the sample edges towards the destined equilibrium vortex state at a givenH. These data, in conjunction with the earlier observations made while studying the thermomagnetic history dependence inJ
c(H) in the tracing of the minor hysteresis loops, imply that the partially disordered state heals towards the more ordered state
between the peak field of the SMP anomaly and the onset field of the PE. The vortex phase diagram in the given crystal of
Ca3Rh4Sn13 has been updated in the context of the notion of the phase coexistence of the ordered and disordered regions between the
onset field of the SMP anomaly and the spinodal line located just prior to the irreversibility line. A multi-critical point
and a critical point in the (H,T) region of the Bragg glass phase have been marked in this phase diagram and the observed behavior is discussed in the light
of recent data on multi-critical point in the vortex phase diagram in a single crystal of Nb. 相似文献
6.
7.
Boruah A Rao IN Nandy JP Kumar SK Kunwar AC Iqbal J 《The Journal of organic chemistry》2003,68(12):5006-5008
A cis-proline derived cyclic mimic of a type VI beta-turn is synthesized via a ring-closing metathesis reaction. The solution NMR conformational study indicates that the major conformer of the cyclic peptide adopts a type VIa beta-turn in CDCl(3) and a type VIb beta-turn in DMSO-d(6). 相似文献
8.
Nandy JP Prabhakaran EN Kumar SK Kunwar AC Iqbal J 《The Journal of organic chemistry》2003,68(5):1679-1692
A novel chemo- and diastereoselective aerobic epoxidation of the N-cinnamoyl peptides catalyzed by polyaniline-supported cobalt(II) salen (PASCOS) is described. The N-cinnamoyl proline derived peptides 1 show a high pi-facial selectivity during these epoxidations. The origin of this diastereoselectivity in 1 has been attributed to (i) the propensity of the N-cinnamoyl proline amide to exist predominantly as trans rotamer in CDCl3, DMSO-d6, and CH3CN medium and (ii) existence of these peptides as organized structures (gamma- and beta-turns) due to the presence of intramolecular hydrogen bonds. An extensive solution NMR and MD simulation study on 1d and 1f indicates that the origin of the high pi-facial selectivity is due to the well-defined gamma- and beta-turns which result in the hindrance of one face of the cinnamoyl double bond in the transition state of the epoxidation reaction. 相似文献
9.
S. P. Mishra /Miss/ Jyoti Singh 《Journal of Radioanalytical and Nuclear Chemistry》1986,105(2):107-116
Fractional precipitation techniques have been utilized to separate the lower valent and parent forms of56Mn in permanganate targets and an attempt is made to study a few aspects of chemical stabilization of recoil56Mn in permanganates. Ammonium permanganate, recoil behaviour of which has not been studied previously, is chosen as one of the targets along with the potassium permanganate for initial retention and also for isothermal annealing.56Mn initial retentions of about 12% and about 4% are obtained for potassium and ammonium permanganate, respectively, by activation from a Ra–Be neutron source. A usual trend for KMnO4 and the reduction of recoil fragments by ammonium ions in NH4MnO4 are seen through the isothermal annealing study. 相似文献
10.
Rajeev K. Thakur C. Villette J.M. Aubry G. Delaplace 《Colloids and surfaces. A, Physicochemical and engineering aspects》2007,310(1-3):55-61
Formulation–composition map is an interesting tool to predict the nature of an emulsion, stability, viscosity and nevertheless to decide the mixing protocol of its ingredients. Information based on optimum formulation (environmental conditions at which the affinity of an emulsifier for oil and for aqueous phase is same), which is depicted through hydrophilic–lipophilic deviation (HLD) concept, is necessary to make a formulation–composition map of an emulsion. In order to apply this concept in food emulsions, it is necessary to determine characteristic constants of each component of the system, i.e. the aqueous phase, the oil phase and the emulsifier at equilibrium. In this work formulation–composition map of a sunflower oil–water–lecithin system, based on the knowledge of phase behavior of lecithin at equilibrium and emulsification, was made. The shape of inversion line on formulation–composition map was not the classical stair type rather an almost vertical inversion line at water-fraction (fw) near 0.20 was observed. It was supposed to be linked to the viscosity of oil phase which was 50 times the viscosity of aqueous phase. Additionally, emulsions were of oil-in-water (O/W) type for fw higher than 0.20, but their viscosity and the drop size behavior with respect to salt concentration as formulation variable did not show the existence of transitional inversion line on formulation–composition map. Such map in advance can certainly facilitate the guidelines for dynamic emulsification. 相似文献