全文获取类型
收费全文 | 553篇 |
免费 | 7篇 |
国内免费 | 3篇 |
专业分类
化学 | 397篇 |
晶体学 | 4篇 |
力学 | 12篇 |
数学 | 21篇 |
物理学 | 129篇 |
出版年
2023年 | 2篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2014年 | 6篇 |
2013年 | 19篇 |
2012年 | 30篇 |
2011年 | 27篇 |
2010年 | 18篇 |
2009年 | 16篇 |
2008年 | 25篇 |
2007年 | 30篇 |
2006年 | 53篇 |
2005年 | 38篇 |
2004年 | 30篇 |
2003年 | 35篇 |
2002年 | 27篇 |
2001年 | 12篇 |
2000年 | 18篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1997年 | 9篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 11篇 |
1984年 | 5篇 |
1983年 | 7篇 |
1982年 | 6篇 |
1980年 | 2篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1970年 | 2篇 |
1966年 | 3篇 |
1935年 | 2篇 |
排序方式: 共有563条查询结果,搜索用时 31 毫秒
1.
Hiroyuki Saimoto Tomoyuki Onitsuka Satoko Okabe Minoru Morimoto 《Tetrahedron letters》2004,45(48):8777-8780
Treatment of 1,3-dihydroxyacetone and acrolein with aqueous KOH gave a tetrahydrofuran derivative, 1,4-dihydroxy-3,7-dioxabicyclo[3.3.0]octane, in 80% yield. Similarly, 6-alkyl substituted 1,4-dihydroxy-3,7-dioxabicyclo[3.3.0]octanes were obtained by reaction of 1,3-dihydroxyacetone with various α,β-unsaturated aldehydes. In the cases of long chain alkenals, the reaction was effectively accelerated in the presence of organic co-solvent. On the other hand, the corresponding tricyclic products were synthesized by reaction of 1,3-dihydroxyacetone with cyclic enones, such as 2-cyclopentenone and 2-cyclohexenone. This method was successfully applied to the reaction of a tetrulose in the absence of any protecting groups. 相似文献
2.
3.
N. Hamamoto J. Jitsukawa C. Satoko 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,19(2):211-221
First-principle electronic structure calculations are carried out for MxC 60 q , where M = Li, Na, K and ( x , q ) = (1, 0),(1,±1),(2, 0),(3, - 1),(6, 0),(6, - 1),(12, 0) using the local density functional. The electric dipole moment for MC60 agrees with the experimental results. The calculated Mulliken charge indicates that the bonding of the alkali atom with C60 is mostly ionic except for lithium. The alkali atom prefers to make many bonds with the carbon atoms rather than a single bond with the neighbor carbon atom. The calculated adsorption energy suggest that the metal-metal bonding of sodiums and potassiums on C60 arises for more than the six valence electrons in the alkali atoms. The lithium-lithium bond is, on the other hand, not appeared for x ? 12. The difference in the most stable geometry between lithiums and the other alkali atoms on C60 comes from the covalent character of the lithium-carbon bond. 相似文献
4.
An InGaAs/InAlAs five-layer asymmetric coupled quantum well (FACQW) is expected to show very large electrorefractive index change. n in a wideband transparency region. Band structures of the FACQW are analyzed with Luttinger-Kohn Hamiltonian. The electrorefractive characteristics of the FACQW are discussed. 相似文献
5.
Arakawa R Shimomae Y Morikawa H Ohara K Okuno S 《Journal of mass spectrometry : JMS》2004,39(8):961-965
A low molecular mass polyester was analyzed by desorption/ionization on porous silicon (DIOS) mass spectrometry. The results were compared with those of matrix-assisted laser desorption ionization (MALDI) mass spectrometry using matrixes of alpha-cyano-4-hydroxycinnamic acid (CHCA) and 10,15,20-tetrakis(pentafluorophenyl)porphyrin (F20TPP). The CHCA matrix was not suitable for characterization of low molecular mass components of the polyester because the matrix-related ions interfered with the component ions. On the other hand, the F20TPP matrix showed no interference because no matrix-related ions appeared below m/z 822. However, the solvent selection for determining optimal conditions of sample preparation was limited, because F20TPP does not dissolve readily in any of the available organic solvents. In the DIOS spectra, the polymer ions were observed at high sensitivity without a contaminating ion. No matrix is needed for DIOS spectra of low molecular mass polyesters, facilitating sample preparation and selectivity of a precursor ion in post-source decay measurements. 相似文献
6.
7.
8.
9.
T Takamura T Kato E Arakawa S Ogawa Y Suzumura T Kato 《Chemical & pharmaceutical bulletin》1989,37(10):2828-2831
Several analogues substituted with fatty acid at the 2'-, 3'-, or 5'-position of the ribose moiety of N6,N6-dimethyladenosine were synthesized and tested for antitumor activity against cultured cells of L1210 leukemia and/or Ehrlich ascites. The cytotoxicity and increase of life span obtained with congeners in the N6,N6-dimethyladenosine 3'- or 5'-substituted series were comparable to in vitro or several times better in vivo than those of the mother compound. 相似文献
10.
Arakawa Y Ohnishi M Yoshimura N Yoshifuji S 《Chemical & pharmaceutical bulletin》2003,51(8):1015-1020
Synthesis of (1R,2S,5S,6R,8S)-3-azabicyclo[3.3.0]octane-2,6,8-tricarboxylic acid (2) from trans-4-hydroxy-L-proline (5) was attempted. A Diels-Alder reaction of 3,4-dehydroproline derivative 9 and cyclopentadiene afforded a single stereoisomer 11. The Diels-Alder adduct was smoothly converted to the hydrochloride of 2 (24) via RuO(4) oxidation. Although some racemization of the material or product was observed during the synthetic processes, the amino acid 24 proved to be optically pure. 相似文献