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1.
A pressure-assisted capillary chromatography-mass spectrometry method based on the use of a monolithic octadecylsilica (ODS) capillary is proposed for the determination of aliphatic amines. A 25 mM citric acid buffer containing 10% methanol is used as running electrolyte. Separation is achieved by simultaneously applying a capillary electrophoresis (CE) voltage of 13 kV and an overimposed pressure of 8 bar. The use of pressure is required to ensure stable electrospray conditions. Analysis times are reduced by using a capillary column consisting of a 30 cm long monolithic silica capillary column bound with ODS and a fused-silica capillary column also 30 cm long. The proposed method was successfully applied to the determination of low-molecular-weight aliphatic amines in tap and river water. The analysis of real samples requires cleanup and preconcentration, which can be performed automatically by inserting a minicolumn in the replenishment system of the commercial instrument. 相似文献
2.
Organo-silica sol-gel membranes have been prepared and demonstrated in a single layer format for pH measurement and multiple-layer format for both carbon dioxide and ammonia. The sensors are simple and versatile since the same chemistry and membranes are used for each sensor. The sensors use hydroxypyrenetrisulfonic acid (HPTS) as the indicator immobilized in a base-catalyzed sol-gel containing poly(dimethyl)siloxane, aminopropyltriethoxysilane (APTES) and tetraethylorthosilicate (TEOS). This indicator gel is over coated with a hydrophobic sol-gel to reduce cross reactivity to pH when either CO(2) or NH(3) are examined. The gels are very stable and the sensors retain response up to a 12-month period. Sensors can be stored in buffer or dry without loss of function and have response times to that are comparable to literature values. 相似文献
3.
Orte A Bermejo R Talavera EM Crovetto L Alvarez-Pez JM 《The journal of physical chemistry. A》2005,109(12):2840-2846
The presence of excited-state buffer-mediated proton exchange reactions influences the steady-state fluorescence signals from dyes in solution. Since biomolecules in general have some chemical groups that can act as proton acceptors/donors and are usually dissolved in buffer solutions which can also behave as appropriate proton acceptors/donors, the excited-state proton exchange reactions may result in distorted steady-state fluorescence signals. In a previous paper (J. Phys. Chem. A 2005, 109, 734-747), we evaluated kinetic and other pertinent parameters for the excited-state proton reactions of the prototropic forms of 2',7'-difluorofluorescein (Oregon Green 488, OG488), recording a fluorescence decay surface at different pH values and acetate buffer concentrations, analyzed by means of global compartmental analysis. In this article we use the rate constants and the corrected pre-exponential factors from the previously recorded fluorescence decay traces to simulate the decay times and associated pre-exponentials at different acetate buffer concentrations and constant pH and compare these theoretically calculated values with new experimental data. We also calculate the steady-state fluorescence intensity vs pH and vs acetate buffer concentration (at constant pH) and compare these calculated emission values with the experimental data previously published. The agreement between the experimental and simulated data is excellent. 相似文献
4.
María F. Beer Guillermo F. Reta Adrin Puerta Augusto E. Bivona Andrs Snchez Alberti Natacha Cerny Emilio L. Malchiodi Carlos E. Tonn Jos M. Padrn Valeria P. Sülsen Osvaldo J. Donadel 《Molecules (Basel, Switzerland)》2022,27(10)
Cancer is one of the most important causes of death worldwide. Solid tumors represent the vast majority of cancers (>90%), and the chemotherapeutic agents used for their treatment are still characterized by variable efficacy and toxicity. Sesquiterpenes are a group of natural compounds that have shown a wide range of biological activities, including cytotoxic and antiparasitic activity, among others. The antiproliferative activity of natural sesquiterpenes, tessaric acid, ilicic acid, and ilicic alcohol and their semisynthetic derivatives against HeLa, T-47D, WiDr, A549, HBL-100, and SW1573 cell lines were evaluated. The effect of the compounds on Trypanosoma cruzi epimastigotes was also assessed. The selectivity index was calculated using murine splenocytes. Derivatives 13 and 15 were the most antiproliferative compounds, with GI50 values ranging between 5.3 (±0.32) and 14 (±0.90) μM, in all cell lines tested. The presence of 1,2,3-triazole groups in derivatives 15–19 led to improvements in activity compared to those corresponding to the starting natural product (3), with GI50 values ranging between 12 (±1.5) and 17 (±1.1) μM and 16 being the most active compound. In relation to the anti-T. cruzi activity, derivatives 7 and 16 obtained from tessaric acid and ilicic acid were among the most active and selective compounds with IC50 values of 9.3 and 8.8 µM (SI = 8.0 and 9.4), respectively. 相似文献
5.
6.
Angel Bustamante Enrico Mattievich Helio S. de Amorim Ivo Vencato Máximo M. Silveira 《Hyperfine Interactions》2005,166(1-4):599-603
The crystal structure of synthetic ferrous hureaulite, Fe5 2+ (H2O)4(PO4H)2(PO4)2, was refined from single-crystal X-ray data. It is monoclinic, space group C2/c, with a=17.487(4), b=9.017(2), c=9.338(2) Å, β=96.27(3)°, V=1463.6(6) Å3, Z=4 and D calc=3.327 g/cm3. This end member of the hureaulite series was crystallized under distinctly acidic conditions, by a method that gives perfect crystals, large enough for X-ray single crystal studies. The main feature of the hureaulite structure is that it has an equal number of normal (PO4)3+ and acid (PO4H)2+ tetradentate groups. These are centered on Fe2+ atoms and share corners with edge-linked octahedra, forming pentamer units. The five Fe2+ atoms are distributed on three distinct sites in these units. This can be directly observed in the Mössbauer spectrum at 295 K, which contains three doublets whose relative intensities correspond to the 1:2:2 distributions of crystallographic sites. 相似文献
7.
Paul Gundel Gema Martinez‐Criado Martin C. Schubert Juan Angel Sans Wolfram Kwapil Wilhelm Warta Eicke R. Weber 《固体物理学:研究快报》2009,3(9):275-277
Synchrotron based X‐ray excited optical luminescence (XEOL) has been measured with many direct bandgap semiconductors. We present XEOL measurements on crystalline silicon (Si), obtained despite of its indirect bandgap and the consequently low luminescence efficiency. Spectra of monocrystalline and multicrystalline (mc) Si at room temperature are compared to theoretical spectra. A possible application in the synchrotron‐based research on mc‐Si is exemplified by combining XEOL, X‐ray fluorescence (XRF) spectroscopy, photoluminescence (PL) spectroscopy, and microscope images of grain boundaries. This approach can be utilized to investigate the recombination activity of metal precipitates, to analyze areas of different lifetimes on mc‐Si samples and to correlate additional material parameters to XRF measurements. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
8.
Nanograin sizes and crystal lattice microstrains in nanocrystalline materials are typically evaluated from the broadening of their x-ray diffraction (XRD) peaks under the assumption of symmetrical diffraction profiles. Since this assumption is not entirely satisfactory, we formulate a line-broadening analysis model of a single peak that considers explicitly the XRD peak asymmetry. The model is a generalization of the variance method in which the shape of the XRD peaks is idealized through asymmetrical split pseudo-Voigt functions. The model is validated on two nanocrystalline powders. 相似文献
9.
Avila-Brande D Urones-Garrote E Katcho NA Lomba E Gómez-Herrero A Landa-Cánovas AR Carlos Otero-Díaz L 《Micron (Oxford, England : 1993)》2007,38(4):335-345
In this work we report some new well-defined carbon nanostructures produced by direct chlorination of metallocenes (ferrocene and cobaltocene) and NbC, at temperatures from 100 to 900 degrees C. Thus, amorphous carbon nanotubes with variable dimensions depending on reaction temperature were produced from ferrocene. When cobaltocene is the carbon precursor the main product are solid amorphous nanospheres. The high refractory metal carbide NbC as carbon source favours the growth of nanospherical cabbage-like particles with a higher degree of graphene sheets order. Besides, NbC crystallites encapsulated in an amorphous carbon shell were also found at lower temperatures (T< or =700 degrees C). 相似文献
10.
A discrete-time version of the replicator equation for two-strategy games is studied. The stationary properties differ from those of continuous time for sufficiently large values of the parameters, where periodic and chaotic behavior replace the usual fixed-point population solutions. We observe the familiar period-doubling and chaotic-band-splitting attractor cascades of unimodal maps but in some cases more elaborate variations appear due to bimodality. Also unphysical stationary solutions can have unusual physical implications, such as the uncertainty of the final population caused by sensitivity to initial conditions and fractality of attractor preimage manifolds. 相似文献