Electrodialysis of Hydrosols of Ultradispersed Diamonds

The electrical conductivity of hydrosols of ultradispersed diamonds was studied. The electromembrane method for cleaning and concentrating of ultradispersed diamonds in hydrosols was considered. The influence exerted by the concentration of the dispersed phase on the electrical characteristics of the cleaning process was analyzed. A mathematical relation making it possible to evaluate the output characteristics of the process and to determine the geometrical characteristics of the apparatus was proposed.     

Characteristics of high-power radiating imploding discharge with cold start

A qualitative model of the dynamics of a multiterawatt radiating Z-pinch with cold start and high rate of current rise is proposed. The model is used to analyze discharges with currents I ～ 2–5 MA (with dI/dt > 10¹³ A/s) through uniform or structured plasma-producing loads, including wire arrays. The most important consequence of cold start is that spatially nonuniform plasma production is prolonged to almost the entire current rise time. Under these conditions, the Ampére force begins to play a dominant role in the plasma dynamics before the plasma-producing load is completely transformed into an accelerated plasma. The results of computations of wire-array vaporization are presented. A formula is proposed for estimating the highest attainable velocity of plasma flow into a heterogeneous liner driven by the Ampére force. It is shown that local imbalance between radial motion of the produced plasma and supply of the plasma-producing substance to be ionized leads to axially nonuniform breakthrough of magnetic flux into the liner, which precedes plasma collapse. The magnetic-flux breakthrough gives rise to a chaotic azimuthal-axial plasma structure consisting of radial plasma jets of relatively small diameter, which is called a radial plasma rainstorm. The breaking-through azimuthal magnetic flux obstructs further current flow in the breakthrough region. Analyses of Z-pinch implosion based on the theory of Rayleigh-Taylor instability or the snowplow model are incorrect under the plasma-rainstorm conditions. The processes taking place in a stagnant Z-pinch include conversion of the energy carried by the current-generated magnetic field into turbulent MHD flow of the ion component of the plasma, its convective mixing with magnetic field, heating, energy transfer from ions to electrons, and emission from the plasma. Under typical experimental conditions, emission plays a key role in the energy balance in an imploding pinch. Z-pinch is modeled by an electric-circuit component that has a time-dependent nonlinear impedance and consumes the magnetic energy supplied by a generator through a magnetically insulated transmission line (MITL). The peak power reached in the circuit is comparable to the peak soft X-ray power output emitted by the pinch in terms of magnitude and timing. Optimum matching conditions are formulated for the generator-MITL-pinch circuit.     

New Interfaces for Coupling TLC with TOF SIMS

JPC – Journal of Planar Chromatography – Modern TLC - Two interfaces have been tested for coupling thin-layer chromatography (TLC) with time-of-flight secondary-ion mass spectrometry...     

Modelling locational price spreads in competitive electricity markets; applications for transmission rights valuation and replication

The restructuring of the electric utilities industry has forcedindustry participants to rethink their approach to a numberof decision processes. To manage risk and plan investment ingeneration assets, as well as to examine the efficient expansionof the current transmission grid, one needs to have a clearunderstanding of the interaction between the grid propertiesand the behaviour of the regional power markets. In this paperwe discuss a fundamental modelling approach which extracts thestochastic properties of electricity prices by modelling theimpact of physical and economic drivers affecting the production,delivery, and consumption of electricity. If the fundamentalinputs are directly observable, we can use historical data tocalibrate the model parameters. In the case of electricity,this simple and abundant set of training data can make a crucialdifference. We present the bid-based stochastic model (BSM) and look intoits application to valuing of financial derivatives, especiallyoptions based on the locational spread in electricity pricebetween two markets. The advantage of the bid-based model isthat one is able to link the capacity of the transmission line,in megawatts, directly to the correlation between electricityprices at the end nodes. This leads us to a valuation methodfor a locational spread option, the financial equivalent ofa physical transmission right. The model represents an improvementover standard spread option formulation in that it accountsfor the effect of the nonlinear flows in the transmission networkon the correlation and distribution of locational prices. Wealso address the question of whether financial transmissionrights can be replicated with a dynamic portfolio of forwardcontracts at the end nodes. This poses the possibility of model-based arbitrage betweenexisting forward markets and the emerging transmission rightsmarkets. Furthermore, it allows users to simulate the effectof transmission outages or expansion. For example, a for-profittransmission provider who is contemplating addition of a newtransmission line between two markets needs to know whetherhe will be able to recover the fixed cost of investing in theline by selling transmission rights to market participants.By calibrating the bid-based model according to current pricelevels and adding the capacity of the new transmission line,the transmission owner can simulate future cash flows and estimatethe profitability of the investment.     

Photosynthesis and Properties of Halomethyl Derivatives of Azinobenzimidazoles

Photocyclization of 2-(pentafluoroanilino)-, 2-(4-chloro-2-iodoanilino)-, 2-(2-chloro-4-iodo-anilino)-4,6-dimethylpyrimidines, as well as 2-(2-chloro-3-methylanilino)pyridine was used to prepare con-densed azinobenzimidazoles, including previously unknown 8-chloro-1,3-dimethylpyrimido[1,2-a]benzimidazole and 9-methylpyrido[1,2-a]benzimidazole. With isomeric chloroiodoanilinopyrimidines as example it was shown that the iodine atom affects photocyclization direction. Quaternization of 6,7,8,9-tetrafluoro-1,3-dimethylpyrimido[1,2-a]benzimidazole, 8-chloro-1,3-dimethylpyrimido[1,2-a]benzimidazole, and 9-methylpyrido[1,2-a]benzimidazole with alkylating agents and C-H activity of alkyl groups in the quaternary salts in reactions with orthoformic ester were studied.     

Standardization and certification in the area of environmentally degradable plastics

Environmentally degradable polymers and plastics (EDPs) are a group of polymeric materials experiencing a rapid growth in number as well as in their applications and quantities used. The assessment of their key characteristic - degradability, including eventually biodegradability as the ultimate stage, is scientifically and technically a challenging issue and has led to differing interpretations in the past. In order to standardize techniques and criteria a number of standards were established by different standardization bodies which are also used as a basis for certification schemes. An up-to-date inventory of the rapidly growing standardization body is presented with basic interpretation to help guide the non-expert. A basic introduction to EDPs and polymer degradation is added for clarity.