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1.
Growth of thin Ti films on (100)W and the kinetics of their oxidation are studied using thermal-desorption spectroscopy and Auger electron spectroscopy. Titanium films grow nearly layer by layer on the (100)W face at room temperature. The activation energy for desorption of Ti atoms decreases from 5.2 eV for coverage θ=0.1 to 4.9 eV in a multilayer film. Oxidation of a thin (θ=6) titanium film starts with dissolution of oxygen atoms in its bulk to the limiting concentration for a given temperature, after which the film oxidizes to TiO, with the TiO2 oxide starting to grow when exposure of the film to oxygen is prolonged. The thermal desorption of oxides follows zero-order kinetics and is characterized by desorption activation energies of 5.1 (TiO) and 5.9 eV (TiO2). 相似文献
2.
The yield and energy distributions of potassium and cesium atoms emitted in electron-stimulated desorption (ESD) from a molybdenum
surface, oxidized to different extent and maintained at 300 K, have been measured by the time-of-flight technique with a surface
ionization detector. The ESD threshold for potassium and cesium atoms lies around 25 eV, irrespective of molybdenum oxidation
state. In the case of molybdenum coated by an oxygen monolayer, secondary thresholds at ∼40 and ∼70 eV have been observed,
as well as atomic energy distribution tailing down to very low energies. The most probable kinetic energies of the atoms are
a few tenths of one eV. The results are explained within a model involving Auger neutralization of the adsorbed alkali metal
ions after the filling of the 2s O, 4s Mo, and 4p Mo core holes. The possibility of ESD of a neutral species as a result of oxide-cation core-level ionization has been demonstrated
for the first time.
Fiz. Tverd. Tela (St. Petersburg) 39, 758–761 (April 1997) 相似文献
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V. A. Vinokurov Yu. N. Polivin M. A. Silin E. A. Ageev M. A. Zatikyan R. A. Karakhanov 《Russian Chemical Bulletin》1989,38(9):1984-1984
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2154–2155, September, 1989. 相似文献
5.
A. N. Ageev A. A. Aratskova L. D. Belyakova T. N. Gvozdovich A. V. Kiselev Ya. I. Yashin J. Kàlal F. Švec 《Chromatographia》1983,17(10):545-548
Summary The retention of benzene derivatives with nonpolar and polar substituents on a porous methacrylate copolymer containing epoxy groups using both nonpolar and polar eluents was investigated. When n-hexane is used as the eluent, the retention of n-alkylbenzenes and polymethylbenzenes is weaker than that of benzene. In the case of benzene derivatives containing polar functional groups their capacity ratios (k) on this porous polymer increases approximately linearly with the increase of the adsorbate molecules dipole moment. The retention characteristics of the methacrylate copolymer were compared with that of a styrene-divinylbenzene copolymer and silica gels with a hydroxylated surface and with a surface modified by chemically bonded alkylsilyl groups. 相似文献
6.
Yu. N. Polivin R. A. Karakhanov T. S. Sheveleva E. A. Ageev A. S. Remizov 《Russian Chemical Bulletin》1991,40(12):2518-2520
The reaction of 2-ethyl-3-tetrahydrofuryl thiocyanate (I) and triphenylacetonitrile (VIII) with methylmagnesium iodide in ether was studied using GC/MS, PMR and13C NMR spectroscopy. The reaction of (I) with CH3MgI gives the product of the homolysis of the C-S bond, namely, bis(2-ethyl-3-tetrahydrofuryl) disulfide (II), in 81% yield. This reaction is assumed to be general in nature since triphenylacetonitrile (VIII) is also homolytically cleaved by the action of CH3MgI to give triphenylmethane.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2886–2888, December, 1991. 相似文献
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Patterns of small-angle scattering that appear in thin AgCl films containing granular silver upon the formation of spontaneous periodic structures by p-polarized and circularly polarized laser beams (He-Ne laser, P=8 mW, λ = 632.8 nm) are studied. It is found that, at angles of incidence exceeding 4° regardless of the type of polarization, the diffraction of the waveguide modes excited by the dominant C gratings from neighboring microgratings with the vectors K ≠ K c dominantly contributes to the small-angle scattering. In the case of circularly polarized light, the pattern of small-angle scattering becomes more complicated as a result of the formation of S ? gratings and related secondary regular gratings. 相似文献
10.
O. M. Nemtsova A. L. Ageev E. V. Voronina 《Bulletin of the Russian Academy of Sciences: Physics》2007,71(9):1296-1298
To obtain reliable information about the structural properties of samples studied by Mössbauer spectroscopy, a technique for estimating the error in the hyperfine parameter distribution in the uniform metric is proposed. The distribution error contains the error caused by the statistical spread of experimental data and the error of the method for solving the ill-posed inverse problem. A criterion of choice of the regularization parameter is proposed. 相似文献