全文获取类型
收费全文 | 578篇 |
免费 | 21篇 |
国内免费 | 2篇 |
专业分类
化学 | 360篇 |
力学 | 20篇 |
数学 | 36篇 |
物理学 | 185篇 |
出版年
2023年 | 12篇 |
2022年 | 10篇 |
2021年 | 13篇 |
2020年 | 15篇 |
2019年 | 30篇 |
2018年 | 12篇 |
2017年 | 18篇 |
2016年 | 27篇 |
2015年 | 14篇 |
2014年 | 25篇 |
2013年 | 38篇 |
2012年 | 50篇 |
2011年 | 52篇 |
2010年 | 30篇 |
2009年 | 29篇 |
2008年 | 24篇 |
2007年 | 40篇 |
2006年 | 33篇 |
2005年 | 35篇 |
2004年 | 19篇 |
2003年 | 14篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有601条查询结果,搜索用时 15 毫秒
1.
Arabinda Mallick 《Journal of luminescence》2006,118(2):165-172
Solvatochromic effects on the fluorescence behavior of 7-hydroxy-4-methyl-8-(4′-methyl-piperazine-1′ yl)methylcoumarin (HMMC) was studied in different solvents. The fluorescence of HMMC was found to be highly sensitive to both the polarity and the protic character of the solvent. Exploiting the polarity-sensitive fluorescence property of HMMC, its excited-state dipole moment has been determined. Fluorescence (Förster) resonance energy transfer (FRET) process from HMMC to a potent bioactive molecule 3-acetyl-4-oxo-6,7-dihydro-12 H indolo-[2,3-a] quinolizine (AODIQ) was studied. From the determined KSV and R0 values, it is argued that a long-range dipole-dipole interaction is operating for the energy transfer mechanism. The energy transfer efficiency (E) and the distance between the acceptor and the donor (r0) have been determined. 相似文献
2.
Raj Gandhi Kamales Kar S. Uma Sankar Abhijit Bandyopadhyay Rahul Basu Pijushpani Bhattacharjee Biswajoy Brahmachari Debrupa Chakraborti M. Chaudhury J. Chaudhury Sandhya Choubey E. J. Chun Atri Desmukhya Anindya Datta Gautam Dutta Sukanta Dutta Anjan Giri Sourendu Gupta Srubabati Goswami Namit Mahajan H. S. Mani A. Mukherjee Biswarup Mukhopadhyaya S. N. Nayak M. Randhawa Subhendu Rakshit Asim K. Ray Amitava Raychaudhuri D. P. Roy Probir Roy Suryadeep Roy Shiv Sethi G. Sigl Arunansu Sil N. Nimai Singh Mark Vagins Urjit Yagnik 《Pramana》2003,60(2):405-409
This is the report of neutrino and astroparticle physics working group at WHEPP-7. Discussions and work on CP violation in
long baseline neutrino experiments, ultra high energy neutrinos, supernova neutrinos and water Cerenkov detectors are discussed. 相似文献
3.
Majumdar A Behnke JF Hippler R Matyash K Schneider R 《The journal of physical chemistry. A》2005,109(41):9371-9377
Chemical reactions in a dielectric barrier discharge at medium pressure of 250-300 mbar have been studied in CH(4)/Ar and CH(4)/N(2) gas mixtures by means of mass spectrometry. The main reaction scheme is production of H(2) by fragmentation of CH(4), but also production of higher order hydrocarbon molecules such as C(n)H(m) with n up to 9 including formation of different functional CN groups is observed. Formation of C(2)H(2), C(2)H(4), and C(2)H(6) molecules has been investigated in some detail. Significant differences are noted in comparison to a theoretical estimate. 相似文献
4.
Michael A. Luzuriaga Candace E. Benjamin Michael W. Gaertner Hamilton Lee Fabian C. Herbert Snipta Mallick 《Supramolecular chemistry》2019,31(8):485-490
ABSTRACTDrug delivery using metal-organic frameworks (MOF) has elicited interest in their biocompatibility; however, few studies have been conducted on their stability in common buffers, cell media, and blood proteins. In particular, the use of ZIF-8, a MOF interconnected by Zn and methylimidazole, has been frequently employed. In this study, we tested single crystals of ZIF-8 with common laboratory buffers, cell media, and serum, and noted several issues. Buffers containing phosphate and bicarbonate alter the appearance and composition of ZIF-8; however, these buffers do not appear to cause cargo to leak out even when the ZIF-8 itself is displaced by phosphates. On the other hand, serum dissolves ZIF-8, causing premature cargo release. Our results show that ZIF-8 undergoes surface chemistry changes that may affect the interpretation of cellular uptake and cargo release data. On the other hand, it provides a rational explanation as to how ZIF-8 neatly dissolves in vivo. 相似文献
5.
We look at some one-dimensional semi-infinite superlattices with an underlying Hamiltonian that is of the nearest neighbour, tight binding type. A real space rescaling procedure which is exact in one dimension is applied to obtain the location of the subbands. It has been found that these subbands never overlap in 1D, and we interpret this as a band repulsion effect. Relevance in the case of a disordered system where this band repulsion crosses over to the well-known level repulsion is discussed. Then with a proper matching at the boundary we solve for the sets of denumerably infinite number of decaying solutions (the surface states) in the gaps. These types of states have been proposed quite some time ago. We look at detail theirexact analytical solutions in 1D and find that their decay lengths near the band edges diverge as |E–E
b|–v, wherev=1/2 andE
b is the nearest band edge. The decay lengths and their divergence exponent match extremely well with those obtained from transfer matrix method. Some recent experiments on quantum well structures seem to have observed such states. 相似文献
6.
Periodic first principle calculation correlates the role of metal substitution (Sr and Ba in place of Ca) on selective encaging of active O− radicals inside the microporous 12MO, 7Al2O3 crystal structure. We have exchanged Ca by Sr and Ba and as well extracted electron stepwise to monitor selectivity of different anion encaging inside the same structure type. Ca favors O2− encaging and shows no electron transition when neutral, whereas Sr shows no transition in absence of unpaired electron and can successfully trap O−, Ba though less active than the other metal substituents shows oxygen encaging at its zero and mono-positive state. 相似文献
7.
A general route for the synthesis of highly substituted aryl cyclopentanes has been developed involving Diels-Alder reaction of asymmetric dienes prepared from (+)-camphoric acid followed by aromatization of the resulting cyclohexene derivatives. Employing this protocol enantiospecific synthesis of (+)-herbertene and (+)-cuparene has been accomplished. 相似文献
8.
Anuradha Rout Swoyam P. Rout Nigamananda Mallick Baishnab C. Singh M. Santappa 《Journal of polymer science. Part A, Polymer chemistry》1978,16(2):391-397
The polymerization of acrylonitrile (M) initiated by the Ce(IV)–acetophenone (AP) redox pair has been studied in acetic–sulfuric acid mixtures in a nitrogen atmosphere. The rate of polymerization is proportional to [M]3/2, [AP]1/2 and [Ce(IV)]1/2. The rate of disappearance of ceric ion,–RCe, is proportional to [AP], [M], and [Ce(IV)]. The effect of certain salts, solvent, acid and temperature on both the rates have been investigated. A suitable kinetic scheme has been proposed, and the composite rate constants kp 2(k/k/t) and k0/ki are reported. 相似文献
9.
Mallick A Haldar B Maiti S Chattopadhyay N 《Journal of colloid and interface science》2004,278(1):215-223
Photophysical properties of 3-acetyl-4-oxo-6,7-dihydro-12H indolo-[2,3-a] quinolizine (AODIQ) have been studied in different aqueous micellar environments using steady-state and time-resolved emission spectroscopy. The charge transfer (CT) fluorescence exhibits appreciable hypsochromic shift, along with an enhancement in the fluorescence intensity in all the micellar media. This is associated with an increase in the fluorescence anisotropy (r), which suggests that the fluorophore molecule experiences motionally restricted environments upon binding with the micelles. Fluorescence spectral position and fluorescence quenching studies suggest that the fluorescing moiety does not penetrate into the core of the micellar units; rather it binds at the micelle-water interfacial region. The binding constant and free energy change during probe-micelle binding have been evaluated from relevant fluorescence data. Light has been thrown on the mode of action of urea on micelle bound probes. The results are interpreted in terms of the model that urea displaces water molecules from the micellar interface and the consequent destabilization leads to the expulsion of the probe molecules from the interfacial region. Polarity and viscosity of the microenvironments around the probe have been determined in the micellar systems. 相似文献
10.