Synthesis of cationic molybdenum and cobalt diene complexes from neutral allyl compounds by ligand exchange in a strong protic acid

Conclusions The allyl ligand in neutral molybdenum and cobalt complexes is readily exchanged by dienes in the presence of a strong protic acid with the formation of cationic complexes. This exchange is facilitated by an increase in the basicity of the starting compounds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1655–1657, July, 1987.     

Growth of NaBi（WO4）2 Dendrite and Mechanism

The solid-liquid interface motion of NaBi（WO4）2 （NBWO） melt crystal growth is observed in an in situ system, in which the whole processes of interface transition from fiat interface and cellular to dendrite are visualized. The spacing of the dendrite under smaller temperature gradient turns out to be larger than that under larger temperature gradient, which is found to be sensitive to the temperature distribution. The mechanism of dendrite growth of NBWO is studied based on the model of the growth units of anion coordination polyhedra. The { 001} face has two apex links, so it shows higher stability and has high growth rate and forms the arm of dendrite, whereas the {010} face has only one apex link, and thus shows relative slower growth rate and firstly forms the branches.     

Multilayer optics for XUV spectral region: technology fabrication and applications

We present research investigations in the field of multilayer optics in X-ray and extreme ultra-violet ranges (XUV), aimed at the development of optical elements for applications in experiments in physics and in scientific instrumentation. We discuss normal incidence multilayer optics in the spectral region of “water window”, multilayer optics for collimation and focusing of hard X-ray, multilayer dispersing elements for X-ray spectroscopy of high-temperature plasma, multilayer dispersing elements for analysis of low Z-elements. Our research pays special attention to optimization of multilayer optics for projection EUV-lithography (ψ-13nm) and short period multilayer optics.     

Optical third-harmonic generation in coupled microcavities based on porous silicon

The resonance features of the third-harmonic generation have been observed in 1D coupled microcavities consisting of three Bragg reflectors and two identical half-wave layers of mesoporous silicon. The third-harmonic intensity increases by a factor of about 10³ in the resonance of fundamental radiation with each of the modes of coupled microcavities. It has been shown that the resonance positions in the angular spectra of the third-harmonic intensity depend on the coupling between microcavities that is determined by the transmission of the intermediate Bragg reflector. In the framework of the transfer-matrix method with nonlinear sources, it has been shown that the basic mechanism of the enhancement of the third-harmonic generation in coupled microcavities based on porous silicon is the constructive interference of the partial third-harmonic waves that are generated by near-surface layers.     

Possibility of observing chiral-symmetry effects in ferromagnetic nanoparticles

The statistics of left-and right-handed vortical magnetization states in a system of submicron-sized ferromagnetic disks is studied experimentally. Lattices of elliptic cobalt particles with a planar size of 750 × 450 nm and a thickness of 25 nm were formed using high-resolution electronic lithography. To visualize the magnetization distributions in the disks, magnetic force microscopy was used. The experimental results indicate the conservation of magnetic chiral symmetry in cobalt ferromagnetic particles of the above size and shape.     

Properties of Josephson junctions in the inhomogeneous magnetic field of a system of ferromagnetic particles

The effect of an array of ferromagnetic nanoparticles on the field-dependent critical current of the short overlap Josephson junction is experimentally studied. Large reversible variations of the maximum critical current are observed depending on the magnetic state of the particles. The pronounced commensurability effects are detected which are proved by the additional peaks of magnetic field induced diffraction pattern.     

Statistical characteristics of an intense wave behind a two-dimensional phase screen

An analysis of the parameters of nonlinear waves transmitted through a layer of a randomly inhomogeneous medium is carried out. The layer is modeled by a two-dimensional phase screen. Passing through the screen plane, the wave acquires a random phase shift. The wave front becomes distorted, and randomly located regions of ray convergence and divergence are formed, in which the nonlinear evolution of the wave alters profoundly. The problem is solved in the approximation of geometrical acoustics. The ray pattern of a plane wave transmitted through the regular screen is constructed. The solution that describes the spatial structure of the field and the evolution of an arbitrary temporal wave profile behind the screen is obtained. Statistical characteristics of the discontinuity amplitude are calculated for different distances from the screen. A random modulation is shown to result in a faster (in comparison with the case of a homogeneous medium) nonlinear attenuation of the wave and in the smoothing of the shock profile. The distribution function of the wave field parameters becomes broader because of random focusing effects.     

Photostimulated phenomena in relaxors

The action of illumination on the conducting and dielectric properties of lead magnoniobate was investigated. The photostimulated currents were examined and the spectral dependence of photoconductivity in the region of diffuse phase transition was obtained. It was found that the illumination affects the dielectric properties and that its action is memorized at temperatures below room temperature. The role of defect states in the formation of relaxor properties is discussed on the basis of the obtained data.