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1.
The high-temperature cubic phase of non-stoichiometric strontium ferrite SrFeOx (2.5≤x≤3.0) has been studied by in situ neutron powder diffraction in air over the temperature range 300-1273 K. The composition of SrFeOx changes within the range 2.56≤x≤2.81 from 1273 to 673 K, respectively.Rietveld refinements of the diffraction patterns show that the high-temperature cubic phase of SrFeOx is consistent with a face-centred Fm3c structure. This structure leads to agreement with previous density measurements. This cell allows the high-temperature structure of SrFeOx to be described in terms of a solid solution of the composition end members. Cubic SrFeOx at high temperature is found to closely obey Vegard's law. The density of cubic SrFeOx is also found to exhibit a linear relationship with composition. 相似文献
2.
The contacts of single carbon nanotubes and bundles of carbon nanotubes with superconducting and metallic electrodes are investigated in order to create bolometers and electron coolers. Tunneling contacts of the carbon nanotubes with aluminum electrodes are obtained. The current-voltage characteristics of junctions are analyzed for temperatures from room temperature to 300 mK. The resistance of individual nanotubes is primarily determined by defects and is too large for applications. The use of the bundles of carbon nanotubes makes it possible to considerably reduce the resistance of the bolometer, which is determined by a small number of conducting tubes with good tunneling contacts with the electrodes. The energy gap is equal to hundreds and tens of millivolt in the former and latter cases, respectively. Structures containing bundles of carbon nanotubes can be described in a model with a Schottky barrier. The samples with bundles of carbon nanotubes exhibit the bolometric response to external high-frequency radiation at a frequency of 110 GHz with an amplitude up to 100 μV and a temperature voltage response to 0.4 mV/K. 相似文献
3.
Neutron irradiation of Cp2MoCl2 for 24 h afforded the radiotracer Cp299MoCl2 which was characterised by UV–Vis spectroscopy and thin layer chromatography. Binding experiments with the thiol containing protein human serum albumin (HSA) or calf thymus DNA, were monitored for 99Mo using a gamma counter. Under the conditions investigated, molar ratios of binding of 0.2:1 (Cp2MoCl2:DNA) and 9.4:1 (Cp2MoCl2:HSA) were calculated. The results are consistent with in vitro coordination studies that have shown strong preferential interaction of Cp2MoCl2 with thiols versus other donor sites in biomolecules including DNA. 相似文献
4.
The issues involved in teaching English language learners mathematics while they are learning English pose many challenges for mathematics teachers and highlight the need to focus on language-processing issues related to teaching mathematical content. Two realistic-type problems from high-stakes tests are used to illustrate the complex interactions between culture, language, and mathematical learning. The analyses focus on aspects of the problems that potentially increase cognitive demands for second-language learners. An analytical framework is presented that is designed to enable mathematics teachers to identify critical elements in problems and the learning environment that contribute to increased cognitive demands for students of English as a second language. The framework is proposed as a cycle of teacher reflection that would extend a constructivist model of teaching to include broader linguistic, cultural, and cognitive processing issues of mathematics teaching, as well as enable teachers to develop more accurate mental models of student learning. 相似文献
5.
Veerasingam R. Campbell R.B. Mcgrath R.T. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1995,23(4):688-697
A one-dimensional multispecies model of a helium filled AC plasma display cell is described. The model includes a continuity equation for each species. Poisson's equation and a circuit equation. The fill gas is helium for which the cross sections for ionization and excitation for the various atomic states are well known. The reaction rates for the different species were parametrized as functions of E/N using a zero-dimensional spatial and two velocity multispecies Boltzmann kinetic code. Calculations are performed using address and sustain voltages operating at a frequency of 50 kHz to model the pulse behavior of a dielectric barrier discharge which occurs over a time scale on the order of 200 ns or less. The code simulates multipulse behavior and shows reasonably good agreement with experimental data. The simulations show that the circuit filters out the discharge dynamics and that the pulse width of the discharge current depends on the circuit RC time constant. Using a 123 V sustain voltage, the calculated discharge current is 0.4 A with a full width at half maximum (FWHM) of 28 ns. Experimental values using a 120 V sustain voltage are 0.32 A discharge current and 42 ns FWHM 相似文献
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7.
The effects of vanadium substitution on the iron magnetism in YFe12-x V x compounds (x~2–4) have been studied by57Fe Mössbauer spectroscopy. The preference of vanadium atoms for the 8i site of these ThMn12-structure type compounds is confirmed. The rapid collapse of the iron sublattice magnetization with increasing vanadium concentration is analysed in terms of the ‘magnetic valence’ model. 相似文献
8.
L. Andrew Campbell 《Mathematical and Computer Modelling》1993,17(12):3-8
Samuelson maps are maps whose Jacobian matrix has nowhere vanishing leading principal minors. This paper surveys some recent results on invertibility of Samuelson maps and their decomposition into maps that fix all but one coordinate. The most noteworthy result is that real, rational, everywhere defined Samuelson maps are invertible. Proofs are sketched or omitted entirely. 相似文献
9.
Abe F Amidei D Apollinari G Atac M Auchincloss P Baden AR Bamberger A Barbaro-Galtieri A Barnes VE Bedeschi F Behrends S Belforte S Bellettini G Bellinger J Bensinger J Beretvas A Berge JP Bertolucci S Bhadra S Binkley M Blair R Blocker C Booth AW Brandenburg G Brown D Buckley E Byon A Byrum KL Campagnari C Campbell M Carey R Carithers W Carlsmith D Carroll JT Cashmore R Cervelli F Chadwick K Chiarelli G Chinowsky W Cihangir S Clark AG Connor D Contreras M Cooper J Cordelli M Crane D Curatolo M 《Physical review letters》1990,65(18):2243-2246
10.