土壤及其他背景样品中铅同位素比值的测定方法

为给铅同位素示踪技术在判别土壤、大气、水体和人体中铅与相关重金属污染来源,区别汽车尾气铅污染和工业铅污染等方面的应用提供科学依据。通过大量的对比条件实验,拟出了土壤、煤、汽车尾气和气溶胶样品中铅同位素比值的测定方法。利用这三个流程分别测定了采自杭州茶园的土壤及茶园附近的煤、汽车尾气和气溶胶样品的铅同位素比值,其中207Pb/206Pb的精度(2σ)均优于±0.03%。重复样误差优于±0.05%2。08Pb强度一般均在1V以上,有的高达8 V以上。监控分析流程的国际标准物质NBS981的207Pb/206Pb为0.91449±0.00004。全流程本底铅为10-8数量级。     

Chronology and origin of VMS deposits in Xinjiang, NW CHINA

VMS deposits in Xinjiang, NW China are widespread in the Altay, Tianshan and WestKunlun orogenic belt, mainly formed during the Proterozoic rifting and Phanerozoic post-orogenicextension and are related to the bimodal volcanism. The VMS deposits are middle and small inscale. According to assemblages of metallogenetic elements, they can be divided into four types(Cu-Zn, Cu-S, Pb-Zn-Cu and Pb-Zn types) with the Cu-Zn and Pb-Zn types being the most impor-tant ones. Research of isotopic chronology shows that the VMS deposits in Xinjiang were formedduring the Proterozoic, Ordovician, Deovonian, Carboniferous and Permian periods and usuallyunderwent multi-stage mineralization, especially the large-sized deposits usually have post-volcanic superimposed mineralization by tectonomagmatic or metamorphic hydrothermal metal-logenic fluids.