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~~Pulse radiolysis of one-electron oxidation of rare tricyclic nucleoside derivative@赵红卫$Shanghai Institute of Nuclear Research, Chinese Academy of Sciences! Shanghai 201800,China
@江致勤$Department of Chemistry, Tongji Unviersity!Shanghai 200092,China
@窦大营$Shanghai Institute of Nuclear Research, Chinese Academy of Sciences! Shanghai 201800,China
@吴铁一$Shanghai Institute of Nuclear Research, Chinese Academy of Sciences! Shanghai 201800,China
@王文锋$Shanghai… 相似文献
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Using the ns pulse radolysis, we studied the characteristic absorption spectrum and kinetic decay of cytosine anion radical (Cyt-). Results showed that the characteristic absorption of Cyt- was located at λ=355±5 nm, and decayed following the first order kinetics with τ1/2=265 ns at pH=7.0. The decay became slower and τ1/2 rapidly rised with the increment of pH value, Cyt- protonated at C6 in acidic solution, and the characteristic absorption was located at λ=310±5 nm, and decayed following the second order kinetics: Cyt- protonated at N3 in aqueous solution of pH≥7, and the characteristic absorption was located at λ=295±5 nm, and decayed following the second order kinetics. 相似文献
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利用紫外-可见稳态吸收光谱, 稳态荧光发射光谱和激光光解瞬态光谱实验方法研究了磷酸基团在环丙沙星(CPX)光敏损伤DNA中的作用. 紫外-可见和稳态荧光光谱实验证实了磷酸根离子影响环丙沙星的稳态吸收和发射谱, 实验结果表明磷酸根是通过弱相互作用与环丙沙星结合. 我们还利用激光闪光光解实验分别研究了鸟苷(Gua), 脱氧鸟苷(dG)以及脱氧鸟苷酸(dGMP)对环丙沙星三线态(3CPX*)的影响, 通过对比实验证实了在环丙沙星光敏损伤dGMP中, 由于磷酸基团的存在, 导致了环丙沙星三线态吸收峰的改变, 从而改变了光敏损伤反应的途径. 通过研究发现, 光敏损伤途径的改变是由于dGMP结构上磷酸基团通过氢键与环丙沙星结合所造成的. 最后, 根据实验结果并对比Gua, dG和dGMP的结构, 提出了一个合理的磷酸基团的作用机理. 相似文献
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DNA repair has received heightened attention in recent years as ozone depletion threatens to significantly increase DNA damage by UVB radiation[1—6]. The major lesions formed in DNA by this radiation are cis-syn cyclobutane pyrimidine dimers, which are created by the linkage of two neighboring pyrimidine bases in DNA via C5-C5 and C6-C6 atoms by [2+2] cycloaddition[2,5—8]. This potentially lethal or mutagenic damage can be repaired either by the removal of the damaged bases by excisio… 相似文献
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采用纳秒激光光解技术研究了含冠醚螺吡喃化合物(简称BN-BIPS)的光致变色过程.结果表明:BN-BIPS是经一激发单线态生成醌式结构的部花菁B;在乙腈溶液中,激发生成的部花菁B的瞬态吸收有较明显的衰减,同时440 nm左右有新的瞬态吸收生成;当在BN-BIPS的乙腈溶液中加入高氯酸钠后,激发生成的部花菁B的瞬态吸收衰减加快, 440 nm左右的瞬态吸收生成也同步加快.但在BN-BIPS相对应的不含冠醚的螺吡喃BIPS中,未观察到异构体C的生成. 相似文献
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利用基于飞秒超快激光的太赫兹时域光谱(terahertz time domain spectroscopy, THz-TDS)对D-木糖、D-核糖、D-阿拉伯糖、D-来苏糖及相关的五元糖进行了研究, 得到了它们在0.1~2.0 THz波段的THz-TDS吸收谱图. 不同糖类化合物的吸收谱表现出明显的特征, 表明THz-TDS技术可以分辨化合物结构上的微小差异, 可以应用于物质检测与分析. 同时还研究比较了不同旋光性五元糖的THz-TDS光谱. 相似文献
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基于局部方向编码的遥感影像平行边缘识别 总被引:2,自引:0,他引:2
针对高分辨率遥感图像中道路、建筑物和水域等的特征识别难题,提出了一种基于边缘局部方向信息的平行边缘自动识别算法。该算法首先定义平行边缘由一系列相互平行的短直线组成;然后提出了交叉点共线约束的8-邻域边界追踪和9-像素滑动窗口内直线检测算法,实现了边缘连续线条局部方向信息编码;最后通过分析连续线条结构及方向编码规律,提出了主元分析及方向一致性判别准则进行平行特征识别。实验结果表明,该算法能够有效提取高分辨率遥感图像中具有最近邻关系的平行直线和曲线特征,平均识别准确率在95%以上,但算法执行速度有待提高。 相似文献