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This paper is concerned with the interaction of ethyl benzoate (EBA) and trifluoroaceticacid (TFA) molecules in the excited state by measurements of steady--state and transient fluo-rescence spectra at room and low temperatures. The results show that not only the 1:1 exci-plex but also the 2:1 triplex between EBA and TFA was formed. The formation pathway ofthe triplex is that the exciplex formed at first, then by the interaction with the EBA mole-cule it transformed into triplex. But it could not be formed by the dimer of EBA by interac-tion with TFA. The dimer of EBA is confirmed in the concentrated solution. So there arefour components in EBA/TFA--concentrated solution and their fluorescence lifetimes aremeasured respectively. 相似文献
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利用固相反应法制备了稀土掺杂钙钛矿(La_(0.2)Pr_(0.8))_(0.7)Sr_(0.3)CoO_3靶材,并采用脉冲激光沉积(PLD)技术,在n型0.7%Nb-SrTiO_3(100)单晶衬底上制备了(La_(0.2)Pr_(0.8))_(0.7)Sr_(0.3)CoO_3薄膜样品。实验表明所形成的(La_(0.2)Pr_(0.8))_(0.7)Sr_(0.3)CoO_3/Nb-SrTiO_3异质结具有良好的整流特性和明显的光生伏特效应。在室温下,相同光强的调制脉冲激光激励下,波长为473 nm时,异质结产生的光生电压最大值为67 mV;波长532 nm时,光生电压最大值为33 mV。光生电压的最大值随着温度的降低而增加,而光生电压上升沿和下降沿的时间常数随着温度升高减小,分析表明这主要与异质结中热激发载流子浓度与迁移率有关。 相似文献
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本文研究咔唑及其衍生物对9-氰基蒽(9CNA)的荧光猝灭机理。结果表明, 猝灭过程有以下三种方式:(1)一系列N-烷基咔唑及1,4-二咔唑丁烷、反式1,2-二咔唑环丁烷、N-苄基咔唑等对9CNA的荧光猝灭是通过形成激基复合物。(2)咔唑对9CNA的荧光猝灭是通过形成氢键。(3)1,3-二咔唑丙烷及N-痖烯基咔唑对9CNA的荧光猝灭是属于一般碰撞猝灭过程。以上所有猝灭过程主要都是来自电荷转移相互作用。另外, 还讨论了空间位阻对形成激基复合物的影响。并由稳态和动态荧光实验结果,应用Ware关于激基复合物的形成和解离的动力学公式计算出一系列光物理速率常数。 相似文献
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