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为扩大稀土荧光配合物的应用范围,满足水溶液中微量铬的高灵敏高选择性探测要求,制备了一种基于水分散纳米无定形水杨酸甲酯铽配合物(A-MS-Tb)的高灵敏三价铬离子荧光传感器。结果表明:在水溶液中直接反应合成的配合物A-MS-Tb为无定形的纳米沉淀,其粒子尺度在50~100 nm之间,具有与报道的配合物晶体类似的组成。该配合物在494、549、591和625 nm处呈现出强的荧光发射,归属于铽离子的5D4→7FJ(J=6,5,4,3)能级跃迁。A-MS-Tb与晶体配合物的显著差别在于其在水中的悬浮稳定性和荧光稳定性更好,这对于其作为荧光材料和离子传感器非常重要。尤其突出的是,当将三价铬离子加入到它的水悬浮溶液中后,会减弱配体与铽离子之间的配位作用,导致其绿色荧光被淬灭。据此,构建了一种高灵敏测定溶液中铬离子浓度的荧光探针,并对其分析的选择性、灵敏度和抗干扰能力进行了评价。 相似文献
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The Hard X-ray Modulation Telescope (HXMT) is an X-ray astronomy satellite consisting of three slat-collimated instruments, the High Energy X-ray Instrument (HE), the Medium Energy X-ray Instrument (ME), and the Low Energy X-ray Instrument (LE). HXMT will carry out an all sky survey and make pointed observations in the 1-250 keV energy band. In order to get the source and background fluxes simultaneously in the pointed observations, two methods, i.e., the combined field of view (FOV) method and the off-axis pointing method are proposed in this paper. Comprehensive analyses of the sensitivities of the three instruments by using these two methods are presented, respectively. It is found that the off-axis pointing method has a higher sensitivity for HE and ME but a lower sensitivity for LE. Since the axes of the three instruments are aligned along the same direction, the off-axis pointing method is recommended as the main method in the pointed observation for HXMT; the combined FOV method can be used when LE is the most relevant instrument in order to satisfy the scientific objective of the observation. 相似文献
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绪言从价值低廉的煤和石灰所制得的乙炔,由于它的巨大分子生成热以及叁键的存在,就决定了乙炔的化学特性。它的化学活泼性很强,能进行很多种化学反应。利用这些反应可以制造出千百种化学产品,广泛应用于合成橡胶、人造纤维、塑料、高级油漆、染料、药物等工业。无疑地,在国民经济中起着如此重大作用的乙炔化学工业对于我国的化学工业工作者和研究工作者们也是极其感到兴趣的。在苏联帮助下所建成的吉林电石厂为我国的乙炔生产打下了很好的基础,此后的发展只是时间问题。可以说我国的基本有机合成工业,已揭开了新的一页,因此对于乙炔的化学加以特别注意是十分有意义的。如所周知,从乙炔制造乙醛、醋酸、氯乙烯、醋酸乙 相似文献
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