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荧光光谱法研究肌红蛋白活性中心铁卟啉与铜离子的相互作用 总被引:4,自引:1,他引:3
首次应用荧光光谱法研究了肌红蛋白 (FePP Mb)的活性中心铁卟啉与铜离子的相互作用 ,结果表明在水溶液中肌红蛋白中的铁可被铜离子取代 ,形成铜卟啉化合物 (CuPP Mb) ,并且随着体系中铜离子量的增加 ,其相互作用增强。本课题从蛋白质的角度研究了金属离子同生物大分子相互作用的现象并探讨了作用机理 ,可以为进一步研究有害重金属在人体内作用及毒害机理提供一定的理论依据。同时 ,本文采用的荧光光谱法与常规的UV和CD法相比有较高的灵敏度。 相似文献
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The interaction between Sm3+ and MP-11 in the aqueous solution was investigated with cyclic voltammetry, UV-Vis absorption spectrum and circular dichroism. It was found for the first time that Sm3+ could bond to O of carboxyl group in the heme group altering the surface charge of MP-11 molecule and thus increasing its diffusion coefficient. In addition, the interaction between Sm3+ and MP-11 molecule would change the secondary structure of the MP-11 molecule increasing the exposure extent of the heme group in the MP-11 molecule. The above results could increase the reversibility of the electrochemical reaction of MP-11. 相似文献
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用电化学和圆二色性(CD)光谱方法比较了不含和含质量分数为20%甲醇的微过氧化物酶-11(MP-11)溶液的电化学和电催化性能及结构的差别.发现加入甲醇使MP-11的电化学反应的可逆性和对H2O2还原的电催化活性增加,这是由于加入甲醇使部分双聚的MP-11分子变成单体分子,分子的α-螺旋和β-转角的结构含量增加,无规卷曲的结构含量降低,MP-11分子中血红素的暴露程度增加而引起的. 相似文献
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Introduction Recently ,therehasbeenanincreasinginterestinthedevelopmentofelectricdoublelayercapacitors (EDLCs)us inghighlyporouscarbonsastheelectrodematerialsduetotheirpossibletechnologicalapplicationsasenergystoragede vicespossessinghighpowerdensitycapability .1,2 Themainadvantagesofsuchdevicesaretheirpossiblehighratecapa bilityandlongcyclelifeascomparedtorechargeablebatter ies,butitsenergydensityislowerthanthatofrechargeablebatteries.Inordertoobtaintherequiredenergyandpowerdensity,EDLC… 相似文献