聚(苯乙烯－丙烯酸)磁性高分子微球的制备和表征

利用双层表面活性剂改性的Fe3O4磁流体为种子,通过乳液聚合法考察了苯乙烯或苯乙烯-丙烯酸对Fe3O4磁流体的包覆情况,并考察了丙烯酸浓度及加入时间对磁性微球表面羧基含量的影响.结果表明,丙烯酸的加入可以明显改善包覆效果,在反应进行2h后加入0.4mL的丙烯酸可以得到包覆效果好且表面羧基含量大的磁性微球.     

An electromagnetic simulation assisted small signal modeling method for InP double-heterojunction bipolar transistors

We present a convenient and practical electromagnetic (EM) assisted small-signal model extraction method for InP double-heterojunction bipolar transistors (DHBTs). Parasitic parameters of pad and electrode fingers are extracted by means of 3D EM simulation. The simulations with a new excitation scheme are closer to the actual on-wafer measurement conditions. Appropriate simulation settings are calibrated by comparing measurement and simulation of OPEN and SHORT structures. A simpler $\pi $-type topology is proposed for the intrinsic model, in which the base-collector resistance $R_\mu$, output resistance $R_{\rm ce}$ are deleted, and a capacitance $C_{\rm ce}$ is introduced to characterize the capacitive parasitic caused by the collector finger and emitter ground bar. The intrinsic parameters are all extracted by exact equations that are derived from rigorous mathematics. The method is characterized by its ease of implementation and the explicit physical meaning of extraction procedure. Experimental validations are performed at four biases for three InGaAs/InP HBT devices with $0.8\times 7 $μm, 0$.8\times 10 $μm and $0.8\times 15 $μm emitter, and quite good fitting results are obtained in the range of 0.1-50 GHz.     

聚醚砜醚酮的合成与性能

以4,4′-二羟基二苯砜和4,4′-二氟二苯酮为单体, 通过溶液缩聚合成了聚醚砜醚酮(PESEK), 其分子结构相当于聚醚砜(PES)与聚醚醚酮(PEEK)的交替共聚物. 在共聚物分子中, 存在砜基、醚基和酮基, 整个结构单元形成了大共轭体系, 聚合物属无定形聚合物, 玻璃化转变温度(Tg)为198 ℃, 介于PEEK和PES的Tg之间, 其热稳定性和加工性能优于PES, 而力学性能与PES接近.