4-氯酚稀水溶液的脉冲辐解研究

利用脉冲电子束进行了多种条件下4－氯酚稀水溶液的脉冲辐解研究,对其瞬态光谱中的主要吸收峰作了归属,并初步考察了这些瞬态物种的生长、衰减等行为,研究表明,·OH基与4－氯酚在碱性条件下反应生成氯代酚氧基,速率常数为4.14×10^9L/(mol·s),在酸性条件下要经过OH-adducts;H原子与4-氯酚反应生成H-adducts的速率常为2.0×10^9L/(mol·s),产物可通过双分子二级反应逐步脱氯;eaq^-可直接从4-氯酚分子夺氯,反应速率常数为1.82×10^9/L(mol·s)。     

Memoryless cooperative graph search based on the simulated annealing algorithm

We have studied the problem of reaching a globally optimal segment for a graph-like environment with a single or a group of autonomous mobile agents. Firstly, two efficient simulated-annealing-like algorithms are given for a single agent to solve the problem in a partially known environment and an unknown environment, respectively. It shows that under both proposed control strategies, the agent will eventually converge to a globally optimal segment with probability 1. Secondly, we use multi-agent searching to simultaneously reduce the computation complexity and accelerate convergence based on the algorithms we have given for a single agent. By exploiting graph partition, a gossip-consensus method based scheme is presented to update the key parameter--radius of the graph, ensuring that the agents spend much less time finding a globally optimal segment.