pH值对聚四氨基酞菁钴膜电化学和紫外光谱性质的影响

用循环伏安法在导电玻璃(ITO)和玻碳电极(GC)上制备了聚氨基酞菁钴(CoTAPc)修饰电极(CoTAPc/GC)。探讨了pH值对CoTAPc膜的光谱和电化学性质的影响，发现其氧化还原电位与pH值有线性关系，电催化活性也随酸度的增加而增加。CoTAPc膜的紫外吸收带变化与溶液pH值及在溶液中浸泡时间有关。     

红藻藻胆体内部蛋白间的能量传递研究 Ⅰ.人工合成R-PE/R-PC/APC复合物内的能量传递

研究了人工合成的藻胆体模拟复合物的时间分辨荧光光谱,并运用多指数拟合的方法对数据进行了详细的处理和分析,结果表明能量在Ｒ－ＰＥ和Ｒ－ＰＣ之间的传递时间与能量从Ｒ－ＰＣ传递到ＡＰＣ的时间几乎相等（５０ｐｓ）;除此之外,Ｒ－ＰＥ到ＡＰＣ还有两种能量传递的通道,能量在这两个通道的传递时间分别为１１０ｐｓ和４００ｐｓ．即：蛋白之间的能量传递通道是并行的．     

双核金属酞菁类化合物催化脱硫机理研究Ⅳ──中心金属离子对MPc－PcM催化活性的影响

实验研究结果表明双核金属酞菁类化合物ＭＰｃ－ＰｃＭ（Ｍ＝Ｖ、Ｃｒ、Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ）是催化Ｈ＿２Ｓ液相氧化反应的良好催化剂，且其催化活性顺序为Ｃｏ＞Ｎｉ＞Ｖ＞Ｆｅ＞Ｃｕ＞Ｃｒ＞Ｍｎ．采用量子化学理论计算方法（ＩＮＤＯ／Ｓ）分析了其前线分子轨道的构成特征，结果表明这几种ＭＰｃ－ＰｃＭ的ＬＵＭＯ轨道皆为有金属离子参与形成的π轨道，但ＨＯＭＯ轨道间的差异却很大．Ｍ＝Ｃｏ、Ｎｉ、Ｃｕ、Ｃｒ时，其ＨＯＭＯ为π轨道；而Ｍ＝Ｆｅ、Ｍｎ时，其ＨＯＭＯ却为σ轨道．正是在前线分子轨道的轨道类型、共轭程度及金属轨道贡献三方面因素的协同作用下，才导致ＭＰｃ－ＰｃＭ的催化活性顺序并非按中心金属离子价电子层ｄ电子数的递变而呈现出规律性的变化．     

L2[a,b]空间Volterra型积分方程解的存在性

抽象函数的积分问题是非线性泛函的重要内容,深入研究抽象函数的积分有着重要的理论价值和应用价值.笔者利用数学归纳法在L2[a,b]空间中给出了Volterra型积分方程解的存在性.     

Excitation energy transfer mechanisms in allophycocyanin (I)

The mechanisms of excitation energy transfer within allophycocyanin monomer with the theory of generalized master equation (GME) and the technique of time-resobed fluorescence anisotropic spectroscopy are studied. In the case of known information of its structure and spectra, the theory applied is based on the assumption that the coupling interaction between two chromophores is fairly weak. The theory correctly predicts the experimentlly observed rate for excitation energy transfer in allophycocyanin monomer. Based on the results, the energy transfer mechanism can be described as Förster and these processes cannot take place from the high vibrational levels of donor to acceptor.     

Tetra-β-(2-(diethylamino)ethoxy) nickel phthalocyanine: synthesis and inclusion in MCM-41

In order to include phthalocyanine macromolecule in MCM-41 molecular sieve, a inclusion-suitable phthalocyanine derivative tetra-β-(2-(diethylamino)ethoxy) nickel phthalocyanine was synthesized, in two steps, from 4-nitrophthalonitrile and 2-(diethylamino)ethanol, and characterized by mass spectra, ¹H nuclear magnetic resonance spectroscopy, ultraviolet visible spectroscopy, infrared spectroscopy and elemental analysis, which confirmed the proposed molecular structure. The inclusion of synthesized phthalocyanine compound in MCM-41 was carried out by the in situ synthesis method using cetyltrimethyl ammonium bromide as structure template and tetraethyl orthosilicate as silica source in presence of this phthalocyanine compound. The inclusion material was studied by means of X-ray diffraction, field emission scanning electron microscopy, high-resolution transmission electron microscopy, nitrogen adsorption isotherm measurements, etc. Results showed that the macromolecular compound was successfully included into MCM-41, the obtained inclusion material displayed mainly prisms and globes, and the material was a kind of mesoporous materials with regularly hexagonal honeycomb array of uniform cylindrical pores and high surface area.     

基于海洋生物多聚物的功能因子递送系统

基于海洋多聚物的纳米材料是一种新型的功能因子负载体系,临床应用中药物与功能因子的递送方式主要有3种,分别是口服、经皮和注射,但由于体感差、药物递送量低、副作用和有效成分活性丧失等诸多问题的困扰,人们更加希望选择既能提高医疗效果和健康水准,又能满足良好舒适性的传输递送方式。研究发现基于海洋多聚物的纳米材料与传统口服递送体系的系统结合可以实现抗癌药物、营养物质、益生菌、疫苗等功能成分的高效递送,大大提高了上述成分的整体生物利用度。通过阐述纳米载体的制备、功能因子的负载及其吸收机制为基于海洋多聚物功能因子递送体系的发展提供参考和借鉴。     

Expeditious synthesis of 9-allenylpurines via cesium carbonate catalyzed isomerization of 9-alkynylpurines

An expeditious and convenient method to synthesize 9-allenylpurines via cesium carbonate catalyzed isomerization of 9-alkynylpurines has been successfully developed. The reactions proceeded rapidly under the base conditions and formed the desired products in good to excellent yields. The method was suitable with a broad substrate scope and proceeded well even on a multgram-scale. The obtained 9-allenylpurines were successfully applied to prepare various potential bioactive 9-acyclic nucleosides with high regioselectivity promoted by AgNO₃.     

许浑籍里小考

晚唐诗人许浑的籍里,学术界多认定是润州丹阳。考察许浑的诗作,自称是朱方、京口及丁卯桥人。朱方、京口皆古地名,相当于唐润州丹徒县,其所居之地有丁卯桥。即许浑是唐润州丹徒人。