Novel alternating copolyoxamides with high crystallinity and heat resistance

Two series of novel alternating copolyoxamides (PAnT-alt-n2 and PAn2-alt-62) are synthesized via solution/solid-state polycondensation (SSP). The alternating structures are analyzed carefully with ¹H NMR and ¹³C NMR spectra. The melting behaviors, thermal stabilities, crystal structures and crystallinities are systematically evaluated by DSC, TGA and WAXD. The results reveal that these alternating copolyoxamides possess almost perfect alternating chain structures and have high melting temperature (T_m > 270 °C), high crystallinity (X_c > 32%) and high decomposition temperature (T₅ > 405 °C) as well as low saturated water absorption (<3.5 wt%), which suggests that they have high potential as engineering plastic of high heat resistant.     

A Novel Biaryl Derivative from Hydrangea chinensis

Chemistry of Natural Compounds - A novel bibenzyl derivative, hydrangchinenin (1), was isolated from the stems of Hydrangea chinensis Maxim. (Hydrangeaceae). Its structure was determined on the...     

Isoflavonoids from Astragalus membranaceus Hairy Roots

Chemistry of Natural Compounds -     

Effect of temperature on the interactions between cellulose and lignin via molecular dynamics simulations

Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and...     

电缆槽对电缆间串扰的影响研究

电缆在使用时一般会铺设在电缆槽中,而电缆槽对铺设其中电缆之间的串扰会形成影响.针对电缆槽中电缆之间的串扰问题,提出一种结合多端口网络理论及分块级联思想的建模方法,使用基于波导格林函数的矩量法来提取电缆槽中电缆间的分布参数,并用虚拟节点理论将提取的分布参数矩阵转化为模型中的传输函数.通过与商业电磁仿真软件的仿真结果进行对比,验证了本文的模型及算法在分析电缆槽中电缆间的串扰问题时具有较好的精确度,最后运用此方法分析了电缆处于电缆槽中不同位置时的线间串扰大小,并结合铁路现场的实际情况对电缆槽中电缆的布线方式提出了建议.     

Flower-like titanium dioxide as novel co-reaction accelerator for ultrasensitive “off–on” electrochemiluminescence aptasensor construction based on 2D g-C3N4 layer for thrombin detection

Journal of Solid State Electrochemistry - An ultrasensitive “signal-off–on” electrochemiluminescence (ECL) biosensor is constructed based on f1-TiO2/g-C3N4/PDA for thrombin...     

Auto-deposition of 210Bi and 210Po on nickel discs and their application in the analysis of natural waters

Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature...     

Excellent UV-absorbing cotton fabric with high durability and hydrophobicity based on surface-initiated ATRP of polymerizable organic UV-absorber

Cellulose - Ultraviolet (UV) protective cotton fabric is a convenient and reliable way to protect human body from sunlight. Herein, a polymerizable UV-absorber,...