Designing Covalent Organic Frameworks with a Tailored Ionic Interface for Ion Transport across One-Dimensional Channels

A strategy based on covalent organic frameworks for ultrafast ion transport involves designing an ionic interface to mediate ion motion. Electrolyte chains were integrated onto the walls of one-dimensional channels to construct ionic frameworks via pore surface engineering, so that the ionic interface can be systematically tuned at the desired composition and density. This strategy enables a quantitative correlation between interface and ion transport and unveils a full picture of managing ionic interface to achieve high-rate ion transport. Moreover, the effect of interfaces was scaled on ion transport; ion mobility is increased in an exponential mode with the ionic interface. This strategy not only sets a benchmark system but also offers a general guidance for designing ionic interface that is key to systems for energy conversion and storage.     

上海基础房价相关指标及走势的分析与研究

基础房价的相关指标及其走势一直是大众关心的热门话题．本文通过对上海基础房价相关指标的分析，建立了市场房价走势的两个数学模型．模型一：在相关性分析的基础上利用主成分分析消除指标间的共线性，再用回归拟合房价模型并进行预测；模型二：在相关性分析的基础上利用核估计方法预测出房价．继呵对2005年下半年的房价走势进行了预测，得出的结果与实际情况相吻合．     

NRET from naphthalene labels in multilayer shell wall on melamine formaldehyde microparticles fabricated with layer-by-layer self-assembly to pyrene-labeled polyelectrolyte in solution

Core-shell colloidal particles were prepared with the core of monodisperse melamine formaldehyde particles (MF) with a diameter of 3.5 μm. The shell deposited on the core by the layer-by-layer (LbL) self-assembly was made with a copolymer ANp3 of 2-acrylamido-2-methylpropanesulfonate sodium (AMPS) and 3 mol% naphthalene label monomer and poly(diallyldimethylammonium chloride) (PD). Nonradiative energy transfer (NRET) from the naphthalene labels deposited on the MF particles to pyrene labels at a polyelectrolyte APy3, a copolymer of AMPS and 3 mol% pyrene label monomer, or to an ionic pyrene probe 1-pyrenemethylamine hydrochloride (PyMeA · HCl) in water was observed. The NRET efficiency was expressed as the emission intensity ratio I/I₀ of naphthalene with and without existence of pyrene in the surrounding solution. With increasing pyrene concentration, I/I₀ decreased down to about 0.2 and the mechanism for this NRET from the inner naphthalene label to the pyrene labels in solution is still ambiguous.     

The vibration-rotation emission spectrum of gaseous HZnCl

Gaseous HZnCl has been synthesized for the first time in a high-temperature tube furnace with a dc discharge in a flowing mixture of pure HCl and Zn vapor. The vibration-rotation emission spectrum of HZnCl was recorded at high resolution using a Fourier transform spectrometer. The H-Zn stretching modes (nu(1)) of the H(64)Zn(35)Cl, H(66)Zn(35)Cl, H(68)Zn(35)Cl, and H(64)Zn(37)Cl species, as well as the 2nu(1)-nu(1) hot band of the most abundant isotopologue H(64)Zn(35)Cl, were observed near 1966 cm(-1). A least-squares fit was performed for each of the four observed isotopologues, and their spectroscopic constants were determined.     

Waterborne polyurethane assembly multifunctional coating for hydrophobic and antibacterial fabrics

Surface modification of fabrics is a powerful strategy that can endow fabrics with desired effects while keeping the intrinsic properties. Herein, an ordinary strategy, dipping-drying based layer-by-layer self-assembly (LbL) coating, is reported to functionalize fabrics’ surfaces. Firstly, the novel cation waterborne polyurethanes (QAHDPU) and anion waterborne polyurethanes (HDPU) are successfully designed and synthesized. By incorporating targeted molecule, hydantoin diol (HD) and quaternary ammonium salt with long alkyl chain (DOQA), the QAHDPU are antibacterial and hydrophobically functionalized. Taking advantage of strong adhesion, waterborne polyurethanes (WPUs) are physically bonded to surfaces of fabrics to generate durable antibacterial and hydrophobic fabrics. The QAHDPU with long alkyl chain combined with rough and porous fabric surface fabricates hydrophobic fabric surface, which can prevent bacteria from adhering to the fabrics. Furthermore, the coated fabrics present excellent antibacterial properties after chlorination, forming a second barrier against bacteria. The chlorinated coated fabrics, can inactivate 85.0–99.9% of Staphylococcus aureus and 85.0–97.7% of Escherichia coli with contact time of 60 min. The hydrophobic properties of coated fabrics are greatly improved with water contact angles of 122.0°–141.1°. In addition, the proposed method is applicable for a variety of fibers and expected to be used for industrial production.

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纺织类高校国家自然科学基金资助情况及科研竞争力分析

基于国家自然科学基金委网站科学基金网络信息系统平台,对7所具有纺织背景的高校在2006—2016年间获得国家自然科学基金资助的情况进行全面的统计分析,探讨了纺织背景高校近年来纺织学科的发展现状,客观评价了各高校纺织学科的学术影响力.研究结果显示:苏州大学和江南大学获得国家自然科学基金资助项目的数量和金额都明显高于其他高校,总体科研竞争力较强;武汉纺织大学、浙江理工大学和天津工业大学的纺织学科获得资助项目的数量和金额占比较高,其纺织学科科研竞争力强;综合性的纺织背景高校越来越倚重其他学科的发展,而对传统纺织技术创新性的研究很少,今后应在传统纺织技术上有所突破.     

多分量地震监测系统AETA的研究与实现

研制多分量地震监测系统AETA(acoustic & electro-magnetic testing all in one system)。在云南、四川、西藏、河北、北京、广东等地区的现场实验表明, 该系统能够满足大区域密集布设中高灵敏度、低成本和易布设的需求。同时, 若干点的实验观测数据和均值、振铃率、峰值频率在一定程度上反映了映震效果。目前正在中国西南部、首都圈、台湾海峡等地区密集布设, 系统地开展映震效果研究。     

多分量地震监测系统AETA的感应式磁传感器磁棒研制

根据多分量地震监测系统AETA的技术需求, 完成一种感应式磁传感器的研制和工业化实现。通过分析电磁扰动的监测需求, 确定感应式磁传感器磁棒的各项设计参数, 并提出较优材料选取以及结构设计方案。磁棒的设计指标为0.1 Hz~10 kHz, 工作温度范围为40~130℃, 监测的磁场强度范围为1~1000 nT, 灵敏度大于20 mV/nT@(0.1 Hz~10 kHz)。测试结果表明, 研制的磁传感器满足AETA的性能要求。该传感器已成功地投入应用, 正在大区域规模化布设。     

Some limit theorems for negatively associated random variables

Let {X _n , n ≥ 1} be a sequence of negatively associated random variables. The aim of this paper is to establish some limit theorems of negatively associated sequence, which include the L ^p -convergence theorem and Marcinkiewicz–Zygmund strong law of large numbers. Furthermore, we consider the strong law of sums of order statistics, which are sampled from negatively associated random variables.