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For fairly high concentrations, the effective arsenic diffusioncoefficient is known to grow linearly with the concentration.In this paper, we consider the strongly enhanced diffusion ofarsenic by asymptotic methods, and extend the results of a previouspaper (King & Please, 1987) in three ways: we characterizean additional (low-concentration) region; we consider the influenceof the initial data; and we consider the case of constant surfaceconcentration. 相似文献
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R. B. KING 《Molecular physics》2013,111(10):1567-1577
Topological representations (top-reps), which originally were developed to model molecular polyhedral isomerization processes, can be extended to depict the relationships between the polygons and polyhedra involved in Jahn-Teller (JT) distortions. Using this approach, the top-rep of the E ? (b 1g + b 2g) distortion of square planar molecules to rectangle and rhombus isomers becomes a rhombus in which the vertices alternately represent distortions to the rectangle and rhombus isomers. Similarly the top-rep of the E ? e distortion of regular Oh octahedra to elongated D4h tetragonal bipyramids becomes a triangle in which the vertices represent the three distinct tetragonal bipyramids from a given octahedron and the edge midpoints represent lower symmetry rhombic D2h intermediates. A regular octahedron can be used as a top-rep for the T ? (e + t 2) distortions of regular octahedra if the 6 vertices represent distortions to D4h tetragonal bipyramid isomers, the 8 face midpoints represent distortions to D3d trigonal antiprism isomers, and the 12 edge midpoints represent lower symmetry rhombic D2h intermediates. In the case of Jahn-Teller T ? h distortions of regular Ih icosahedra, the corresponding top-rep becomes a regular icosahedron in which the 12 vertices represent distortions to pentagonal D5d isomers, the 20 face midpoints represent distortions to trigonal D3d isomers, and the 30 edge midpoints represent D2h intermediates. A 4-dimensional analogue of the tetrahedron (i.e. the 4-simplex) can be used as a top-rep for the G ? g problem and the H ? g component of the H ? (g + 2h) problem for JT distortions of regular icosahedra. In this case the 5 vertices and the 10 edge midpoints correspond to Th isomers and D3d intermediates, respectively. 相似文献
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对国内外两组膨体聚四氟乙烯(ePTFE)人工血管从管壁结构、理化性能和生物力学性能进行对比研究.通过试验研究两组人造血管管壁的宏观及微观结构、表面润湿性、结晶度和融熔温度、周/轴向拉伸、顶破拉伸以及手术线固位强力,对比两组样品的性能差异,并分析了导致差异的可能原因,讨论了管壁结构、理化性能与力学特性之间的关系.研究结果表明,国产和进口ePTFE人工血管试样均为双层结构,两者都有良好的疏水性表面和抗水渗透性.但进口试样具有更加规整均匀的节点和纤维形态结构,有利于人工血管的生物耐久性. 相似文献
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In this paper, we have calculated the elastic scattering of high energy electrons with nuclei C12 by phase shift calculation.We take the charge distribution of the nucleus C12 as following:(1) exponential distribution:ρ(x)=ρ0θ-x/a, (2) gaussian distribution:ρ(x)=ρ0e(-x2/a2),(3) uniform distribution: ρ(x) ={ρ0 when 0kR, where a and b are the parameters, and the constant R is the radius of the nucleus C12. The energy of the electrons is 187 Mev.The result of the calculation shows that the gaussian distribution confirms the experimental result better than the other two kinds of distributions, and gives R=(12)1/3r0, where r0=1.35×10-13 cm. 相似文献
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