全文获取类型
收费全文 | 50900篇 |
免费 | 6590篇 |
国内免费 | 5369篇 |
专业分类
化学 | 22343篇 |
晶体学 | 553篇 |
力学 | 1756篇 |
综合类 | 381篇 |
数学 | 3340篇 |
物理学 | 12471篇 |
综合类 | 22015篇 |
出版年
2024年 | 149篇 |
2023年 | 700篇 |
2022年 | 1203篇 |
2021年 | 1411篇 |
2020年 | 1399篇 |
2019年 | 1440篇 |
2018年 | 1200篇 |
2017年 | 1262篇 |
2016年 | 1727篇 |
2015年 | 2088篇 |
2014年 | 2511篇 |
2013年 | 3114篇 |
2012年 | 3819篇 |
2011年 | 3950篇 |
2010年 | 3168篇 |
2009年 | 3348篇 |
2008年 | 3696篇 |
2007年 | 3327篇 |
2006年 | 3147篇 |
2005年 | 2786篇 |
2004年 | 2334篇 |
2003年 | 1875篇 |
2002年 | 2010篇 |
2001年 | 1773篇 |
2000年 | 1448篇 |
1999年 | 1338篇 |
1998年 | 991篇 |
1997年 | 901篇 |
1996年 | 768篇 |
1995年 | 718篇 |
1994年 | 641篇 |
1993年 | 513篇 |
1992年 | 403篇 |
1991年 | 390篇 |
1990年 | 311篇 |
1989年 | 247篇 |
1988年 | 208篇 |
1987年 | 142篇 |
1986年 | 106篇 |
1985年 | 73篇 |
1984年 | 40篇 |
1983年 | 39篇 |
1982年 | 25篇 |
1981年 | 24篇 |
1980年 | 24篇 |
1979年 | 14篇 |
1978年 | 11篇 |
1977年 | 8篇 |
1975年 | 6篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Qin Yin Shou-Guo Wang Xiao-Wei Liang De-Wei Gao Jun Zheng Shu-Li You 《Chemical science》2015,6(7):4179-4183
An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation. 相似文献
2.
A nanomaterials-based novel molecular beacon has attracted growing attentions in fluorescent assays as many nanomaterials possess excellent quenching efficiency. In this work, a gold-based nanobeacon probe was established to detect organophosphorus pesticides for the first time. The constructed gold-based nanobeacon acted as a signal indicator and could display the decreasing of the intensity in the presence of targets, which competitively bound to single strand DNA. To achieve a high sensitive probe, some parameters including solution pH, temperature and reaction time were investigated and optimized. The gold-based nanobeacon probe assay was proved to be rapid and sensitive to achieve a detection limit of 0.035 μM for isocarbophos, 0.134 μM for profenofos, 0.384 μM for phorate and 2.35 μM for omethoate, respectively. The prepared nanobeacon effectively reduced the background and improved the detection sensitivity and selectivity. The probe is stable, easy to operate and does not need sophisticated instruments. These features makes the probe feasible for screening trace organophosphorus pesticides in real samples. 相似文献
3.
就标准厚度卡片在霍尔传感器的定标方面的应用作了有益的探讨。在纵向测量微小长度时,霍尔片处于磁场边缘位置,其对磁场的梯度更大,即灵敏度更高,且靠中心位置的线性更好。 相似文献
4.
5.
Dr. Jun Zeng Dr. Zhichao Wang Dr. Xin Huang Dr. Sabine S. Eckstein Prof. Dr. Xiaohui Lin Prof. Dr. Hailong Piao Prof. Dr. Cora Weigert Dr. Peiyuan Yin Prof. Dr. Rainer Lehmann Prof. Dr. Guowang Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(21):5427-5432
Mass spectrometry (MS) driven metabolomics is a frequently used tool in various areas of life sciences; however, the analysis of polar metabolites is less commonly included. In general, metabolomic analyses lead to the detection of the total amount of all covered metabolites. This is currently a major limitation with respect to metabolites showing high turnover rates, but no changes in their concentration. Such metabolites and pathways could be crucial metabolic nodes (e.g., potential drug targets in cancer metabolism). A stable-isotope tracing capillary electrophoresis–mass spectrometry (CE-MS) metabolomic approach was developed to cover both polar metabolites and isotopologues in a non-targeted way. An in-house developed software enables high throughput processing of complex multidimensional data. The practicability is demonstrated analyzing [U-13C]-glucose exposed prostate cancer and non-cancer cells. This CE-MS-driven analytical strategy complements polar metabolite profiles through isotopologue labeling patterns, thereby improving not only the metabolomic coverage, but also the understanding of metabolism. 相似文献
6.
In this paper, we propose a sufficient and necessary condition for the boundedness of all the solutions for the equation with the critical situation that on g and p, where , is periodic and is bounded. 相似文献
7.
罗兆均 《大理学院学报:综合版》2015,(1):22-28
通过对云南跨境民族地区的田野调查,该区域宗教渗透不仅没有停止,反而呈现出多样性、隐蔽性等特点。宗教渗透对跨境民族的国家政治认同等造成了严重破坏,对云南边疆社会的稳定构成了较大的威胁,成为了云南边疆地区非传统安全问题中最敏感、最复杂、最难解决的问题之一。抵御宗教渗透不仅要完善政府宗教管理能力、改善经济条件等,更要调动作为文化主体者的跨境民族自身的"文化自觉",以主动抵御宗教渗透。只有如此才是最有效的抵御宗教渗透举措,才最终有利于和谐边疆的构建。 相似文献
8.
Nonclassical light states are important for both conceptual and practical reasons: they are basic ingredients in testing and exploring quantum foundations, and are crucial resources in quantum technologies. Various useful criteria have been developed to detect nonclassicality in the literature, and several meaningful measures of nonclassicality have been introduced and measured experimentally. In this work, by use of a non-Hermitian generalization of the Wigner-Yanase-Dyson skew information and playing with operator ordering in evaluating average photon number, we develop a novel family of criteria for detecting nonclassicality of light based on Lieb's concavity, which is a deep and powerful result concerning interaction between quantum states and observables. We elucidate the information-theoretic as well as the physical meaning of the criteria, and illustrate their effectiveness in capturing and quantifying nonclassicality of various important light states. 相似文献
9.
Sung Hwan Koo Dong Jun Li Taeyeong Yun Dong Sung Choi Kyung Eun Lee Gil Yong Lee Youngtak Oh Joonwon Lim Suchithra Padmajan Sasikala Ho Jin Lee In Ho Kim Hong Ju Jung Rishabh Jain Sang Ouk Kim 《Particle & Particle Systems Characterization》2019,36(7)
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of ≈169 mV at a current density of ≈10 mA cm?2. Accordingly, efficient charge transfer is attained with Tafel slope of ≈52 mV dec?1 and a charge transfer resistance (Rct) of ≈12 Ω. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well‐controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer. 相似文献
10.