全文获取类型
收费全文 | 32619篇 |
免费 | 3743篇 |
国内免费 | 4431篇 |
专业分类
化学 | 13923篇 |
晶体学 | 294篇 |
力学 | 1119篇 |
综合类 | 374篇 |
数学 | 2415篇 |
物理学 | 7169篇 |
综合类 | 15499篇 |
出版年
2024年 | 97篇 |
2023年 | 450篇 |
2022年 | 772篇 |
2021年 | 882篇 |
2020年 | 919篇 |
2019年 | 801篇 |
2018年 | 720篇 |
2017年 | 747篇 |
2016年 | 1012篇 |
2015年 | 1256篇 |
2014年 | 1588篇 |
2013年 | 1923篇 |
2012年 | 2197篇 |
2011年 | 2275篇 |
2010年 | 1932篇 |
2009年 | 1946篇 |
2008年 | 2224篇 |
2007年 | 2151篇 |
2006年 | 2008篇 |
2005年 | 1743篇 |
2004年 | 1409篇 |
2003年 | 1238篇 |
2002年 | 1475篇 |
2001年 | 1353篇 |
2000年 | 1192篇 |
1999年 | 1008篇 |
1998年 | 678篇 |
1997年 | 611篇 |
1996年 | 614篇 |
1995年 | 526篇 |
1994年 | 500篇 |
1993年 | 461篇 |
1992年 | 378篇 |
1991年 | 346篇 |
1990年 | 286篇 |
1989年 | 269篇 |
1988年 | 232篇 |
1987年 | 171篇 |
1986年 | 98篇 |
1985年 | 80篇 |
1984年 | 65篇 |
1983年 | 38篇 |
1982年 | 35篇 |
1981年 | 19篇 |
1980年 | 26篇 |
1979年 | 9篇 |
1977年 | 4篇 |
1973年 | 3篇 |
1957年 | 4篇 |
1955年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Liu Wenbin Huang Yiwei Huang Guolin Fan Lijiao Xie Yuming Shi Jeffery 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2055-2068
Journal of Radioanalytical and Nuclear Chemistry - Eco-friendly and low-cost composite, amidoxime-functionalized microcrystalline cellulose/mesoporous silica (MCC/MS-AO), were synthesized by... 相似文献
2.
Shilin Jiang Dr. Yalan Liu Dr. Lin Wang Prof. Zhifang Chai Prof. Wei-Qun Shi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201145
The coordination chemistry of f-block elements (lanthanide and actinide) in molten salts has become a resounding topic in view of its great importance to the research and development (R&D) of molten salt reactors and pyroprocessing. In this Review article, a general overview of the coordination chemistry of f-block elements in molten salts is provided including past achievements and recent advances. Particular emphases are placed on the oxidation state, speciation, and solution structure of f-block metal ions in molten salts, as well as their relationships with the salt composition. Furthermore, this review briefly discusses the spectroscopic and theoretical methods that complement each other in revealing the coordination properties. 相似文献
3.
Dr. Zaifa Shi Dr. Yihuang Jiang Dr. Jingxiong Yu Prof. Shanjun Chen Prof. Jun Chen Prof. Zichao Tang Prof. Lansun Zheng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(8):e202103546
At present, the reactivity of cyclic alkanes is estimated by comparison with acyclic hydrocarbons. Due to the difference in the structure of cycloalkanes and acycloalkanes, the thermodynamic data obtained by analogy are not applicable. In this study, a molecular beam sampling vacuum ultraviolet photoionization time-of-flight mass spectrometer (MB-VUV-PI-TOFMS) was applied to study the low-temperature oxidation of cyclopentane (CPT) at a total pressure range from 1–3 atm and low-temperature range between 500 and 800 K. Low-temperature reaction products including cyclic olefins, cyclic ethers, and highly oxygenated intermediates (e. g., ketohydroperoxide KHP, keto-dihydroperoxide KDHP, olefinic hydroperoxides OHP and ketone structure products) were observed. Further investigation of the oxidation of CPT – electronic structure calculations – were carried out at the UCCSD(T)-F12a/aug-cc-pVDZ//B3LYP/6-31+ G(d,p) level to explore the reactivity of O2 molecules adding sequentially to cyclopentyl radicals. Experimental and theoretical observations showed that the dominant product channel in the reaction of CPT radicals with O2 is HO2 elimination yielding cyclopentene. The pathways of second and third O2 addition – the dissociation of hydroperoxide – were further confirmed. The results of this study will develop the low-temperature oxidation mechanism of CPT, which can be used for future research on accurately simulating the combustion process of CPT. 相似文献
4.
Li Y. Shi W. H. Dong L. M. Xu S. X. Huang H. J. Yin J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,... 相似文献
5.
6.
为了测试在太空环境下航天机构中弹性机构的性能指标,研制了高低温环境下测量角度-力矩特性的测试平台.分析测试平台测试原理后,设计了平台的机械结构、设计电气系统结构并搭建软件系统.机械结构考虑对被测对象的保护,针对高低温测试带有高低温箱,可以为被测对象提供-100℃~100℃的温度环境,具有热变形偏差测量与补偿设计,减少温度变化对测量精度的影响.软件系统具备收集、处理、存储数据和图形化显示能力.分析平台不确定度的组成,对传感器进行测试校准并对航天弹性机构进行测试,测试结果验证了:该测试平台的力矩检测范围为0~50 N·m,力矩检测精度≤0.5%FS,角度测量扩展不确定度为U=35.6″,得到了被测对象的角度-力矩特性曲线图. 相似文献
7.
Journal of Visualization - The increasing availability of spatiotemporal data provides unprecedented opportunities for understanding the structure of an urban area in terms of people’s... 相似文献
8.
采用视觉搜索范式,研究图标视觉特征及数量变化对图标布局认知绩效的影响.实验表明,当图标数量N=6时,仅图标视觉特征主效应显著,布局方式对搜索速度无显著影响,图标视觉特征是认知绩效的主要影响因素;当图标数量N=15时,仅图标布局方式主效应显著,横向排列搜索速度最快.通过图标数量的连续性变化实验发现,图标数量超过10个,横向排列反应时显著低于纵向排列,两者错误率无显著差异;随着图形面板 L○长度 / S○宽度比值的降低,两者平均反应时差距逐渐缩小,趋于一致.研究表明,图标数量的变化对布局方式和视觉特征的认知绩效产生显著影响. 相似文献
9.
The chiral phase transition and equation of state are studied within a novel self-consistent mean-field approximation of the two-flavor Nambu-Jona-Lasinio model. In this newly developed model, modifications to the chemical μ and chiral chemical \begin{document}$\mu_5$\end{document} ![]()
![]()
potentials are naturally included by introducing vector and axial-vector channels from Fierz-transformed Lagrangian to the standard Lagrangian. In the proper-time scheme, the chiral phase transition is a crossover in the \begin{document}$T-\mu$\end{document} ![]()
![]()
plane. However, when \begin{document}$\mu_5$\end{document} ![]()
![]()
is incorporated, our study demonstrates that a first order phase transition may emerge. Furthermore, the chiral imbalance will soften the equation of state of quark matter. The mass-radius relationship and tidal deformability of quark stars are calculated. The maximum mass and radius decrease as \begin{document}$\mu_5$\end{document} ![]()
![]()
increases. Our study also indicates that the vector and axial-vector channels exhibit an opposite influence on the equation of state. 相似文献
10.
Herein, we successfully construct the 3D biocompatible graphene through crosslinking 2D graphene nanosheet onto carbon fiber paper with poly(diallyldimethylammonium chloride) (PDDA) as anode of the alcohol biofuel cell. Compared with the bioanode without 3D graphene, the current density and output power of PDDA-graphene-ADH bioanode is increased by 23 % and 41 % at a high concentration of ethanol at pH 8.9, suggesting the stabilization role of graphene in enzyme loading. The study provides us a deep analysis on structures and performances of the bioanode incl. electrochemistry, X-ray photoelectron spectra, and atomic force microscopy images, which is significant to develop the new methods to construct 3D porous electrodes in energy conversion device. 相似文献