Surface of room temperature ionic liquid [bmim][PF6] studied by polarization- and experimental configuration-dependent sum frequency generation vibrational spectroscopy

Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface.     

20世纪上半叶“扬黛抑钗”审美倾向浅探--钗黛形象接受史研究之三

“扬黛抑钗”的审美倾向贯穿于20世纪上半叶的四个历史阶段并各有特色，它鲜明地折射出每个时期的时代意识。     

Selenium Nanoparticles Prepared from Reverse Microemulsion Process

Selenium nanoparticles were prepared by a reverse microemulsion system. Sodium selenosulfate was used as selenium source. The results showed that hydrochloric acid concentration and reaction temperature had great influence on the morphology of products. The crystalline selenium nanowires and amorphous selenium nanorods were obtained in given condition.     

Earthshaker: A mobile rescue robot for emergencies and disasters through teleoperation and autonomous navigation

To deal with emergencies and disasters without rescue workers being exposed to dangerous environments, this paper presents a mobile rescue robot, Earthshaker. As a combination of a tracked chassis and a six-degree-of-freedom robotic arm, as well as miscellaneous sensors and controllers, Earthshaker is capable of traversing diverse terrains and fulfilling dexterous manipulation. Specifically, Earthshaker has a unique swing arm—dozer blade structure that can help clear up cumbersome obstacles and stabilize the robot on stairs, a multimodal teleoperation system that can adapt to different transmission conditions, a depth camera-aided robotic arm and gripper that can realize semiautonomous manipulation and a LiDAR aided base that can achieve autonomous navigation in unknown areas. It was these special systems that supported Earthshaker to win the first Advanced Technology & Engineering Challenge (A-TEC) championships, standing out of 40 robots from the world and showing the efficacy of system integration and the advanced control philosophy behind it.     

羧甲基壳聚糖对胆红素的吸附性能研究

合成了不同取代度的羧甲基壳聚糖(CM-CTS)作为吸附剂，研究了不同条件对CM-CTS吸附胆红素性能的影响．结果表明：在实验条件下，随着羧甲基取代度的增加和体系温度的升高．最大吸附率和吸附速率均相应增加：在接近人体血液pH值的条件下，CM-CTS对胆红素的吸附性能较佳：人血清白蛋白和离子强度的增加对CM—CTS吸附胆红素有明显的抑制作用。     

粗糙集方法在基于属性分类中的应用

介绍粗糙集基础上的属性分类系统的构造,给出一种数据挖掘中新的分类方法:从初始的数据信息出发,依次构造约简属性集,并对其使用Bayes判别法进行基于属性的分类。最后给出了实例,验证算法的可行性。     

信息时代的大学毕业生如何利用网络求职

本文通过分析网络时代如何获取和处理求职信息,从而对大学毕业生利用网络成功求职的技巧进行探讨和指导。     

相容关系与相容核

给定论域上的相容关系,本文提出了相容核的概念。较之于相容关系的最大相容类,相容核是一个局部化的相容类。我们还讨论了有关相容核的若干数学性质,并且给出了相容关系与其相应的相容核族之间相互唯一确定的充分必要条件。     

基于自识别水印模式的抗几何攻击水印算法研究

提出了一种不依赖于同步性的抗几何攻击的水印算法,通过对水印模式结构进行精心设计,使得其自身具有可识别性,通过对不同结构的水印模式进行识别,从而判断对应的水印信号.算法从根本上消除了同步性的依赖,也不需要对图像进行区域剖分和规范化,因此大大节省计算消耗.实验结果表明,该水印算法对旋转、缩放、裁剪、改变纵横比等几何操作具有鲁棒性,同时对高斯噪声、低通滤波等信号处理操作也具有鲁棒性.     

菲涅耳全息图的计算机生成及数字重现

本文研究菲涅耳(Fresnel)衍射积分的两种计算机模拟算法,分别用卷积算法和傅里叶变换算法实现菲涅耳积分,阐述了两种算法的优点和缺点。尝试将计算全息与数字全息相结合,模拟光线的菲涅耳衍射传播,用计算机生成菲涅耳全息图,并由所生成的全息图再现出原始图像,完成全息图的数字重现,真正实现整个全息记录和重现过程的计算机模拟。