半钢的热加工

本文研究了半钢材料的热加工性。给出了半钢热加工的工艺参数、组织和性能。并以大型铸锭为例,实施了半钢的锻造工艺和轧辊产品的试制,取得了良好的结果。     

大冷变形对化学镀Ni-Sn-P非晶态合金晶化的影响

本文研究了大冷变形对化学镀Ni-Sn-P非晶合金晶化的影响,结果表明,冷变形促进了晶化,不仅降低了Ni-Sn-P非晶合金的热稳定性,而且在冷变形过程中就有晶化产生.     

阻燃粘胶纤维的研究进展

粘胶纤维是一种性能优良,穿着舒适的再生纤维素纤维,一直受到人们的欢迎。由于生产过程造成污染,发达国家逐渐关停了传统粘胶工业,发展中国家成为粘胶纤维的主要生产国。粘胶纤维的主要缺点是极易燃烧,湿态强度低。为减少人员伤亡和火灾损失,有必要添加阻燃剂对粘胶纤维进行改性。本文参考了国内外大量文献,介绍了国内外广泛使用的阻燃剂及最新开发的新型阻燃剂,对阻燃粘胶的发展历史和现状进行了详细的介绍,探讨了阻燃粘胶纤维的未来发展趋势。     

Researches on the In Situ Copolymerization of Ethylene with Catalysts Immobilized onto the Molecular Sieves

In this paper,the bi-functional catalyst system composed of molecular sieve(MCM-41) immobilized oligomerization catalyst(C25H17Cl2N3·FeCl2) and copolymerization catalyst(Et(Ind)2ZrCl2) was employed in the in situ copolymerization of ethylene aiming to prepare the Linear low density polyethylene(LLDPE).In this paper,we mainly argued the regular pattern of the in situ copolymerization of ethylene in limited nano-space and compared it with that happening in free space.The impact of variance of the reaction temperature,Fe/Zr value and the A1/(Fe+Zr) value on the activity of the in situ copolymerization of ethylene has also been introduced.Furthermore,the degree of branching,thermal properties and crystalline changes of the obtained polymerization products prepared from different reactivity were investigated.     

Supercontinuum generation with 15-fs pump pulses in microstructured fiber with combination core and random cladding

We demonstrate the generation of supercontinuum (SC) of over 1350 nm by injecting 790-nm, 15-fs, 74-MHz optical pulses into a 183-mm-long microstructured fiber with combination core and random cladding. The maximum total power of SC is 73 mW with 290-mW pump power from 40x microscope objective. The wavelength and power ranging in SC as well as the polarization states and waveguide modes of the visible light can be tuned by adjusting the input end of MF.In particular, white light has been observed. To our knowledge, this is the first report of tunable properties in SC generation process using microstructured fiber with combination core and random cladding.     

锶掺杂对钙钛矿型氧化物LaMnO3电催化性能的影响研究

采用正交实验方法,研究了当x取不同值时,混合初始溶液的pH值、表面活性剂OP-10以及络合物柠檬酸的添加量,和前驱体的焙烧温度等因素对La1-xSrxMnO3结晶形态和粒径的影响。采用TG／DTA对凝胶的热分解历程进行了分析,以XRD分析了不同煅烧温度下所得产物的相组成,以TEM观察了不同条件下的纳米粉体的颗粒尺寸及其分散状况。并将制备出的钙钛矿粉体压成电极,进行放电分析,以检验其催化活性。得出了采用溶胶-凝胶法合成钙钛矿型纳米氧化物La1-xSrxMnO3的优化反应条件。     

在铜合金上获得Ni-Fe合金镀层的电镀工艺研究

研究了适用于连铸机结晶器的Ｎｉ－Ｆｅ合金单层电镀技术的工艺及配方，以及镀层的硬度、耐磨耗性能、耐热性能及耐热冲击性能，结果表明。在本工艺条件下获得的含３％～５％Ｆｅ的Ｎｉ－Ｆｅ合金镀层。其硬度、耐磨耗性能、耐热性能及耐热冲击性能最佳。耐磨性比原来提高两倍。     

天然金刚石与合成金刚石的耐磨性比较及磨损的各向异性

利用软压头技术，研究了室温条件下天然金刚石和ＤｅＢｅｅｒｓ公司生产的大工合成金刚石的摩擦磨损行为。结果表明，磨损时，金刚石对摩擦方向敏感。存在有磨损的各向异生。「１１０」方向的耐磨性是「１００」方向的二倍。天然金刚石的耐磨性比人工合成金刚石高，这种现象是由于氮原子在金刚石晶格中位置不同的结果。     

点接触加载条件下金刚石薄膜的破坏行为

本文利用软压头技术,探讨了金刚石薄膜材料在点接触加载条件下的破坏形式以及外加应力与薄膜破坏之间的关系.