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Fe(OH)2悬浮液在EDTA作用下氧气氧化生成δ-FeOOH的机理研究 总被引:1,自引:0,他引:1
At room temperature and in the presence of trace EDTA, the formation of δ-FeOOH was studied by the rapid oxidation of Fe(OH)2 suspension with O2. The structural and morphological changes were characterized by various techniques such as XRD, FTIR and TEM. γ-FeOOH and (δ-FeOOH) formed simutaneously in the early period of oxidation. But as the rate of mass transfer was in equilibrium, trace (γ-FeOOH) vanished gradually. Accordingly, pure phase δ-FeOOH was obtained. At the same time, critical amount ratio K of EDTA to Fe2+ was verified. The experiments show that the reactivity, rate of the oxidizing agent and pH of the initial medium were important factors for the formation of pure phase (δ-FeOOH). Under the auxiliary effect of EDTA, the reactivity of O2 was nearly improved to that of H2O2. And the process of the oxidation that Fe(OH)2 suspension was oxidized by O2 under that condition was discussed. 相似文献
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合成了Pr、Yb的苯磺酰化甘氨酸配合物,观测了它们对水稻幼苗初期生长的影响以及对油菜种子萌发和幼苗生长情况。结果表明,适宜含量的该类配合物可促进种子萌发的启动,并对种苗根系和幼苗的生长有明显促进作用,并以2.5×10-6~5.0×10-6含量范围效果最佳。 相似文献
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Fe(OH)2悬浮液在EDTA作用下氧气氧化生成δ-FeOOH的机理研究 总被引:2,自引:0,他引:2
At room temperature and in the presence of trace EDTA, the formation of δ-FeOOH was studied by the rapid oxidation of Fe(OH)2 suspension with O2. The structural and morphological changes were characterized by various techniques such as XRD, FTIR and TEM. γ-FeOOH and δ-FeOOH formed simutaneously in the early period of oxidation. But as the rate of mass transfer was in equilibrium, trace γ-FeOOH vanished gradually. Accordingly, pure phase δ-FeOOH was obtained. At the same time, critical amount ratio K of EDTA to Fe^2 was verified. The experiments show that the reactivity, rate of the oxidizing agent and pH of the initial medium were important factors for the formation of pure phase δ-FeOOH. Under the auxiliary effect of EDTA, the reactivity of O2 was nearly improved to that of H2O2. And the process of the oxidation that Fe(OH)2 suspension was oxidized by O2 under that condition was discussed. 相似文献
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本文利用微电极技术研究了Eu(NO_3)_3·DB—18—C—6配合物在乙腈介质中的电化学性质,并由方波伏安(SWV)实验数据,经单纯形曲线拟合方法计算出了其电还原过程的部分动力学参数n、α、k~0、D、E_0~′等值。实验结果表明,Eu(NO_3)_3·DB—18—C—6配合物为主客体配合物,它在乙腈中的电还原经过了二个单电子电化学步骤。 相似文献
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利用电化学交流阻抗的方法研究了苯胺与聚硫橡胶干态复合膜内的电荷传输问题,通过非线性最小二乘法拟合,得出了聚苯胺(PAn)与聚硫橡胶不同配比原等效电路,并计算出其电荷的散系数和异相电子传递反应的交换电流。实验结果表明,干态膜中PAn含量的增加,不但可以提高复合膜的导电性,而且可以提高反应活性。 相似文献
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苯胺与聚硫橡胶原位电化学复合的性质 总被引:1,自引:1,他引:0
讨论了苯胺与聚硫橡胶电聚合时的相互作用,结果表明,聚苯胺与聚硫橡胶之间具有互相催化作用,且随着复合膜厚度的增加催化活性增高;同时还可提高聚硫橡胶电氧化还原的可逆性 相似文献
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以cis-[Ru(dpq)2Cl2]·2H2O(dpq=二吡啶[3,2-d:2',3'-f]二氮萘)为原料与5,5'-二(1-(三乙胺)甲基)-2,2'-联吡啶阳离子(L)合成钌(Ⅱ)配合物[Ru(dpq)2L](PF6)4,并研究了该配合物与G-四链体DNA的作用:FRET实验表明,配合物对人端粒DNAh-telo具有选择性,其作用能力要强于同癌基因启动子区域的四链DNA,如c-myc和bcl2;CD光谱表明,在Na+和K+都不存在的情况下,配合物能诱导h-telo形成平行结构;此外,紫外和发射光谱都显示,配合物在K+溶液中与h-telo的作用力要大于在Na+溶液中的。 相似文献
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以TiCl4为原料,采用胶溶法制备出了具有金红石结构的纳米针状TiO2粉体,该针形晶体长约180nm,直径约30nm,讨论了反应时间、反应温度对TiO2粒子形貌的影响,并采用TEM和XRD等方法对晶体进行了表征。 相似文献