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The title complex Cu[C5H3N(CCH3=N-C6H5)2]2(PF6)2 has been synthesized by reaction of Schiff base C5H3N(CCH3=N-C6H5)2 and cupric sulfate in toluene solution. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 1041.85. The crystal structure belongs to triclinic system with space group P1 and cell parameters: a=12.6470(10)?, b=14.123(2)?, c=15.613(2)?;α=66.150(10)°,β=79.470(10)°,γ=78.290(10)°, V=2481.6(5)?3, Z=2, Dc=1.394Mg·m-3 and F(000)=1064. The final R[I >2σ(I)]:R1=0.0668, wR2=0.1927; R(all data): R1=0.1133, wR2=0.2357. The Cu(Ⅱ) was coordinated by six nitrogen, at the same time the Cu(Ⅱ) formed a distorted octahedron, besides the angles and planes of this compound were discussed . The result of kinetics of the thermal decomposition indicated that the first step of it is 2 series chemical reactions, the function of machanism is f(a)=(1-a)2, and the activation energy is 144.64E/kJ. CCDC: 180872. 相似文献
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希夫碱2,6—双(1—苯基亚氨基甲基)吡啶的合成及晶?… 总被引:1,自引:0,他引:1
通过2,6-二乙酰吡啶与苯胺在甲苯中胺1:2的物质的量比进行反应,首次合成了标题化合物,并获得了其单晶,测定了单晶的结构,用热分析对其进行了表征。 相似文献
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希夫碱2,6-双(1-苯基亚氨基甲基)吡啶的合成及晶体结构 总被引:2,自引:2,他引:0
通过2,6-二乙酰吡啶与苯胺在甲苯中按1:2的物质的量比进行反应,首次合成了标题化合物,并获得其单晶,测定了单晶的结构,用热分析对其进行了表征. 相似文献
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以二甲亚砜/丙酮-二甲亚砜为反应介质,合成了Cu(Ⅱ),Fe(Ⅲ)的L-从氨酸,吡啶-2,6-二甲酸三元配合物,并用化学分析,元素分析,电导率,热分析和红外光谱对其进行了表征,确定了化合物的组成分别是「FeC12H13N2O8」Cl2,「CuC12H14N2O8」Cl2。同时,对其溶解性进行了研究。 相似文献
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