新鲜温郁金中姜黄与莪朮挥发性成分的顶空-气相色谱-质谱联用对比分析

本文用顶空-气相色谱-质谱的方法测定了温郁金的不同药用部位：莪朮与姜黄，有60多种挥发性化合物被检测到，通过NIST谱库检索结合保留指数数据分别定性了其中51和48种挥发性成分。实验中用β-榄香烯作为外标进行相对定量分析，比较了不同产期莪术中挥发油含量的变化，从而有利于最佳采收时间的确定。对于同产期的温郁金的不同药用部位：莪术和姜黄，本文也进行了比较，它们的有效成分相似，但是含量有差别。用H/D交换的方法进一步确定了含活泼H的化合物，g-萜品烯在烯丙位也发现了很明显的H/D交换，通过裂解途径的分析本文确定了H/D交换的位置。这种方法不仅可以用于含挥发油成分的药用植物有效成分的定性，还可以用于它们有效成分的相对定量。     

平阳岭根峡谷植物区系性质及资源利用研究

平阳岭根峡谷的植物资源丰富，有种子植物428种，隶属于105科299属．对植物的区系性质进行了研究，同时对野生植物资源的开发利用与保护进行了探讨.     

温州地区外来入侵植物的种类组成及区系特点

温州地区现有外来入侵植物64种,隶属于28科、52属.菊科、苋科和禾本科构成了温州地区外来入侵植物的主体,其中以菊科为最多,共有17种,占总种数的26.56%.外来入侵植物中,有51种来自美洲,占总种数的79.69%,说明来自美洲的植物更容易入侵温州.外来入侵植物中,草本植物共有59种,占总种数的92.19%,说明草本植物更具有入侵性,木本植物的入侵性相对较小.外来入侵植物中,热带成分占70.28%.     

Comparative Analysis of the Volatile Components in the Fresh Roots and Rhizomes of Curcuma wenyujin by Static Headspace Gas Chromatography Mass Spectrometry

Static headspace GC-MS method coupled with H/D exchange was firstly developed to determine and identifythe volatile components in the fresh root and rhizome of Curcuma wenyujin.The TIC chromatograms of 3 batchesof fresh roots harvested at different time showed significant difference in the volatile components:the constitutionwas the same but the content of them was different.More than 60 volatile components in fresh roots(Root of C.wenyujin)and rhizomes(Rhizome of C.wenyujin)of C.wenyujin were detected,of which 51 and 48 volatile com-ponents were identified respectively.The fresh roots and rhizomes of C.wenyujin were found to have the similarvolatile components.The contents of these components were calibrated by the response of β-elemene.In addition,the principal active component,β-elemene,was further confirmed and relatively quantified by its standard.γ-terpinene showed obvious allylic hydrogen/deuterium exchange using deuterium oxide which gave a new methodto identify some compounds containing allylic hydrogen.At the same time,the active hydrogen compounds werealso further confirmed.The results show that HS-GC-MS method is a fast,simple and efficient way for the analysisof volatile components from medical plants.