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利用M-2000UI型宽光谱可变入射角椭偏仪研究十六氟铜酞菁(F16CuPc)和铜酞菁(CuPc)薄膜的光学性质. 在248~1 650 nm使用逐点拟合的方法对测得椭偏光谱进行分析, 获得两种薄膜的折射率、消光系数、复介电常数和吸收系数. 讨论了外环氟取代基对酞菁光学性质的影响, 结果表明, 共轭酞菁大环上的外围取代基对薄膜的响应波长和非正常色散影响较大. 分析了两种酞菁的电子结构及吸收谱成因, 并由吸收边外推得到两种材料的光学禁带宽度(Eg). 相似文献
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铒酞菁的合成及光学性质研究 总被引:1,自引:1,他引:0
使用溶剂热法合成了三种具有不同分子对称性的三明治结构的铒酞菁,并用时间飞行质谱、元素分析、紫外-可见-近红外吸收谱和近红外光致发光谱对它们的结构和近红外光谱特性进行了表征.在酞菁铒[Er(Pc)2]的吸收谱中,可以明显看到其中位于318 nm附近的吸收带为B带,对应着酞菁配体的π-π*电子跃迁,位于667nm附近的吸收带为Q带,也对应着酞菁配体的π-π*电子跃迁,1528 nm附近有一个强度非常弱的吸收,对应着三价铒离子4I15/2-4I13/2跃迁的吸收.在二笨甲酰基甲烷酞菁铒[Er(Pc)(DBM)]的吸收谱中,与Er(Pc)2的吸收谱类似,只是Q带红移了11nm,达到672nm,B带红移了24nm,达到342nm.值得注意的是:随着配合物分子结构不对称性的增加1530nm附近的发射增强.这被认为是由于三价铒离子所处的配体场的不对称性的增加导致原本宁称禁阻的4f-4f跃迁几率增加,从而使1530nm附近发射增强.1530nm处的发光对应着三价铒离子4I15/2-4I13/2跃迁. 相似文献
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We demonstrate the near-infrared (NIR) organic light-emitting devices (OLEDs) based on copper hexade-cafluorophthalocyanine (CuPcF16) doped into 2,2,2”-(1,3,5-benzenetriyl)tris-[1-phenyl-1H-benzimidazole] (TPBI). The device structure is ITO/ NPB/ TPBI:CuPcF16/BCP/Alq3/Al. Room-temperature electro- luminescence is observed at about 1106 nm due to transitions from the first excited triplet state to the ground state (T1-S0) of CuPcF16. The result indicates that FSrster and Dexter energy transfers play a minor role in these devices, while the direct charge trapping is the dominant mechanism. The absorption spectra of CuPeF16 solution in pyridine and vacuum sublimed films on quartz have also been investigated. 相似文献
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设计了MV级小型重复频率Marx发生器,简化了发生器充放电回路,减小了能量损失;分析了隔离电感变化时对发生器输出脉冲电压波形的影响,减小了隔离电感体积,提高了隔离有效性;优化了开关腔体结构,实现了间距连续可调,且受外围结构的变化或振动影响,13个开关间隙置于同一垂线上,火花放电时产生的紫外线或射线相互照射,加速了开关导通,减小了Marx发生器输出电压抖动。塑壳电容降压使用,提高了发生器的可靠性;通过Pspice模拟和三维静电场分析,实现了发生器小型化,整个Marx发生器放置在一个密封纯净SF6气体的金属圆筒内,体积小于0.25m3。优化设计和实验研究,发生器在高阻负载上输出峰值1.02MV、前沿约30ns的高压脉冲,发生器储能290J,电压幅度抖动约10%,前沿抖动小于10ns,可实现重复频率20Hz稳定运行。 相似文献
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Near-Infrared Emission from Organic Light-Emitting Diodes Based on Copper Phthalocyanine with a Periodically Arranged Alq3:CuPc/DCM Multilayer Structure
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We demonstrate near-infrared organic light-emitting devices with a periodically arranged tris(8-quinolinolato)aluminum (Alq3):copper phthalocyanine (CuPc)/4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminost-yry)-4H-pyran (DCM) multilayer structure. DCM and Alq3 doped with CuPc were periodically deposited. Room-temperature electrophosphorescence was observed at about 1.1 μm due to transitions from the first excited triplet state to the singlet ground state (T1 - S0) of CuPc. In this device, we utilize the overlap between the Q band πr - π^* at about 625nm of the absorption spectra of CuPc and the PL spectra of the DCM. The near-infrared emission intensity of the CuPc-doped Alq3 device with DCM increases about 2.5 times larger than that of the device without DCM. We attribute the efficiency enhancement to the better overlap between the PL spectra of DCM and the absorption spectra of CuPc. 相似文献
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