Effects of barium on the nonlinear electrical characteristics and dielectric properties of SnO2-based varistors

The effects of barium on electrical and dielectric properties of the SnO_2·Co_2O_3·Ta_2O_5 varistor system sintered at 1250℃ for 60min were investigated. It is found that barium significantly improves the nonlinear properties. The breakdown electrical field increases from 378.0 to 2834.5V/mm, relative dielectric constant (at 1kHz) falls from 1206 to 161 and the resistivity (at 1kHz) rises from 60.3 to 1146.5kΩ·cm with an increase of BaCO_3 concentration from 0mol% to 1.00mol%. The sample with 1.00mol% barium has the best nonlinear electrical property and the highest nonlinear coefficient (α=29.2). A modified defect barrier model is introduced to illustrate the grain-boundary barrier formation of barium-doped SnO_{2}-based varistors.     

Phase Transition and High Piezoactivity of Sb Doped （Na0.53K0.435Li0.035）Nb0.94Ta0.06 O3 Lead-Free Ceramics

Lead-free piezoelectric ceramics with the composition of （Na0.53K0.435Li0.035）Nb0.94Ta0.06 O3 （NKLNST） axe synthesized by a conventional solid-state sintering process. An MPB-like region between orthorhombic and pseudocubic phases is found in this system. The density, piezoelectric and dielectric properties axe enhanced greatly in this region. A composition （Na0.53K0.435Li0.035）（Nb0.94Ta0.06）O3 is found to have excellent electrical properties： d33 = 320pC/N, kp= 49% and kt =43%, as well as relatively low loss, tan δ=4.2%, and high relative density higher than 96%, which indicate that this ceramics is a promising lead-free piezoceramics replacing for lead zirconate titanate.     

在黑龙江省珠算协会建会三十周年暨2009年工作总结表彰大会上的讲话

同志们:今年是我省珠算协会建会30周年,今天我们召开纪念表彰大会。首先我代表省财政厅党组、代表继纯厅长,对我省珠算协会成立30周年表示热烈的祝贺!向全省各级珠算协会、全体珠协工作者、珠心算教育工作者致以崇高     

钛酸铋钠系铁电体的相变研究

研究了(Na0.5Bi0.5)TiO3,(Na0.5Bi0.5)(1-x)BaxTiO3和(Na0.5Bi0.5)(1-x)SrxTiO3陶瓷的介电温谱,确认了该系列材料在520℃以下的高、低温两种介电反常和存在于这一温度区间的巨大热滞现象.发现该类材料只存在对应于低温介电反常的介电损耗峰,而对于高温介电峰则无对应的损耗峰.同时,常温时材料的结构特征对于其介电温谱的特征影响较小,但施加偏置场却可明显改变材料的介电温谱特征:1)可使得材料的热滞现象几乎消失;2)适当偏置场下材料升降温介电曲线可与零偏场下介电 关键词： 钛酸铋钠 热滞 相变 极性微区     

纯金属电阻率的简化模型

提出了纯金属电阻率的两个简化模型：一个统计模型，一个电子一声子耦合模型。由统计模型可得出：纯金属电阻率与声子浓度及声子平均动量的平方成正比。由电子－声子耦合模型得出：电子的散射几率不仅正比于声子数，而且正比于电子－声子的耦合强度。由这两个模型皆能得出纯金属电阻率在高温时与温度Ｔ成正比，低温时与Ｔ５成正比的结果。由电阻率—温度曲线的比较表明，两模型相当吻合。     

立方晶系两套晶列,晶面指数的转换

晶列和昌面的指数与坐标系的选择有关.以布喇菲晶胞基矢为坐标系时,晶面密勒指数记为(hkl)[1],立方晶系的晶列指数记为[hkl];以初基原胞基矢为坐标系时,晶面指数记为(h1h2h3),而晶列指数记为[l1l2l3][2].坐标系不同,同一晶面族的晶面指数和密勒指数一股都不相同.晶列的情况也是如此.本文仅就体心立方和面心立方点阵的两套指数的转换关系加以讨论. 体心立方和面心立方的晶胞基矢a,b,c与初基原胞基矢a1,a2和a3的习惯选取方法如图1所示.山图1不难求出两套丛矢间的转换关系. 对于体心立方点阵, 对于面心立方点阵, 倒格基矢的转换也有类似的结果,…     

《固体物理教程》一书的特色

新编《固体物理教程》的第一个特色是只论述基础理论，不包括专业内容、除了教材体系作了改革外，对教学内容作了革亲提本书的第二大特点，对某些固体物理问题的处理方法和物理模型进行了改进是本收的又一特点。     

（Na0.52K0.44Li0.04）Nb0.9-xSbxTa0.1O3 Lead-Free Piezoelectric Ceramics with High Performance and High Curie Temperature

（Na0.52K0.44Li0.04）Nb0.9-x Sbx Ta0.1O3 lead-free piezoelectric ceramics are prepared by a solid-state reaction method. With increasing Sb content, the transition temperature from orthorhombic to tetragonal polymorphic phase decreased. A composition （Na0.52K0.44Li0.04）Nb0.863Sb0.037Ta0.1O3 is found to possess excellent piezo- electric and electromechanical performances （d33 = 306pC/N, kp =48%, and kt=50%）, and high Curie temperature （Tc = 320 ℃）. These results indicate that （Na0.52K0.44Li0.04）Nb0.863Sb0.037 Ta0.1O3 is a promising lead-free piezoceramics replacement for lead zirconate titanate.     

Phase Transition and High Piezoactivity of Sr Doped Lead-Free （Na0.53K0.422Li0.048） （Nb0.89Sb0.06Wa0.05）O3 Ceramics

Lead-free piezoelectric ceramics （Na0.53K0.422Li0.048 ） （Nb0.89Sb0.06 Ta0.05 ）03 （NKLNST） ＋ x tool SrCO3 are prepared by conventional solid state sintering method. The specimens with pure perovskite structure show tetragonal phase at x 〈 0.01, and become pseudo-cubic phase at x 〉 0.02. A lattice parameter discontinuity is found in the specimens with 0.004 〈 x 〈 0.0075, along with a great improvement in piezoactivity. The 0.004 mol SrCO3 added NKLNST ceramics possesses outstanding performances of kp = 0.53, kt = 0.26, and d33=309 pC/N. Moreover, the Sr^2＋ modification inhibits the gra/n growth, decreases the Curie temperature, and induces a diffuse phase transition.     

Effects of Li Substitution and Sintering Temperature on Properties of Bi0.5（Na,K）0.5TiO3 Lead-Free Piezoelectric Ceramics

Bi0.5 （Na0.72K0.28- x Lix ）0.5 TiO3 （BNKLT- 100x） lead-free piezoelectric ceramics are synthesized by conventional solid state sintering techniques. The dielectric and piezoelectric properties of the BNKLT-100x ceramics as a function of Li content are systematically investigated. It is found that not only Li content but also the sintering temperature has a strong effect on the piezoelectric properties of BNKLT. The piezoelectric constant d33 Of BNKLT varies from 120 to 252pC/N in the Li content range from 0.03 to 0.16. In the sintering temperature range from 1080 to 1130℃, the d33 value of BNKLT-6 changes from 200pC/N to 252pC/N. The BNKLT-6 sample sintered at 1100℃ has the highest piezoelectric constant d33 of 252pC/N, with the electromechanical coupling factors kp of 0.32 and kt of 0.44.