Phase transition and near-zero thermal expansion of Zr_(0.5)Hf_(0.5)VPO_7

The Zr_(0.5)Hf_(0.5)VPO_7 is successfully synthesized by the solid-state method with near-zero thermal expansion. Powder x-ray diffraction(XRD), Raman spectroscopy, thermal dilatometry, and scanning electron microscopy(SEM) are used to investigate the structure, the phase transition, and the coefficient of thermal expansion(CTE) of Zr_(0.5)Hf_(0.5)VPO_7. The investigation results show that the samples are of the single cubic type with a space group of Pa3ˉ at room temperature(RT).It can be inferred that the superstructure is transformed from the 3 × 3 × 3 superstructure to the 1 × 1 × 1 ideal crystal in a temperature range between 310 K and 323 K. The CTE is measured by a dilatometer to be 0.59 × 10~(-6) K~(-1)(310 K–673 K). The values of intrinsic(XRD) and extrinsic(dilatometric) thermal expansion are both near zero. The results show that Zr_(0.5)Hf_(0.5)VPO_7 has near-zero thermal expansion behavior over a wide temperature range.     

Determination of 12 additives in beverages by evaporation-assisted dispersive liquid-liquid microextraction based on the solidification of floating organic droplets combined with liquid chromatographyEI北大核心CSCD

An analytical method for the simultaneous determination of 12 additives in beverages was developed using evaporation-assisted dispersive liquid-liquid microextraction based on the solidification of floating organic droplets EVA-DLLME-SFOcombined with high performance liquid chromatography HPLC. The samples were extracted twice with 70%V/Vmethanol aqueous solution and extracted by EVA-DLLME-SFO method after the combination of the extractsand finally determined by HPLC. Extraction parameterssuch as types and amounts of extractantevaporant and heating agentthe concentration of saltand the extraction time were optimized. Under the optimized conditionsthere were good relationships in the ange of 0.25-50 μµg/mL with the limits of detection of 1.5 to 13.6 mg/kg and limits of quantification of 5.2 to 45.3 mg/kg. The recoveries at three spiked levels1025 and 50 mg/kgwere 76.8% to 101.2% with the relative standard deviations of 0.11% to 4.7%. The method can be used for rapid detection of 12 additives in beverages. © 2022, Youke Publishing Co.,Ltd. All rights reserved.     

基于芬顿反应和硫磺素T构建免标记荧光传感器用于葡萄糖的检测

基于芬顿反应和硫磺素T(ThT)构建新奇的免标记荧光传感器用于葡萄糖的检测。当无葡萄糖存在时,ThT诱导富G-DNA探针形成G-四链体/ThT复合物,ThT的荧光强度显著增强;当葡萄糖存在时,葡萄糖氧化酶催化葡萄糖产生H2 O2,在Fe^2+催化的芬顿反应作用下,H2 O2转化为羟基自由基(·OH),·OH引发DNA的氧化损伤导致富G-DNA探针裂解为短寡核苷酸片段而丧失形成G-四链体/ThT的能力,ThT的荧光强度显著降低,从而实现对葡萄糖的检测。在优化的检测条件下,G-四链体/ThT荧光强度变化和葡萄糖浓度在0.5~45μmol/L的范围内呈现较好的线性关系(R^2=0.99268),检出限为0.1μmol/L。利用本法对葡萄糖加标的血液样品进行分析,葡萄糖的回收率为90.7%~118.3%,相对标准偏差为1.7%~5.8%,方法可用于血糖检测。     

膜载体酶标记dip-stick快速检测西维因的痕量残留

利用直接竞争酶联免疫吸附分析技术研发了一种快速、灵敏的膜载体酶标记dip-stick农残西维因检测方法。该方法以带正电尼龙膜(Millipore)为固相载体,将西维因抗体包被于膜上,包被有抗体的膜插入含有西维因和西维因酶标抗原的混合液中竞争反应10 min后直接目视判断分析结果。该方法的整个检测过程只需15 min,对西维因的检出限可达到10μg.L-1,且稳定性较好。通过与高效液相色谱法(HPLC)比较,验证了该检测方法的有效性,可作为品质控制和快速定性检测的一种有效工具。     

系统还原算法分析

介绍了系统还原算法的设计思想,深入分析了转存缓冲原理,创建了系统还原算法的数据结构,详细描述了系统还原与系统更新的算法工作流程,讨论了未来系统还原的研究方向。     

植物检疫学多媒体教学初探

植物检疫学是植物保护专业的重要专业基础课,课程内容多且覆盖面广,涉及微生物、昆虫及杂草的形态特征等。多媒体教学有利于提高课程的教学效果。因此,就多媒体教学在植物检疫学中的优势、缺点及解决方法和多媒体课件的制作进行了探讨。     

工科物理教学中创新思维的培养策略

随着工科物理教学改革的不断深入,如何在教学过程中培养学生的创新思维能力,已经成为教育工作者广泛关注的课题。作为起主导作用的教师应该高度重视学生的主体地位,树立创新教育的理念,建立合理知识结构,充分利用现代信息技术,设计教学情景,对学生进行积极、恰当的评价,培养适应时代发展需要,具有创新思维、创新观念和创新能力的复合型人才。     

SMW工法桩在地下工程中的应用

SMW工法桩,即是在水泥桩中插入大型H型钢,由型钢承受土体侧压力,而水泥土则具有良好的抗渗性能,由于SMW工法桩具有以上双重作用,故广泛应用于地下工程中。     

Open critical area model and extraction algorithm based on the net flow-axis

In the integrated circuit manufacturing process, the critical area extraction is a bottleneck to the layout optimization and the integrated circuit yield estimation. In this paper, we study the problem that the missing material defects may result in the open circuit fault. Combining the mathematical morphology theory, we present a new computation model and a novel extraction algorithm for the open critical area based on the net flow-axis. Firstly, we find the net flow-axis for different nets. Then, the net flow-edges based on the net flow-axis are obtained. Finally, we can extract the open critical area by the mathematical morphology. Compared with the existing methods, the nets need not to divide into the horizontal nets and the vertical nets, and the experimental results show that our model and algorithm can accurately extract the size of the open critical area and obtain the location information of the open circuit critical area.     

转型背景下地方高校光电类专业实践教学体系构建

在应用技术型人才培养中, 实践教学体系直接决定了应用型人才培养的质量和水平, 在地方高校的转 型背景下, 分析了光电信息科学与工程专业实践教学体系的构建原则, 构建了“ 五大体系、 三大层次、 七大模块、 三大 平台”的层次化、 模块化光电信息科学与工程专业实践教学体系, 明确了实践教学体系的中各环节的目标与内容, 进一步实现专业建设与行业标准的融合, 学历教育与岗位技能的对接