含缺失数据线性模型回归系数的约束EM算法

应用EM算法求含缺失数据的约束线性模型回归系数的极大似然估计,该回归系数满足线性不等式约束.我们提出M-步的优化算法,并针对正态模型讨论EM序列的收敛性,最后举例说明算法的应用.     

线性模型回归参数极大似然估计的约束EM算法

提出了非线性不等式约束下线性模型回归系数渐进极大似然估计的EM算法,利用极大似然估计的渐近正态性质,将EM算法的M-步转化为随机优化问题,给出了该随机优化问题的极限问题,即利用更易求解的极限问题的最优解来代替原优化问题的最优解,并证明了原优化问题的最优解是依概率收敛于极限问题的最优解.     

First-principle investigation on the thermodynamics of X_2N_2O(X = C,Si, Ge) compounds

The structures under different pressures, elastic properties, electronic structures and lattice vibrations of the X_2N_2O(X = C, Si, Ge) compounds are investigated by using the first-principle method. Based on the phonon density of state,the thermodynamic properties of the present compounds are studied under different pressures and at different temperatures. The structural parameters including the bond lengths and bond angles are in agreement with available experimental measurements and theoretical calculations. We employ the elastic theory to calculate the nine independent elastic constants(C_(ij)) and the derived elastic moduli(B, G, E, v). Results indicate that these X_2N_2O(X = C, Si, Ge) compounds are mechanically stable and show the brittle behaviors. The electronic properties of the present compounds are analyzed by using the band structure and density of states. The phonon dispersion calculations imply that the present compounds are dynamically stable. Based on the quasi-harmonic approximation, the calculations of the specific heat indicate that the temperature in a range of 0 K–1500 K and pressure in a range of 0 GPa–40 GPa have a large effect on the thermal quantities of Ge_2N_2O,compared with on those of the C_2N_2O and Si_2N_2O compounds.     

具有无穷边界值的二次非线性奇摄动边值问题的双边界层

研究了具有无穷边界值的二次非线性奇摄动边值问题的双边界层,利用边界层校正函数,构造其渐近解,并利用微分不等式理论,给出了一致有效渐近估计.最后给出算例验证了相关结论的正确性.