Urothermal Synthesis,Crystal Structure,and Luminescent Property of a New Zn(Ⅱ) Coordination Polymer Constructed from TerephthalicAcid and 5-Methyl-1H-tetrazole Ligands

A new luminescent Zn(II) compound, [Zn(pbdc)0.5(mtz)(DMPU)]n(1, H2pbdc = terephthalic acid, Hmtz = 5-methyl-1H-tetrazole, DMPU = N,N'-dimethylpropyleneurea), has been urothermally synthesized and characterized by elemental analysis, IR, X-ray powder diffraction(PXRD) and single-crystal X-ray diffraction. The title compound crystallizes in orthorhombic Pbca space group with a = 17.2649(5), b = 10.4680(3), c = 17.4457(7) ?, V = 3152.94(18) ?3, C12H17N6O3Zn, Mr = 358.71, Z = 8, Dc = 1.511 g/cm3, F(000) = 1480, μ = 1.579 mm-1, the final R = 0.0379 and wR = 0.0971 for 2785 observed reflections(I 2?(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a 2D undulated layer with a 3-connected hcb topology. Moreover, the luminescent properties of 1 have also been investigated in the solid-state at room temperature.     

油菜蜀杂1号F_1(8208×S45A)及其亲本的核酸比较

用一种简便的方法,提取并纯化杂交油菜蜀杂1号F_1(8208×S45A)及其亲本的核酸,并比较它们的核酸含量及DNA的(G+C)％.结果表明,F_1(8208×S45A)的杂种优势与DNA和RNA的含量的增加有关,也与DNA的碱基组成变化有关.     

多元热流体在井筒中的流动与传热规律

建立高温烟气与水的热交换模型以及多元热流体在井筒内流动传热的温度场、压力场计算模型,计算含过热蒸汽和两相流状态的多元热流体在不同井深时的温度、压力以及其他参数。结果表明:随着井筒深度的增加,多元热流体的温度、压力均有所降低,并在某一深度多元热流体中水蒸气开始凝结,进入两相流状态,与纯蒸汽注入相比,其热损失量小,干度下降慢,在井底干度较大;井口注入温度越高、压力越小、流量越大,多元热流体的压降、温降幅度越大,热损失量越小;随着注入温度的降低,环空介质导热系数和注汽流量的增大,多元热流体干度的变化越早或过热度降幅越大,而注入压力对干度的影响有一个最优点,此时蒸汽在井底干度最大。