氯磺化聚乙烯结构和性能研究Ⅰ.氯磺化反应及其对晶体结构的影响

氯磺化聚乙烯水解后是一种性能特异的离子交换膜。本文研究了低密度及高密度聚乙烯中空纤维氯磺化反应时间与交换容量之间的关系,并用红外光谱及广角X射线衍射法测定了氯磺化反应对聚乙烯晶体结构的影响。结果表明,氯磺化反应主要发生在聚乙烯的非晶区,最大交换容量及反应速度均与非晶区含量有关。反应对晶粒表面也有一定程度的侵蚀作用,随着交换容量的增加,结晶度下降,晶粒度减小。低密度及高密度聚乙烯的变化趋势相似,但前者比后者变化更显著。     

第二届全国膜和膜过程学术报告会在杭州举行

由国家海洋局杭州水处理中心玉办的第二届全国膜和膜过程学术报告会于1996年11月6-10日在杭州举行。这是继1991年大连会议后我国膜科学与技术领域的又一次重要的学术活动。来自全国60多个科研、高等院校、生产应用单位的140多位代表参加了这次会议。他们当中既有长期从事膜研究的老专家,也有一批年轻的后起之秀。会议遴选出的134篇论文涵盖了当今膜和膜过程的各领域,包括:反渗透,纳滤,超滤,微滤,气体分离,渗透汽化,无机膜及膜反应,膜蒸馏,电渗析及膜过程在各领域中的应用。大会分组作了报告交流并进行了热烈讨论。报告内容基本展示了“八五”期间我国膜技术在膜材料、基础研究、应用开发及产业化上所取得导的进展。会议安排了六个人会报告:①液体分离膜进展(高从谐院士);②气体分离膜的研究与应用近况(徐仁贤教授);③新膜及膜过程的研究现状及发展动向(陈翠仙教授);④膜技术的新进展(徐纪平教授);⑤渗透汽化膜与过程研究的现状(陈观文教授);⑥微滤、超滤过程中的膜污染与清洗(刘忠洲教授)。     

壳聚糖·聚丙烯酸配合物半互穿聚合物网络膜及其对pH和离子的刺激响应

壳聚糖·聚丙烯酸配合物半互穿聚合物网络膜及其对ｐＨ和离子的刺激响应李文俊王汉夫卢玉华汪志亮钟伟（复旦大学高分子科学系聚合物分子工程开放实验室上海２００４３３）关键词高分子间配合物，互穿聚合物网络（ＩＰＮ），水凝胶，壳聚糖，刺激响应敏感性水凝胶是一种...     

壳聚糖-丝心蛋白合金膜的研究(Ⅱ)──半互穿聚合物网络型膜对pH和离子的敏感性

研究了壳聚糖-丝心蛋白半互穿聚合物网络型膜对pH值和离子的敏感性,发现该膜在pH<3.3时溶胀度剧烈增加;在pH=2时,是否出现溶胀极大值与膜组分的含量及交联剂的含量有关;膜在不同pH值溶液中可交替溶胀和收缩,且这种溶胀-收缩行为重复可逆。同时,该膜在不同离子溶液中的溶胀度亦不同;在相同离子强度的溶液中,此膜在3价离子中的溶胀度最大。     

富水砂卵石地层大直径 泥水盾构施工地表沉降规律

北京地下直径线工程位于富水砂卵石地层中,穿越诸多建（构）筑物。通过实际监测结果分析,总结掘进参数与地表沉降之间的规律及隧道周围重要建筑物的变形规律,经与类似工程比较后发现本工程在变形控制上有很大的成效。     

Urban rail departure capacity analysis based on a cellular automaton model

As an important traffic mode, urban rail transit is constantly developing toward improvement in service capacity and quality. When an urban rail transit system is evaluated in terms of its service capacity, the train departure capacity is an important index that can objectively reflect the service level of an urban rail transit facility. In light of the existing cellular automaton models, this paper proposes a suitable cellular automaton model to analyze the train departure capacity of urban rail transit under different variable factors and conditions. The established model can demonstrate the train operating processes by implementing the proposed sound rules, including the rules of train departure at the origin and intermediate stations, and the velocity and position updating rules. The properties of train traffic are analyzed via numerical experiments.The numerical results show that the departure capacity is negatively affected by the train departure control manner. In addition,(i) the real-time signal control can offer a higher train service frequency;(ii) the departure capacity gradually rises with the decrease in the line design speed to a limited extent;(iii) the departure capacity decreases with extension in the train length;(iv) the number of departed trains decreases as the train stop time increases;(v) the departure capacity is not affected by the section length. However, the longer the length, the worse the service quality of the urban rail transit line.The experiments show that the proposed cellular automaton model can be used to analyze the train service capacity of an urban rail transit system by performing quantitative analysis under various considered factors, conditions, and management modes.     

Conductivity and applications of Li-biphenyl-1,2-dimethoxyethane solution for lithium ion batteries

The total conductivity of Li-biphenyl-1,2-dimethoxyethane solution(Li_xBp(DME)_(9.65), Bp = biphenyl, DME = 1,2-dimethoxyethane, x = 0.25, 0.50, 1.00, 1.50, 2.00) is measured by impedance spectroscopy at a temperature range from 0℃ to 40℃. The Li_(1.50)Bp(DME)_(9.65) has the highest total conductivity 10.7 m S/cm. The conductivity obeys Arrhenius law with the activation energy(E_(a(x=0.50))= 0.014 eV, E_(a(x=1.00))= 0.046 eV). The ionic conductivity and electronic conductivity of Li_xBp(DME)_(9.65) solutions are investigated at 20℃ using the isothermal transient ionic current(ITIC) technique with an ion-blocking stainless steal electrode. The ionic conductivity and electronic conductivity of Li_(1.00)Bp(DME)_(9.65) are measured as 4.5 mS/cm and 6.6 mS/cm, respectively. The Li_(1.00)Bp(DME)_(9.65) solution is tested as an anode material of half liquid lithium ion battery due to the coexistence of electronic conductivity and ionic conductivity. The lithium iron phosphate(LFP) and Li_(1.5)Al_(0.5)Ti_(1.5)(PO_4)_3(LATP) are chosen to be the counter electrode and electrolyte, respectively. The assembled cell is cycled in the voltage range of 2.2 V-3.75 V at a current density of 50 mA/g. The potential of Li_(1.00)Bp(DME)_(9.65) solution is about 0.3 V vs. Li~+/Li, which indicates the solution has a strong reducibility. The Li_(1.00)Bp(DME)_(9.65) solution is also used to prelithiate the anode material with low first efficiency, such as hard carbon, soft carbon and silicon.     

Properties of train traffic flow in a moving block system

The development direction of railways is toward the improvement of capacity and service quality, where the service quality includes safety, schedule, high speed, and comfort. In light of the existing cellular automaton models, in this paper, we develop a model to analyze the mixed running processes of trains with maximal speeds of 500 km/h and 350 km/h respectively in the moving block system. In the proposed model, we establish some sound rules to control the running processes of a train, where the rules include the departure rules in the intermediate stations, the overtaking rules, and the conditions of speed limitation for a train stopping at a station or passing through a station. With the consideration of the mixed ratio and the distance between two adjacent stations, the properties of the train traffic flow (including capacity and average speed) are simulated. The numerical results show that the interactions among different trains will affect the capacity, and a proper increase of the spatial distance between two adjacent stations can enhance the capacity and the average speed under the moving block.