HILIC-HPLC法检测三乙烯四胺铜的含量

建立了一种测定三乙烯四胺铜含量的高效液相色谱法.对HPLC法的色谱条件进行了优化：以Agilent ZORBAX RR HILIC Plus(4.6 mm×100 mm, 3.5μm)为色谱柱,以乙腈-水为流动相进行梯度洗脱,流速为1 mL/min,检测波长为260 nm,柱温为室温.结果表明,三乙烯四胺铜浓度在0.05～1.0 mg/mL范围内与峰面积的线性关系良好,线性方程为y=6×10⁶x-34901,相关系数r为0.999 2;平均加样回收率为99.0%,RSD为1.43%.此方法操作简单,结果准确,可作为三乙烯四胺铜的含量测定方法.     

Cryptanalysis of quantum broadcast communication and authentication protocol with a one-time pad

Chang et al.[Chin.Phys.623 010305(2014)]have proposed a quantum broadcast communication and authentication protocol.However,we find that an intercept-resend attack can be preformed successfully by a potential eavesdropper,who will be able to destroy the authentication function.Afterwards,he or she can acquire the secret transmitted message or even modify it while escaping detection,by implementing an efficient man-in-the-middle attack.Furthermore,we show a simple scheme to defend this attack,that is,applying non-reusable identity strings.