结晶化学基础理论在现代X射线单晶结构分析中的一些应用

研究化学物质分子结构的方法很多,而衍射法是其中主要的方法之一,它包括X射线衍射、中子衍射和电子衍射等。由于X射线容易得到,而且成本较低,因此、X射线衍射法是分     

Fabrication and Characterization of Ni Thin Films Using Direct-Current Magnetron Sputtering

Ni films are deposited by using ultra high vacuum dc magnetron sputtering onto silicon substrates at room temperature, and the high-quality and high-density films are prepared. The parameters, such as thickness, density and surface roughness, are obtained by using small-angle x-ray diffraction (XRD) analyses with the Marquardt gradient-expansion algorithm. The deposition rate is calculated and the Ni single layer can be fabricated precisely. Based on the fitting results, we can find that the surface roughness of the Ni films is about 0.7nm, the densities of Ni films are around 97% and the deposition rate is 0.26nm/s. The roughness of the surface is also characterized by using an atomic force microscope (AFM). The changing trend of the surface roughness in the simulation of XRD is in good agreement with the AFM measurement.     

关于用玻璃肋做龙骨的横明竖隐玻璃幕墙结构方法

框架玻璃幕墙是目前非常常见的一种结构型式,我结合多年的设计经验,自行研究出一种新型的幕墙框架结构型式横明竖隐玻璃幕墙结构,主龙骨为玻璃肋,横梁采用普通的明框横梁,这种结构的好处在于增加了幕墙的通透性,又能用于多层连续主龙骨连接的整体幕墙,同时由能够满足幕墙结构的各种性能要求,通过工程的实践证明,这种结构是安全可靠的.     

迎泽大桥改建工程钻孔灌注桩施工质量监理

本文论述了迎泽大桥改建工程钻孔灌注桩施工质量监理的作法。为复杂地质条件,工期紧张情况下钻孔灌注桩施工质量监理提供借鉴依据。     

一种同步转速状态测定方法及其实现

提出一种同步转速状态测定方法．基于该方法设计了采用霍尔传感器的单片机测量系统．实现了对双螺旋推进器的转速和瞬时相差的准确测量,解决了无法预报“碰撞”现象的难题     

低价钒化合物结构化学研究 Ⅰ. [VCL2·(THF)4]+[ZnCl3·THF]-的合成与晶体结构

The title compound has been synthesized under nitrogen atmosphere using V_2O_5 for the initiator by Schlenk techniques. It′s single crystal, which is very air and water-sensitive, was obtained and determined from three-dimensinal x-ray diffraction data collected by the four-circle diffractometer. The crystals are orth- orhombic with space group D_2~4-P_(212121) and unit cell constants a=0.909 nm, b=1.4909 nm, c=2.1635 nm and z=4. We derived first the positional parameters of V, Zn, Cland O atoms by direct method using SHELXTL program. The coordinates of other the non-hyleast-squares refinement for all atoms gave a final discrepency factor R=0.0945 and RW=0.0674.The result of structure analysis shows that the compound is composed of the octahedral cation [VCl_2·(THF)_4]~+ and the tetrahedral anion [ZnCl_3·THF]~-.The reaction mechanism was discussed. The title compound is reaction product of VCl_3 with ZnCl_2 in THF.     

集中供热的节能技术

从集中供热节能的必要性出发，论述了综合治理系统水力失调、合理配置供热水泵、系统变流量运行、多热源共网联合供热等几种节能措施的技术及特点。     

也谈民法在市场经济中的重要作用

首先指出了市场经湃在法律上的反映主要是民法，而民法则是发展、规范市场经济的基础性法律。其次阐述了民法在市场经湃中所处的基础地位，及其所起到的主导作用。     

渝东南民族地区城镇化浅析

加快城镇化进程对渝东南民族地区的经济发展具有举足轻重的影响．本文通过对渝东南民族地区城镇化发展现状及存在问题的分析，提出了一些相应的建议和措施．     

控制室内空调系统的防火排烟探讨

简述了控制室防火排烟的必要性和现在设计中存在的问题，提出轴流风机、空调和排烟兼用这两种可行的防火排烟系统，并对设计和施工运行管理中的注意事项进行了总结。