RADIATION CROSSLINKING OF BRANCHED POLY (VINYL ACETATE)

In the present work, radiation crosslinking of different branched poly (vinyl acetate) have beemstudied and the validity of the relationship between sol fraction and radiation dose: R(S+S~(1/2)=1/U_(1qo)+p′_o/q_oR~βto branched poly(vinyl acetate) have been assured.     

CALCULATING THE MOLECULAR INTERNAL ROTATING STERIC FACTOR OF POLYMERS BY THE RADIATION CROSSLINKING METHOD

In this paper, calculating the molecular internal rotating steric factor of polymers by the radiation crosslinking method is studied and a relationship between the molecular internal rotating steric factor (σ) and crosslinking parameter βis established~([1]) by taking account of the effect of polymer chain flexibility on βvalue, σvalue of polymer obtained by this method is in agreement with that given with other method.     

STRUCTURE EFFECTS ON THE SOL FRACTION-DOSE RELATIONSHIP IN RADIATION CROSSLINKING OF POLYMERS

The structure effects of polymers on the relationship between sol fraction and radiation dose arediscussed in detail. In consideration of the deviation of experimental results from Charlesby-Pin-ner's and Chen-Liu-Tang's expressions relating sol fraction to radiation dose, we introduced an ex-ponent βconcerned with the structure and property parameters of a polymer (glass transition tem-perature T_g and molecular internal rotating steric factor δ) and assumed that the fracture density isproportional to R~β(R is radiation dose). Thus, a general expression, formula (9), relating solfraction to radiation dose is derived. When β=1 andβ=0.5, this expression is reduced to the above-said two expressions. Us-ing this general expression, the experimental data of a number of polymers are treated. It is shownthat the expression is in good agreement with the experimental results, βvalue is in the range of 0. 5 to1.0.     

辐照温度对聚芳醚酮辐射交联行为的影响

<正> 可溶性含酚酞侧基聚芳醚酮(PEK-C)是一种新型的具有耐高温、耐水解、耐化学腐蚀、自润滑性能的工程塑料,它具有如下结构:     

PEO/PVAc共混体系辐射交联反应中溶胶分数与辐照剂量间的关系

In this paper, the relationship between T_m and composition of PEO/PVAc blend were studied and the Flory-Huggins parameter of the blend system were calculated. The experimental results show that this blend system is compatible and have only one glass transition temperature (T_g), so we can extend the relationship between sol fraction (S) and radiation dose (R) of linear polymer to the PEO/PVAc system. The Bb value of PEO/PVAc system were calculated, which is in good agreement with the experimental value.     

具有X-射线自显影功能的碘代聚氨酯栓塞剂材料的研究

设计合成四碘代双酚A(IBPA)作为扩链剂,以聚丁二酸丁二醇酯(PBS-OH)为软段、异佛尔酮二异氰酸酯(IPDI)和IBPA为硬段,通过偶联反应获得一种新型X-射线聚氨酯显影材料.红外光谱和核磁共振氢谱确定所合成碘代聚氨酯(I-PUs)的结构与组成,并用示差扫描量热法,热重分析,X-射线衍射仪和临床X-射线仪评价不同IBPA含量的碘代聚氨酯的热性能、结晶性和显影效果.结果表明,碘代扩链剂IBPA较高含量的引入对聚合物的热稳定性有一定的影响,并促使聚氨酯由结晶态向非晶态转变.引入IBPA对聚氨酯的显影效果有很好的促进增强作用,聚氨酯材料及微球均具有较好的X光显影效果.噻唑蓝比色法(MTT)评价细胞毒性证实制备的较高碘含量的聚氨酯材料均无细胞毒性,是一种很好的血管栓塞剂材料.     

N,N'-亚甲基双丙烯酸酰胺在~(60)Co-γ射线下的辐照效应

报道了 N ,N -亚甲基双丙烯酸酰胺 ( N ,N -MBAA)在 60 Co-γ射线下辐照效应 .对不同辐照条件下的双键含量变化进行了测定 .同时讨论了固态 N,N -MBAA和 N,N -MBAA水溶液经辐照后的结构的变化 .实验结果表明 ,固态 N,N -MBAA在较高温度下辐照易聚合 ,因此辐射敏化反应 PVA纤维应在常温下进行辐照 .     

城市多举措压采地下水技术措施探讨

在对城市多举措地下水压采方案编制原则进行简单阐述后，从城市水资源规划水平年可供水量和需水量预测角度出发，分析了城市水资源优化配置方案。最后，对城市多举措压采地下水的技术措施方案进行了认真分析研究。     

矩形截面型材三维拉弯成形的回弹预测

设计了用于三维拉弯成形的、可重构的柔性模具,并采用支持向量回归机和有限元模拟对柔性三维拉弯成形的回弹进行预测.使用有限元法分析了对回弹量影响较大的6个因素(包括材料参数、几何参数和工艺参数),以及它们对回弹的影响趋势.选用这6个参数设计有限元三维拉弯模拟实验,并用模拟结果训练和检验支持向量回归机回弹预测模型.通过与广泛应用的神经网络预测方法的预测值和有限元模拟试验结果的比较,检验该回弹预测模型的准确性.研究发现,该模型与神经网络相比具有更高的准确度,在试验中根据该模型预测的回弹量对模具型面进行相应的补偿,可以有效地减小回弹和形状偏差.     

煤矿综采液压支架立柱快速排液法

液压支架是现代大型自动化煤矿工作面所采用的主要支护设备。它在工作面为作业工人及采煤机、刮板输送机提供一个安全的工作空间。在我国煤矿企业,井下综采工作面普遍采用液压支架进行支护。在我国北方,井上露天存放的液压支架在防冻期前必须完成各立柱及千斤顶的排液工作,以防止液压设备被冻坏。液压支架立柱排液是一项耗时、费力、效率低下、非常危险的工作。煤矿综采液压支架立柱快速排液法是一项致力于打破传统立柱排液工艺,寻求更科学、更高效、更安全的立柱排液方法的探索性科技创新。希望对我国煤炭行业具有参考和推广价值。