二(三苯基膦)水杨酸铜(Ⅰ)乙醇溶剂配合物的晶体结构

0IntroductionThestudyofcopper?complexesisinvestigatedinmanylaboratories.Amongthereasonsforcarryingouttheinvestigationofsuchspeciesaretheirstructuralfeatures犤1犦,theusefulnessofcopper?compoundsinorganicsyntheses犤2犦andthewell-documentedimpor-tanceofcopper?centersattheactivesitesofanumberofprotein犤3犦.Concerningcopper?carboxy-latesafurtherinterestexists,stemmingfromtheiruseinhomogeheouscatalysedhydrogenation犤4犦.Thecopper?bis(triphenylphosphine)cationisasoft,butflexi-bleacceptorionthatcanacc…     

Synthesis, Structure and Biological Activities of Novel Triazole Compounds Containing N,N-Dialkyldithiocarbamate Moiety

Introduction As an important type of fungicides, triazole compounds are highly efficient, low poisonous and inward absorbent.1-3 At present, the studies on triazole derivatives are mainly concentrated on compounds with triazole as the only active group. The report of triazole compounds that contain both triazole group and other active group in a single molecule has rarely been found. Dialkyl-substituted dithiocarbamate salts have also shown interesting biological effects.4 N,N-Dialkyldithio-…     

基于风险理念的黄土滑坡调查与编图研究

滑坡风险管理在国外已成为缓减地质灾害损失的重要手段,我国(香港地区除外)在滑坡风险管理方面起步较晚,尚处于探索阶段,目前正在开展的地质灾害详细调查项目尚没有很好地采用国际上流行的风险管理的理念和技术方法。本文以国土资源大调查部署实施的延安市宝塔区地质灾害详细调查示范项目为例,借鉴国际滑坡和工程边坡联合技术委员会制订的《土地利用规划滑坡易发性、危险性、风险区划指南》^[1] 及相关最新文献^[2~7],剖析了《滑坡崩塌泥石流灾害详细调查规范》和地质灾害详细调查项目实施中存在的问题及其与风险管理之间的差距。认为我国目前开展的地质灾害详细调查总体上属于中比例尺,还没有达到详细比例尺; 调查精度包括了高精度、中精度和低精度3种精度层次。提出了基于GIS、DEM、RS、地面调查等技术方法的黄土滑坡调查与编图的工作思路和技术路线。从1 :5万滑坡调查与风险编图、1 :1万滑坡调查与风险编图、村镇及重要基础设施滑坡调查与风险评估、典型滑坡点风险调查与评估4个方面,总结了基于风险管理理念的延安市宝塔区黄土滑坡调查与风险编图实例,旨在为《滑坡崩塌泥石流灾害详细调查规范》的修编和地质灾害详细调查项目更好地实施提供借鉴。     

广告传播中的性别定型分析

刻板印象是人们对某个社会群体形成的一种概括而固定的看法。性别定型是刻板印象在社会角色方面的反映。广告传播中存在着根深蒂固的性别偏见,其中女性形象是基于传统男性中心文化对女性的一种规范。广告中社会性别意识的偏离和不公正的表达,通过心理暗示引导女性用广告隐喻的女性社会形象来塑造自己,同时也直接影响正在进行社会化的儿童社会性别意识的正确建立。     

氯化四硫脲合钯配合物Pd[(NH2)2CS]4Cl2的晶体结构

The title compound， Pd[(NH₂)₂CS]₄Cl₂， has been synthesized and structurally characterized. It crystallizes in orthorhombic， Pna2(1) space group ， with M_r=481.79(C₄H₁₆Cl₂N₈PdS₄)， a=12.943(3)， b=8.283(2)， c=15.148(3)?， V=1623.9(6)?³， Z=4. The Pd(Ⅱ) ion has an square-planar geometry， and is coordinated by four S atom donors from four thiourea molecules. The two Cl^- anions found in the apical position balance the charge. In the solid state， the title compound forms three dimensional network structures through hydrogen bonds. The inter-molecular hydrogen bonds connect the {Pd[(NH₂)₂CS]₄}²⁺ and chloride ion to contribute to the stability of the structure. CCDC： 193379.     

Synthesis and Crystal Structure of α-（1,2,4-Triazol-1H-yl）-ρ-chloro Acetophenone, [ClC6H4COCH2（C2H2N3）]

1 INTRODUCTION Triazole nuclei appear frequently in the struc- tures of various natural products and biologically active compounds, notably thiamine (vitamin B), penicillins, antibiotics such as micrococcin[1], and many metabolic products of fungi and primitive marine animals, including 2-(aminoalky)triazole-4- carboxylic acids[2]. Numerous triazole derivatives exhibit pharmacological activity[3], e.g., 4-amino-N- (triazole-2-yl)benzenesulfonamide is a commercial drug. We report herein …     

反式-4,4’-二（邻甲氧基苯乙烯基）联苯化合物的合成、结构及光物理性能

以Wittig-Homer反应合成了反式对称的4,4’-二(邻甲氧基苯乙烯基)联苯化合物, X射线衍射分析测定了化合物的晶体结构. 测定了其在不同溶剂中的线性吸收光谱、荧光发射光谱及荧光量子产率. 飞秒激光做光源研究了化合物的双光子光物理性能. 测试结果表明: 该化合物在蓝光波段有较强的荧光发射, 化合物具有较高的荧光量子产率和较大的双光子吸收截面, 具有双光子诱导蓝光发射光学特性.     

反式-4，4′-二（邻甲氧基苯乙烯基）联苯化合物的合成、结构及光物理性能

以wittig—Homer反应合成了反式对称的4,4′-二（邻甲氧基苯乙烯基）联苯化合物,X射线衍射分析测定了化合物的晶体结构．测定了其在不同溶剂中的线性吸收光谱、荧光发射光谱及荧光量子产率．飞秒激光做光源研究了化合物的双光子光物理性能．测试结果表明：该化合物在蓝光波段有较强的荧光发射,化合物具有较高的荧光量子产率和较大的双光子吸收截面,具有双光子诱导蓝光发射光学特性．     

浅析房建项目施工阶段的成本控制

企业经营的目的就在于获取最大的经营效益,如何减少投资并获取较大的利润是企业管理中的重要主题。目前,有很多的施工企业都进行了深度的项目开发,实施多元化的发展。但对于项目开发单位而言,房建项目工程成本涉及到多个方面,其中涉及到建设期的决策阶段、设计以及后来的施工阶段。文章站在开发单位对施工阶段的工程成本控制展开了论述。     

丁二酮肟双核铜配合物的合成、结构和性能表征

The structure of [Cu₂(Hdmg)₄] (Hdmg=dimethylglyoxime anion) has been determined by X-ray crystallog-raphy. It is monoclinic, space group P2₁/n, with Z=2. The lattice parameters: a=0.71601(14)nm; b=1.7044(3)nm; c=1.0126(4)nm; β=113.89(2)°; M_r=587.52 (C₁₆H₂₈Cu₂N₈O₈); V=1.1299(5)nm³. The copper atom lies in a distorted square-pyramidal environment. The four equatorial donors are four nitrogen atoms from bidentate chelate dimethylglyoxime anion ligands. The oxygen atom from the dimethylglyoxime ligand acts as a bridging atom occupying the apical position of the symmetry-related copper atom in the dimer structure. The two dimethylglyoximes bridge two copper atoms to form a six-member Cu₂O₂N₂ ring, respectively. The thermal gravity (TG) data indicate that the compound [Cu₂(Hdmg)₄] undergoes two exothermic reactions with loss of the organic ligand to give residue CuO. CCDC: 208729.