Oxygen vacancy control of electrical,optical, and magnetic properties of Fe0.05Ti0.95O2 epitaxial films

High-quality Fe-doped TiO₂ films are epitaxially grown on MgF₂ substrates by pulsed laser deposition. The x-ray diffraction and Raman spectra prove that they are of pure rutile phase. High-resolution transmission electron microscopy (TEM) further demonstrates that the epitaxial relationship between rutile-phased TiO₂ and MgF₂ substrates is 110 TiO₂₂. The room temperature ferromagnetism is detected by alternative gradient magnetometer. By increasing the ambient oxygen pressure, magnetization shows that it decreases monotonically while absorption edge shows a red shift. The transport property measurement demonstrates a strong correlation between magnetization and carrier concentration. The influence of ambient oxygen pressure on magnetization can be well explained by a modified bound magnetization polarization model.     

基于改进潜能模型的养老机构空间可达性——以上海市奉贤区为例

空间可达性是判定各类设施布局是否合理的重要参考指标.科学评价服务设施空间可达性则是判断区域服务差异性以及优化资源空间配置的重要基础.在基本潜能模型的基础上,引入需求方阈值,按照养老机构规模设计了3级服务半径,加入地区优先匹配原则,并以上海市奉贤区为例,基于供需点之间的实际驾车时间、ArcGIS空间分析技术,对区域内部养老机构空间可达性进行分析.研究表明:考虑优先原则的奉贤区养老机构空间可达性分布不均程度加剧,其中南桥镇、庄行镇、金汇镇部分区域养老机构空间可达性显著较高;可达性呈现较为明显地从中心城区到外围逐渐降低的趋势;中部区域一些乡镇存在养老机构密集,养老资源相对集中的现象.改进的潜能模型进一步考虑了养老机构服务能力强弱、老年人需求等因素的影响,能更合理地评价机构的空间可达性.研究结果可为养老机构的科学规划提供参考与建议.     

刚性环状低聚物的二维有序单分子膜结构

近十年来 ,为了解决耐高温高分子材料加工温度高、熔体粘度大等问题 ,材料学家们研制和开发了一系列刚性环状齐聚物 ,如环状聚芳醚酮[1] 、环状聚芳醚砜[2 ] 和环状聚苯硫醚[3] 等 .但早期人们主要把含有刚性链段的环状齐聚物 (RCO)作为结构材料研究 .1 993年 ,Miyashita[4 ] 等发现 ,含有近似刚性的酰胺键的手性环状二苯胺低聚物具有与经典 LB分子相似的双亲性 ,可以获得手性 LB膜 .近来我们合成了一系列直径可控、含有不同活性功能基团的 RCO.RCO是一类潜力巨大的有机纳米功能材料 ,其具有以下性质 :(1 )纳米空穴直径稳定且可控 ;(2…     

Electrochemical Role of Transition Metals in Sn–Fe Alloy Revealed by Operando Magnetometry

As promising materials, alloy-type anode materials have been intensively investigated in both academia and industry. To release huge volume expansion during alloying/dealloying process, they are usually doped with transition metals. However, the electrochemical role of transition metals has not been fully understood. Here,pure Sn₃Fe films were deposited by sputtering, and the electrochemical mechanism was systematically investigated by operando magnetometry. We confirmed that Fe parti...