D-青霉胺铅络合物稳定常数的测定——pH滴定法

本文用pH滴定法测定D青霉胺铅络物的稳定常数,这个常数在文献上尚未见有报导。我们所得结果为log~Cβ_1=12.26(30℃)与文献上所报导的DL—青霉胺铅络合物稳定常数log~cβ_1=12.36接近。本文结果对D—青霉胺对铅离子的解毒作用提供了直接的依据,     

过度自信和需求不确定性对多报童模型的影响

研究在竞争条件下过度自信和需求不确定性对库存决策的影响.通过引入一个均值相等且方差缩小的变换来定量刻画决策者的过度自信偏好,得到系统最优订货量关于报童数量和过度自信系数的单调性.进一步,研究需求不确定性对系统的影响,证明随机大的需求导致较高的最优订货量.当需求分布为均匀分布时,对割准则序意义下系统最优订货量进行比较.     

Dynamics of Rabi model under second-order Born Oppenheimer approximation

We apply the second-order Born–Oppenheimer(BO)approximation to investigate the dynamics of the Rabi model,which describes the interaction between a two-level system and a single bosonic mode beyond the rotating wave approximation.By comparing with the numerical results,we find that our approach works well when the frequency of the two-level system is much smaller than that of the bosonic mode.     

Entanglement of Superpositions of Orthogonal Maximally Entangled States

We study the entanglement properties of the superposed state of orthogonal maximally entangled states. It is shown that the superposed state is maximally entangled and the superposed state is separable. The relation between the superposed state and the mutually unbiased state is discussed.     

挠性航天器大角度姿态机动路径规划

针对挠性航天器大角度姿态快速机动快速稳定的控制要求,通过分析挠性航天器姿态动力学特性,提出了一种基于抛物线型角加速度曲线的三段式机动路径规划算法.该算法考虑了机动过程中对最大角加速度与最大角速度限制,充分发挥执行机构的功能来提高系统的快速性,并使角加速度平滑变化以减小帆板的振动.该路径规划方法简单,适于在轨实现.仿真结...     

Single-photon scattering by two separated atoms in a supercavity

We study the single-photon scattering along a one-dimensional cavity array with two distant two-level atoms in a supercavity,which aims to simulate a recent x-ray experiment [Nature 482,199(2012)].Without introducing dissipation,we find that when one atom is exactly located at a node of a mode of the supercavity and the other is at the antinode of that mode,no splitting of the reflectivity peak can appear.Nevertheless,the atom at the node significantly changes the positions of the reflectivity valleys.On the other hand,when the atom is shifted a little from the exact node,then the splitting can appear.We also explain these results with an analysis based on the general formal scattering theory.Our result implies the importance of non-resonant modes of the supercavity in our problem.     

Efficient Numerical Algorithm on Irreducible Multiparty Correlations

We develop a numerical algorithm to calculate the degrees of irreducible multiparty correlations for an arbitrary multipartite quantum state, which is efficient for any quantum state of up to five qubits in my personal computer. We demonstrate the power of the algorithm by the explicit calculations of the degrees of irreducible multiparty correlations in the 4-qubit GHZ state, the Smolin state, and the 5-qubit W state. This development takes a crucial step towards practical applications of irreducible multiparty correlations in real quantum many-body physics.     

锡的电位溶出分析和吸附电位溶出分析法

应用电位溶出分析法,在0.35M NaNO_3 pH=1.4中能测定Sn(Ⅳ)和Sn(Ⅱ)。当使用溶解的氧为氧化剂(7.9×10~(-5)M),预富集时间为4分钟时,此法的测定灵敏度为1×10~(-9)M。循环伏安法显示,Sn(Ⅱ)→Sn(0)是最主要的还原步骤;而在氧化过程中,Sn(0)→Sn(Ⅱ)是最主要的氧化步骤。进行了各种干扰离子的实验。可以将干扰离子分为两类:(1) 与Sn的氧化电位(—0.45Vvs.Ag/AgCl相同者,能使Sn的过渡时间(或称消失时间)增长。(2) 对Sn呈现氧化作用者,使Sn的过渡时间缩短。当有与Sn(Ⅳ)或Sn(Ⅱ)形成络合物的试剂存在时,例如磷苯三酚和α巯基乙酸,由于形成的络合物吸附在电极表面,能使灵敏度提高三至四个数量级。磷苯三酚及α巯基乙酸存在时的灵敏度分别为1×10~(12)M和1×10~(-13)M。循环伏安法显示存在着这种吸附。利用吸附效应进行电位溶出分析的方法称为吸附电位溶出分析法。测定了若干水样中的微量锡的含量。所得的结果与阳极溶出法和分光光度法相对照。     

Preparing highly entangled states of nanodiamond rotation and NV center spin

A nanodiamond with an embedded nitrogen-vacancy(NV) center is one of the experimental systems that can be coherently manipulated within current technologies. Entanglement between NV center electron spin and mechanical rotation of the nanodiamond plays a fundamental role in building a quantum network connecting these microscopic and mesoscopic degrees of motions. Here we present a protocol to asymptotically prepare a highly entangled state of the total quantum angular momentum and electron spin b...     

基于路径规划和反推技术挠性航天器姿态控制

为抑制航天器姿态机动过程中挠性附件的振动,提出了一种基于路径规划和反推技术的姿态自适应控制方案.对航天器姿态机动路径进行规划,以缓解传统控制中快速性和超调量之间的矛盾,并减小姿态机动引起的挠性附件振动.针对航天器姿态动力学和运动学构成的具有不确定性的非线性串级系统,基于反推技术设计了一种仅利用输出信息的自适应控制器,并...