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Palladium nanoparticles/wool keratin-assisted carbon composite-modified flexible and disposable electrochemical solid-state pH sensor 下载免费PDF全文
张文立 刘笑天 林友辉 马利芸 孔令庆 闵光宗 吴荣辉 Sharwari K.Mengane 杨丽坤 Aniruddha B.Patil 刘向阳 《中国物理 B》2022,31(2):28201-028201
Several p H-dependent processes and reactions take place in the human body;hence,the p H of body fluids is the best indicator of disturbed health conditions.However,accurate and real-time diagnosis of the p H of body fluids is complicated because of limited commercially available p H sensors.Hence,we aimed to prepare a flexible,transparent,disposable,userfriendly,and economic strip-based solid-state p H sensor using palladium nanoparticles(Pd NPs)/N-doped carbon(NC)composite material.The Pd NPs/NC composite material was synthesized using wool keratin(WK)as a precursor.The insitu prepared Pd NPs played a key role in the controlled switching of protein structure to the N-doped carbon skeleton withπ–πarrangement at the mesoscale level,which mimics the A–B type polymeric structure,and hence,is highly susceptible to H+ions.The optimized carbonization condition in the presence of Pd NPs showed that the material obtained using a modified Ag/Ag Cl reference electrode had the highest p H sensitivity with excellent stability and durability.The optimized p H sensor showed high specificity and selectivity with a sensitivity of 55 m V/p H unit and a relative standard deviation of 0.79%.This study is the first to synthesize Pd NPs using WK as a stabilizing and reducing agent.The applicability of the sensor was investigated for biological samples,namely,saliva and gastric juices.The proposed protocol and material have implications in solid-state chemistry,where biological material will be the best choice for the synthesis of materials with anticipated performance. 相似文献
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We present a fast algorithm based on polynomial interpolation to approximate matrices arising from the discretization of second-kind integral equations where the kernel function is either smooth, non-oscillatory and possessing only a finite number of singularities or a product of such function with a highly oscillatory coefficient function. Contrast to wavelet-like approximations, ourapproximation matrix is not sparse. However, the approximation can be construced in O(n) operations and requires O(n) storage, where n is the number of quadrature points used in the discretization. Moreover, the matrix-vector multiplication cost is of order O(nlogn). Thus our scheme is well suitable for conjugate gradient type methods. Our numerical results indicate that the algorithm is very accurate and stable for high degree polynomial interpolation. 相似文献
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在水热条件下,利用不同用量的硫酸钛和尿素在涤纶纤维表面包覆一层纳米TiO2颗粒,改性后的涤纶纤维用紫外光辐照光催化降解甲基橙染料.研究结果表明,采用硫酸钛和尿素摩尔比为1∶2,硫酸钛用量为0.05mol时,效果最佳,且原料浪费较少.用该用量的硫酸钛和尿素改性的涤纶纤维对甲基蓝、亚甲基蓝和罗丹明B染料也有良好的光催化降解效果,其降解率均在95%以上,可用于降解废水中染料的光催化剂.利用扫描电子显微镜、X射线衍射和反射光谱对改性结果进行表征,发现采用水热方法可合成出纯锐钛矿型纳米二氧化钛颗粒并包覆在涤纶纤维表面,平均粒径为10.8nm,并且其对紫外线的吸收能力明显增加. 相似文献
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吴荣辉 《中国新技术新产品精选》2014,(19):56-58
随着农村经济的快速发展,农村电网电力需求与日俱增。在用电高峰时期,农村地区农网馈线末端出现低电压的现象越来越严重。本文结合诏安地区桥洪线出现低电压的实际问题,对农网馈线低电压产生的原因进行了细致分析,有针对性地提出了解决对策,对提高农村电网的供电质量提供了参考建议。 相似文献
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互动是一个必要的英语教学环节,以学生为主体的课堂互动分为师生互动与生生互动。从语言学习材料的选择与教学手段的组合两个视角进行观察,阐述在英语教学过程中如何实现有效的互动,实现教学效果优化。 相似文献
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