BiFeO3/H2O2电催化制备氧化淀粉及其对氨咖黄敏的缓释性能研究

通过浸渍热解法制备Ti/BiFeO_3催化剂电极,以H_2O_2为氧化剂、玉米淀粉为原料制备了氧化玉米淀粉,并通过压片法制备的淀粉负载氨咖黄敏药片研究其对氨咖黄敏在水中的缓释性能。扫描电子显微镜(SEM)、红外光谱(FT-IR)、X射线衍射(XRD)以及黏度等测试表明,氧化淀粉颗粒表面粗糙且产生明显裂缝,结晶度、粘度和糊化温度明显下降。与NS相比,制备的OS在270 min之内对氨咖黄敏具有更加均匀的释放速率。在p H=9时AHC的缓释效果最好,而温度影响不明显。     

1,4-双(3,4-二羧基苯氧基)苯二酸酐的合成与表征

以4-硝基邻苯二甲酰亚胺为原料,经过五步反应,即氨解、脱水、取代、水解和脱水合成了一种双醚酐单体1,4-双(3,4-二羧基苯氧基)苯二酸酐.研究了反应条件对产率的影响.用IR,1H-NMR表征了1,4-双(3,4-二羧基苯氧基)苯二酸酐及其他中间体化合物的结构.     

Pulse Compression Based on Laser-Induced Optical Breakdown in Suspension

Pulse compression based on laser-induced optical breakdown in suspension is investigated. The physical mechanism behind it is analyzed theoretically and validated in the Q-switched Nd：YAG laser system. A 12-ns pump pulse is suppressed to 5ns With good fidelity in the front edge and sharp steepness in the trailing edge. The HT-270, which has a small gain coefficient and absorption coefficient, is used as a solvent, and therefore the disturbance induced by stimulated Brillouin scattering and absorption are minimized and the transmittivity is enhanced.     

Measurement of stimulated Brillouin scattering （SBS） threshold based on waveform variation of SBS optical limiting

This paper proposes a method for measuring the stimulated Brillouin scattering (SBS) threshold based on waveform variation of SBS optical limiting. The output waveforms for different pump power densities are numerically simulated, and validated in the Nd:YAG seed-injected laser system. The results indicate that SBS does not take place in the case of a low pump power density and thus the output power scales up linearly with pump power. Once the pump power density exceeds the SBS threshold, SBS takes place and thereby the energies are transferred from pump to Stokes. As a result, a small shoulder appears in the trailing edge of the output waveform, which provides another method to determine the SBS threshold.     

铜催化N-芳基丙烯酰胺与丙酮成环合成吲哚酮

发展了一种高效、简单的铜催化活泼烯烃羰基化成环合成吲哚酮的方法.以氯化亚铜为催化剂,二叔丁基过氧化物（DTBP）为氧化剂,丙酮为溶剂兼反应物,在100 ℃条件下与N-芳基丙烯酰胺类化合物发生自由基串联环化反应,高效地合成了一系列吲哚酮衍生物.探索不同温度、催化剂、溶剂等因素对反应的影响,并推导此环化反应的机理过程.     

一阶非线性常微分方程奇解的求法

给出利用c-判别式和p-判别式求一阶常微分方程奇解的两个定理,还给出同时利用c-判别式和p-判别式求奇解的方法和利用同除因式等于零求奇解的方法,并通过一些具体例子说明这些方法的应用.     

铜催化苯甲酰胺有氧环化合成7-叔烷基异喹啉二酮

发展了一种高效、简单的铜/空气催化体系催化的苯甲酰胺串联自由基环化合成7-叔烷基异喹啉二酮的反应。 在廉价CuI存在下,空气环境中,N-烷基-N-甲基丙烯酰基苯甲酰胺与AIBN发生串联自由基加成/环化/碳碳偶联反应,以52%~73%的产率合成了一系列的7-取代异喹啉二酮。 此研究为合成具有潜在药用价值的含氰取代异喹啉二酮提供了一条快速、简单、温和的构建途径。     

Investigation on the effect of beam divergence angle upon output waveform based on stimulated Brillouin scattering optical limiting

This paper investigates the effect of beam divergence angle on output waveform based on stimulated Brillouin scattering optical limiting. Output waveforms in the case of different pump divergence angles are numerically simulated, and validated in a Nd:YAG seed-injected laser system. The results indicate that a small pump divergence angle can lead to good interaction between pump and Stokes, and a platform can be easily realized in the transmitted waveform. In contrast, a peak followed by the platform appears when the divergence angle becomes large.