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V. Mattoli V. Pensabene T. Fujie S. Taccola A. Menciassi S. Takeoka P. Dario 《Procedia Chemistry》2009,1(1):28-31
Polymeric ultra-thin films, so called nanosheets, show peculiar properties making them potentially useful for several applications in biomedicine. Moreover, the possibility to functionalize these films by using different agents opens new and partially unexplored scenarios, including micro/nano sensing and actuation. This paper compares two different methods for the preparation of free-standing nanosheets, loaded with magnetic particles for no-contact manipulation in liquid environment. Morphology and functionalities of the two types of nanosheets have been characterized and compared. These magnetic nanosheets could find applications as free-standing carriers to be released and controlled in endoluminal surgery or as plasters with nanometric thickness to be delivered in situ on surgical incisions. 相似文献
3.
Alex Virgilio Renata Stabile Amais Daniela Schiavo José Anchieta Gomes Neto Joaquim de Araújo Nóbrega 《Analytical letters》2017,50(5):842-852
A procedure for the determination of As, Cd, Cr, Ni, Pb, and V in phytotherapy medicines by inductively coupled plasma–tandem mass spectrometry is reported. The use of tandem mass spectrometry with oxygen into an octopole reaction system at various gas flow rates and the combination of on-mass and mass-shift modes was evaluated. Cadmium, Cr, Ni, and Pb were determined as free atomic ions while As and V were determined as the oxides AsO+ and VO+ in the same run. Samples were prepared by microwave-assisted digestion with dilute nitric acid and hydrogen peroxide. Two plant-certified reference materials (apple leaves and tomato leaves) were used to check the accuracy. For tandem mass spectrometry with 0.5?mL min?1 O2, recoveries in the 85–113% were typically obtained and no statistical differences were observed at the 95% confidence level (t-test) in comparison with the certified values. Using these conditions, the limits of detection for the method were 0.01, 0.0002, 0.008, 0.008, 0.003, and 0.002?µg g?1 for As, Cd, Cr, Ni, Pb, and V, respectively. The procedure was used for the analysis of four phytotherapic drugs and the determined concentrations were up to 0.168?µg g?1 As, 0.03?µg g?1 Cd, 0.82?µg g?1 Cr, 1.18?µg g?1 Ni, 0.52?µg g?1 Pb, and 2.4?µg g?1 V with average precision values of 8% as the relative standard deviation. The found concentrations were compared with limits proposed in official guidelines and, in most cases, the values were below the maximum limits allowed. 相似文献
4.
Confinement character and its effects on photoluminescence (PL) properties are theoretically investigated and compared between porous silicon (p-Si) and silicon nanowires (Si-NWs). The method is based on the application of the tight-binding technique using the minimal sp3-basis set, including the second-nearest-neighbor interactions. The results show that the quantum confinement (QC) is not entirely controlled by the porosity, rather it is mainly affected by the average distance between pores (d). The p-Si is found to exhibit weaker confinement character than Si-NWs. The confinement energy of charge carriers decays against d exponentially for p-Si and via a power-law for Si-NWs. This latter type of QC is much stronger and is somewhat similar to the case of a single particle in a quantum box. The excellent fit to the PL data demonstrates that the experimental samples of p-Si do exhibit strong QC character and thus reveals the possibility of silicon clustering into nano-crystals and/or nanowires. Furthermore, the results show that the passivation of the surface dangling bonds by the hydrogen atoms plays an essential role in preventing the appearance of gap states and consequently enhances the optical qualities of the produced structures. The oscillator strength (OS) is found to increase exponentially with energy in Si-NWs confirming the strong confinement character of carriers. Our theoretical findings suggest the existence of Si nanocrystals (Si-NCs) of sizes 1-3 nm and/or Si-NWs of cross-sectional sizes in the 1-3 nm range inside the experimental p-Si samples. The experimentally-observed strong photoluminescence from p-Si should be in favor of an exhibition of 3D-confinement character. The favorable comparison of our theoretical results with the experimental data consolidates our above claims. 相似文献
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The aim of this paper is to analyze the statistical properties of solute concentration in natural aquifers as sampled in observation wells, having a small diameter in comparison with the characteristic size of the heterogeneity in hydraulic properties. The analysis, in Langragian framework, takes advantage of the reverse formulation, where, instead of considering the destination of the injected particles, the origin of the particle being sampled is sought. In the case of small values of the log-conductivity variance Y2, it allows the derivation of an analytical expression for concentration mean, variance and pdf, while for aquifer characterized by high value in Y2, a numerical analysis based on a Monte Carlo approach using a reverse scheme is developed and applied for values of Y2 up to 2. In this case, the use of a Beta function to fit the concentration pdf proves valid for practical applications. The comparison between the numerical and the analytical results defines the range of validity of the analytical ones. The relative role of large-scale dispersion processes and pore-scale effects is analyzed in terms of global variance in order to point out limits and accuracy of the Eulerian scheme in comparison with the Lagrangian one. 相似文献
7.
Martino L Virno A Pagano B Virgilio A Di Micco S Galeone A Giancola C Bifulco G Mayol L Randazzo A 《Journal of the American Chemical Society》2007,129(51):16048-16056
The complex between distamycin A and the parallel DNA quadruplex [d(TGGGGT)]4 has been studied by 1H NMR spectroscopy and isothermal titration calorimetry (ITC). To unambiguously assert that distamycin A interacts with the grooves of the quadruplex [d(TGGGGT)]4, we have analyzed the NMR titration profile of a modified quadruplex, namely [d(TGGMeGGT)]4, and we have applied the recently developed differential frequency-saturation transfer difference (DF-STD) method, for assessing the ligand-DNA binding mode. The three-dimensional structure of the 4:1 distamycin A/[d(TGGGGT)]4 complex has been determined by an in-depth NMR study followed by dynamics and mechanics calculations. All results unequivocally indicate that distamycin molecules interact with [d(TGGGGT)]4 in a 4:1 binding mode, with two antiparallel distamycin dimers that bind simultaneously two opposite grooves of the quadruplex. The affinity between distamycin A and [d(TGGGGT)]4 enhances ( approximately 10-fold) when the ratio of distamycin A to the quadruplex is increased. In this paper we report the first three-dimensional structure of a groove-binder molecule complexed to a DNA quadruplex structure. 相似文献
8.
Jean-Marc Belley Michel Virgilio 《Journal of Mathematical Analysis and Applications》2005,306(2):646-662
Conditions are obtained for the Duffing equation with delay and state dependent impulses to admit a periodic solution. 相似文献
9.
Virgilio Pannone 《Annali di Matematica Pura ed Applicata》1990,156(1):323-339
Summary It is proved that the p- groups of submaximal class do not admit equipartitions other than the atomic (Theorem 3.2). This result is then wed to give a complete classification of the groups of order p6 admitting nonatomic equipartitions (Theorem 5.1). 相似文献
10.
Amir Sammak Diego Sabbagh Nico W. Hendrickx Mario Lodari Brian Paquelet Wuetz Alberto Tosato LaReine Yeoh Monica Bollani Michele Virgilio Markus Andreas Schubert Peter Zaumseil Giovanni Capellini Menno Veldhorst Giordano Scappucci 《Advanced functional materials》2019,29(14)
Buried‐channel semiconductor heterostructures are an archetype material platform for the fabrication of gated semiconductor quantum devices. Sharp confinement potential is obtained by positioning the channel near the surface; however, nearby surface states degrade the electrical properties of the starting material. Here, a 2D hole gas of high mobility (5 × 105 cm2 V?1 s?1) is demonstrated in a very shallow strained germanium (Ge) channel, which is located only 22 nm below the surface. The top‐gate of a dopant‐less field effect transistor controls the channel carrier density confined in an undoped Ge/SiGe heterostructure with reduced background contamination, sharp interfaces, and high uniformity. The high mobility leads to mean free paths ≈ 6 µm, setting new benchmarks for holes in shallow field effect transistors. The high mobility, along with a percolation density of 1.2 × 1011cm?2, light effective mass (0.09me), and high effective g‐factor (up to 9.2) highlight the potential of undoped Ge/SiGe as a low‐disorder material platform for hybrid quantum technologies. 相似文献