全文获取类型
收费全文 | 1556篇 |
免费 | 43篇 |
国内免费 | 7篇 |
专业分类
化学 | 1055篇 |
晶体学 | 4篇 |
力学 | 65篇 |
数学 | 235篇 |
物理学 | 176篇 |
无线电 | 71篇 |
出版年
2023年 | 9篇 |
2022年 | 22篇 |
2021年 | 46篇 |
2020年 | 33篇 |
2019年 | 29篇 |
2018年 | 24篇 |
2017年 | 26篇 |
2016年 | 51篇 |
2015年 | 24篇 |
2014年 | 45篇 |
2013年 | 80篇 |
2012年 | 71篇 |
2011年 | 92篇 |
2010年 | 53篇 |
2009年 | 62篇 |
2008年 | 85篇 |
2007年 | 109篇 |
2006年 | 99篇 |
2005年 | 79篇 |
2004年 | 87篇 |
2003年 | 51篇 |
2002年 | 55篇 |
2001年 | 14篇 |
2000年 | 20篇 |
1999年 | 12篇 |
1998年 | 20篇 |
1997年 | 14篇 |
1996年 | 14篇 |
1995年 | 21篇 |
1994年 | 9篇 |
1993年 | 14篇 |
1992年 | 12篇 |
1991年 | 17篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 17篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 12篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 16篇 |
1980年 | 16篇 |
1979年 | 17篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1976年 | 13篇 |
1975年 | 6篇 |
1974年 | 8篇 |
排序方式: 共有1606条查询结果,搜索用时 453 毫秒
1.
Matteo Di Giosia Alice Soldà Markus Seeger Andrea Cantelli Fabio Arnesano Maria I. Nardella Vincenzo Mangini Francesco Valle Marco Montalti Francesco Zerbetto Stefania Rapino Matteo Calvaresi Vasilis Ntziachristos 《Advanced functional materials》2021,31(20):2101527
Fullerenes are candidates for theranostic applications because of their high photodynamic activity and intrinsic multimodal imaging contrast. However, fullerenes suffer from low solubility in aqueous media, poor biocompatibility, cell toxicity, and a tendency to aggregate. C70@lysozyme is introduced herein as a novel bioconjugate that is harmless to a cellular environment, yet is also photoactive and has excellent optical and optoacoustic contrast for tracking cellular uptake and intracellular localization. The formation, water-solubility, photoactivity, and unperturbed structure of C70@lysozyme are confirmed using UV-visible and 2D 1H, 15N NMR spectroscopy. The excellent imaging contrast of C70@lysozyme in optoacoustic and third harmonic generation microscopy is exploited to monitor its uptake in HeLa cells and lysosomal trafficking. Last, the photoactivity of C70@lysozyme and its ability to initiate cell death by means of singlet oxygen (1O2) production upon exposure to low levels of white light irradiation is demonstrated. This study introduces C70@lysozyme and other fullerene-protein conjugates as potential candidates for theranostic applications. 相似文献
2.
3.
Vincenzo Santagada Ferdinando FiorinoElisa Perissutti Beatrice SeverinoSara Terracciano Giuseppe CirinoGiuseppe Caliendo 《Tetrahedron letters》2003,44(6):1145-1148
A novel and convenient microwave-assisted dimerization of an active peptide compound using the DKPs as scaffold is described. The key reaction giving rise to the diketopiperazine scaffold is the intermolecular coupling. No epimerization was detected in the reactions used. Conventional and microwave heating of the reactions are compared. Synthesis by microwave irradiation gave the desired compounds in higher yields and in shorter reaction times than those obtained by conventional heating. 相似文献
4.
5.
Temperature modulated differential calorimetry (TMDSC) is used to examine the crystal-crystal transitions of poly(tetrafluoroethylene). This study gives new information about the dynamic thermal behavior of such transitions. The involvement of reversible and irreversible processes during the phenomenon is observed, which are related to the order-disorder changes occurring during the transition.This study adds a new example to the response of TMDSC during first order transitions. 相似文献
6.
Onofrio Mario Di Vincenzo Plamen Koshlukov Roberto La Scala 《Advances in Applied Mathematics》2006,37(4):541
In this paper we describe completely the involutions of the first kind of the algebra UTn(F) of n×n upper triangular matrices. Every such involution can be extended uniquely to an involution on the full matrix algebra. We describe the equivalence classes of involutions on the upper triangular matrices. There are two distinct classes for UTn(F) when n is even and a single class in the odd case.Furthermore we consider the algebra UT2(F) of the 2×2 upper triangular matrices over an infinite field F of characteristic different from 2. For every involution *, we describe the *-polynomial identities for this algebra. We exhibit bases of the corresponding ideals of identities with involution, and compute the Hilbert (or Poincaré) series and the codimension sequences of the respective relatively free algebras.Then we consider the *-polynomial identities for the algebra UT3(F) over a field of characteristic zero. We describe a finite generating set of the ideal of *-identities for this algebra. These generators are quite a few, and their degrees are relatively large. It seems to us that the problem of describing the *-identities for the algebra UTn(F) of the n×n upper triangular matrices may be much more complicated than in the case of ordinary polynomial identities. 相似文献
7.
Then-th commutator for a,b in a ringR is defined inductively as follows: [a,b]1=[a,b]=ab−ba and[a,b]
n=[[a,b]−1,b]. We characterize the ringsR without non-zero nil right ideals in which[a,b]
nis nilpotent or regular for alla,b∈R. We also examine the case whereR is a semiprime ring with involution in which[t
1, t2]nis nilpotent or regular for all tracest
1,t2∈R. 相似文献
8.
9.
Vincenzo Piazza Vittorio PellegriniFabio Beltram Werner Wegscheider 《Solid State Communications》2003,127(2):163-168
Time-dependent capacitance measurements reveal an unstable phase of electrons in gallium arsenide quantum well that occurs when two Landau levels with opposite-spin are brought close to degeneracy by applying a gate voltage. This phase emerges below a critical temperature and displays a peculiar non-equilibrium dynamical evolution. The relaxation dynamics is found to follow a stretched-exponential behaviour and correlates with hysteresis loops observed by sweeping the magnetic field. These experiments indicate that metastable randomly distributed magnetic domains with peculiar excitations are involved in the relaxation process in a way that is equivalently tunable by a change in gate voltage or temperature. 相似文献
10.
Vincenzo Recupero 《Journal of Mathematical Analysis and Applications》2004,300(2):387-407
In this paper we study a model of phase relaxation for the Stefan problem with the Cattaneo–Maxwell heat flux law. We prove an existence and uniqueness result for the resulting problem and we show that its solution converges to the solution of the Stefan problem as the two relaxation parameters go to zero, provided a relation between these parameters holds. 相似文献