The Role of Radical Bridges in Polynuclear Single-Molecule Magnets

Employing radical bridges between anisotropic metal ions has been a viable route to achieve high-performance single-molecule magnets (SMMs). While the bridges have been mainly considered for their ability to promote exchange interactions, the crystal-field effect arising from them has not been taken into account explicitly. This lack of consideration may distort the understanding and limit the development of the entire family. To shed light on this aspect, herein we report a theoretical investigation of a series of N -radical-bridged diterbium complexes. It is found that while promoting strong exchange coupling between the terbium ions, the N -radical induces a crystal field that interferes destructively with that of the outer ligands, and thus reduces the overall SMM behavior. Based on the theoretical results, we conclude that the SMM behavior in this series could be further maximized if the crystal field of the outer ligands is designed to be collinear with that of the radical bridge. This conclusion can be generalized to all exchange-coupled SMMs.     

A Hydroperoxide-Mediated Decarboxylation of α-Ketoacids Enables the Chemoselective Acylation of Amines

Strategies for the formation of amide bonds, that is, one of the most basic and important transformations in organic synthesis, have so far focused predominantly on dehydration reactions. Herein, we report and demonstrate the practical utility of a novel decarboxylative amidation of α-ketoacids by using inexpensive tert-butyl hydroperoxide (TBHP), which is characterized by high yields, a broad substrate scope, mild reaction conditions, and a unique chemoselectivity. These features enable the synthesis of peptides from amino acid derived α-ketoacids under preservation of the stereochemical information.     

Algebraic decoding of (103, 52, 19) and (113, 57, 15) quadratic residue codes

In this paper, two algebraic decoders for the (103, 52, 19) and (113, 57, 15) quadratic residue codes, which have lengths greater than 100, are presented. The results have been verified by software simulation that programs in C++ language have been executed to check possible error patterns of both quadratic residue codes.     

Influence of exciton-exciton interaction with spin paired charge carriers and exciton-lattice interaction on the surface properties of crystalline solids

Applying tight-binding approximation and spin pairing of like charge carriers in a pair of excitons created in a lattice, the possibility of forming a bound exciton-exciton state is studied. It is found that, provided there exists strong exciton-lattice interaction, such a bound state may be formed and its energy may lie within the valence band deforming the material into a crystalline solid with no energy gap. Lowering of the energy is calculated in naphthalene and anthracene crystals where some experimental results are known. The excess energy released after the formation of such bound state can be adequate, depending on the material, to desorb neutral atoms or eject of electrons from surfaces.     

线性常微分方程的保线性变换及其应用

研究了线性常微分方程的保线性变换，得到任意两个二阶线性常微分方程等价的条件，并用于求解一类二阶线性变系数齐次常微分方程．对数学物理方法教学中怎样通过适当的变换把给定的二阶线性变系数齐次常微分方程化为可解的方程给出了合理解释。     

一类非线性方程存在多个极限环的一个充分条件

关于方程(1)的极限环唯多性问题,不少人作了研究,[1]引进“n重互相包含”曲线类,,经[2]的改进获得较好的结果,但这类曲线要求的条件较多。本文不从[1]的观点出发,不包含[1]的全部条件,独立地用①11。’,LtnnoB变换折叠相平面,据轨线与折叠线交点的位置,对(1)的等价方程按线性方程积分,将积分的正负项作成比值进行比较,得出一组充分条件。     

The Compactness of Commutators on the Heisenberg Group

We consider the commutators of the HSrmander multiplier with CMO-functions on the Heisenberg group. The result of compactness on L^P spaces is proved.     

TFT-AMLCD绝缘层a-SiNx∶H的制备

用等离子体化学气相沉积法(PECVD)在玻璃基板上淀积了厚度约1μm的非晶氮化硅(a-SiNx∶H)薄膜,在最佳工艺下得到薄膜的性能参数,折射率为1.8左右,光吸收系数为1.2×102～2×102cm-1,相对介电常数为7～8.4,电荷面密度为2.5×1012～3.1×1012cm-2.这种薄膜比较适合于用作薄膜晶体管-有源矩阵液晶显示器(TFT-AMLCD)的栅绝缘层.     

Alternative Approach to the Concept of Shape Invariance in Quantum Mechanics

It is shown that in the case of shapeinvariance, with the use of the mixing functionformalism, exact solvability of the Schrodinger equationcan be obtained without recourse to the technique ofsupersymmetrization. Some consequences of the method are outlinedand illustrated by specific examples.