Some inhomogeneous magnetized viscous-fluid cosmological models with varyingΛ

Some cylindrically symmetric inhomogeneous viscous-fluid cosmological models with electromagnetic field are obtained. To get a solution a supplementary condition between metric potentials is used. The viscosity coefficient of bulk viscous fluid is assumed to be a power function of mass density. Without assuming anyad hoc law, we obtain a cosmological constant as a decreasing function of time. The behaviour of the electromagnetic field tensor together with some physical aspects of the model are also discussed.     

A Connecting Link between Lorentz and Dirac Theories of Electrons

A theory, that is an initial step towards bridging the gap between Lorentz and Dirac theories of electrons, is presented. An electromagnetic Lagrangian density is postulated, such that, the theory can be cast into a form, similar to Dirac theory. Electromagnetic interpretation of conserved currents, and of usual bilinear covariants in the Dirac theory, is obtained. A counterpart of Abraham-Lorentz equation, with oscillatory solutions is derived. Self-energy of electrons is expressed in terms of their self-potentials and self-currents.     

The Content Driven Mobile Internet

The development of future mobile networks will be driven, in large part, by content and web based services. In this paper, we examine several performance, scalability and architectural challenges faced by future mobile web applications and how advanced mobile content delivery techniques can address these challenges. We review existing content delivery using a taxonomy that consists of three categories: network scaling, end system acceleration, and content and protocol optimization. While wireline content delivery focuses on network and server scalability, mobile content delivery will likely benefit most from optimizing radio link usage. We also present our ongoing work in this area, which extends the functionality of edge caching to the terminal, uses user interest correlation information to maintain low terminal power consumption and adds a new dimension to radio resource management. This revised version was published online in August 2006 with corrections to the Cover Date.     

Growth and reactivity of silver clusters in amino polycarboxylic acid solutions

Reduction and subsequent aggregation of silver ions in the presence of various chelating agents such as trans-1,2-diaminocyclohexanetetraacetic acid (DCTA) 1,2-propylenediaminetetraacetic acid (PDTA), diethylenetriaminepentaacetic acid (DTPA), and triethylenetetraaminehexaacetic acid (TTHA) have been studied by pulse radiolysis. Rate constants of formation and transient absorption spectra for the ligand-complexed Ag(0) and Ag(2)(+) have been determined. The redox potential of Ag(+)(L)/Ag(0)(L) becomes more negative than that of Ag(+)/Ag(0). Growth and reactivity of silver clusters were also studied in the presence of methyl viologen (MV(2+)). The kinetics of formation of the MV(+*) radical, produced by the same pulse as in the case of silver atoms, confirms the catalytic electron transfer toward super critical silver clusters in the presence of ligands. The results suggest that catalytic electron transfer activity of silver clusters depends on the ligand.     

Gold nanoparticle networks with photoresponsive interparticle spacings

Photoresponsive gold nanoparticle networks were prepared by functionalizing them with azobenzene derivatives. A network can be formed when a linker molecule constituting the azobenzene moiety suitably derivatized on either side with gold surface sensitive groups such as thiols and amines is added to the nanoparticle solution. It is shown that the interparticle spacing in the networks could be controlled by the reversible trans-cis isomerization of the azobenzene moiety induced by UV and visible light, respectively. The photoinduced variation in the interparticle spacings is inferred by the changes in the optical spectra of the gold nanoparticles which display a red or blue shift in the surface plasmon resonance peak depending on a decrease or increase in the interparticle spacing, respectively. Transmission electron microscopy images are in consonance with the evidence from the optical spectra.     

Curvelet Transform Based Watermarking for Telemedicine

Now a days telemedicine is a proactive research area and gaining more engrossment. Digital transmission of medical imaging, remote evaluation and diagnosis together are termed as Telemedcine and it has increasingly gained prominence in the recent times. Remote specialist reckons intemperately on scan images or medicinal images and data of patient for devising diagnostic conclusion. While imparting a scan image (clinical picture) to remote authority, the significant part (ROI) in it may be altered by interlopers. The remote authority must recover the ROI in a clinical picture on the off chance that it has been altered. This paper presents a novel robust watermarking method founded on Curvelet Transform to recover the ROI in medical image in case it is altered. The proposed method hides ROI information inside diagnostically insignificant part in medical image through Curvelet Transform. Experiments carried out using this novel technique have proven that the ROI in medical image is restored to its original state.

     

Synthesis of silver nanoprisms in formamide

Polygonal (mainly triangular) silver nanoprisms were prepared by reducing silver perchlorate in formamide in the presence of polyethylene glycol (PEG) at room temperature. The reduction of silver ions by formamide leads to the deposition of arrays of triangular shaped silver nanoparticles on the glass walls of the container, accompanied by evolution of CO2 gas. In the presence of poly(N-vinyl-2-pyrrolidone) (PVP) and PEG (1:1), both nanospheres and nanoprisms are formed.     

Nucleophilic proteolytic antibodies

Proteolytic antibodies appear to utilizecatalytic mechanisms akin to nonantibody serine proteases, assessed from mutagenesis and protease-inhibitor studies. The catalytic efficiency derives substantially from the ability to recognize the ground state with high affinity. Because the proteolytic activity is germline-encoded, catalysts with specificity for virtually any target polypeptide could potentially be developed by applying appropriate immunogens and selection strategies. Analysis of transition-state stabilizing interactions suggests that chemical reactivity ofactive-site serine residues is an important contributor to catalysis. A prototype antigen analog capable of reacting covalently with nucleophilic serine residues permitted enrichment of the catalysts from a phage-displayed lupus light-chain library. Further mechanistic developments in understanding proteolytic antibodies may lead to the isolation of catalysts suitable for passive immunotherapy of major diseases, and elicitation of catalytic immunity as a component of prophylactic vaccination.     

Stereoselective synthesis of α-glucosides from 3-O-propargyl protected glucal exploiting the alkynophilicity of AuCl3

The stereoselective synthesis of 2,3-unsaturated α-d-glucosides by the S_N2′ addition of diverse aglycones onto 4,6-di-O-benzyl-3-O-propargyl glucal was achieved using a catalytic quantity of AuCl₃. The Au catalyzed reaction was explored using various aliphatic, aromatic, alicyclic and monosaccharide aglycones. The current protocol tolerates diverse functional groups and is highly stereoselective, fast, catalytic and mild.