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1.
Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry 下载免费PDF全文
Victor A. Kusuma Elliot A. Roth William P. Clafshenkel Steven S. Klara Xu Zhou Surendar R. Venna Erik Albenze David R. Luebke Meagan S. Mauter Richard R. Koepsel Alan J. Russell David Hopkinson Hunaid B. Nulwala 《Journal of polymer science. Part A, Polymer chemistry》2015,53(13):1548-1557
Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO2/N2 selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1548–1557 相似文献
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Physical aging in amorphous poly(ethylene furanoate): Enthalpic recovery,density, and oxygen transport considerations 下载免费PDF全文
Steven K. Burgess Christopher R. Mubarak Robert M. Kriegel William J. Koros 《Journal of Polymer Science.Polymer Physics》2015,53(6):389-399
The current work utilizes three separate techniques to study the physical aging process in amorphous poly(ethylene furanoate) (PEF), which is a recently introduced engineering thermoplastic with enhanced properties compared to petroleum‐sourced poly(ethylene terephthalate). Differential scanning calorimetry aging experiments were conducted at multiple aging temperatures and times, and the resultant enthalpic recovery values compared to the theoretical maximum enthalpy loss evaluated from calculations involving extrapolation of the equilibrium liquid line. Density measurements reveal densification of the matrix for the aged versus unaged samples, and provide an estimate for the reduction in free volume for the aged samples. Complementary oxygen permeation and pressure‐decay sorption experiments provide independent verification of the free volume reduction mechanism for physical aging in glassy polymers. The current work provides the first detailed aging study for PEF. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 389–399 相似文献
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Steven D. Bull Simon W. Epstein Nadeam Mujtaba Edward D. Savory Juan A. Tamayo 《Tetrahedron》2006,62(33):7911-7925
Enolates of (S)-N,N′-bis-(p-methoxybenzyl)-3-iso-propylpiperazine-2,5-dione exhibit high levels of enantiodiscrimination in alkylations with (RS)-1-aryl-1-bromoethanes and (RS)-2-bromoesters, affording substituted diketopiperazines containing two new stereogenic centres in high de. Deprotection and hydrolysis of the resultant substituted diketopiperazines provides a route to the asymmetric synthesis of homochiral methyl 2-amino-3-aryl-butanoates and 3-methyl-aspartates in high de and ee. 相似文献
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Steven R. Corman 《Computational & Mathematical Organization Theory》2006,12(1):35-49
The predominant idea for using network concepts to fight terrorists centers on disabling key parts of their communication
networks. Although this counternetwork strategy is clearly a sound approach, it is vulnerable to missing, incomplete, or erroneous
information about the network. This paper describes a different and complementary application of network concepts to terrorist
organizations. It is based on activity focus networks (AFNs), which represent the complex activity system of an organization.
An activity focus is a conceptual or physical entity around which joint activity is organized. Any organization has a number
of these, which are in some cases compatible and in some cases incompatible. The set of foci and their relations of compatibility
and incompatibility define the AFN. A hypothetical AFN for a terrorist organization is specified and tested in a simulation
called AQAS. It shows that certain activity foci, and in particular one combination, have high potential as pressure points
for the activity system. The AFN approach complements the counternetwork approach by reducing the downside risk of incomplete
information about the communication network, and enhancing the effectiveness of counternetwork approaches over time.
Steven R. Corman is Professor in the Hugh Downs School of Human Communication at Arizona State University and Chair of the Organizational
Communication Division of the International Communication Association. His research interests include communication networks
and activity systems, high-resolution text and discourse analysis, and modeling and simulation of human communication systems. 相似文献
6.
Steven S. Ross 《网络电信》2008,(8):13-13
Perhaps the most powerful claim that advocates of fiber can make,on top of the massive bandwidthfiber makes possible today, is that fiber is future-proof. That is, the fiber that is laid today can be upgraded so that the same strands of glass can carry massively more bandwidth in the future. 相似文献
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Blood product transfusion is a financial concern for hospitals and patients. Efficient utilization of this dwindling resource is a critical problem if hospitals are to maximize patient care while minimizing costs. Traditional statistical models do not perform well in this domain. An additional concern is the speed with which transfusion decisions and planning can be made. Rapid assessment in the emergency room (ER) necessarily limits the amount of usable information available (with respect to independent variables available). This study evaluates the efficacy of using artificial neural networks (ANNs) to predict the transfusion requirements of trauma patients using readily available information. A total of 1016 patient records are used to train and test a backpropagation neural network for predicting the transfusion requirements of these patients during the first 2, 2-6, and 6-24 h, and for total transfusions. Sensitivity and specificity analysis are used along with the mean absolute difference between blood units predicted and units transfused to demonstrate that ANNs can accurately predict most ER patient transfusion requirements, while only using information available at the time of entry into the ER. 相似文献
8.
Marcelo Do Amaral Steven Van Es Jos M. Asua 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):3936-3946
The production of high‐solid‐content, low‐viscosity latexes is an active field in both industry and academia. The viscosity of polymer dispersions has a clear dependence on the particle size distribution (PSD). An example is the rule of thumb that a bimodal PSD enables the reduction of the viscosity with respect to monomodal systems. Despite important progress in theoretical work, not much has been done to quantitatively predict the low shear viscosity of aqueous polymer dispersions as a function of the complex PSD. In this work, the capability of a low‐shear‐viscosity equation to quantitatively account for the influence of both the PSD and the physicochemical characteristics of the dispersions is experimentally assessed. An analysis, consistent with theoretical concepts, of the data with semiempirical correlations is proposed. Next, with values of the parameters of the viscosity equation obtained experimentally, the effect of a latex with a 70% solid content on the low shear viscosity is examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3936–3946, 2004 相似文献
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对经固溶处理的二种Al-Li合金(1.94wt.%Li和2.75wt.%Li)的时效过程进行了研究。结果表明:δ’的生长速率遵从Ostward粗化动力学。1.94wt.%Li合金δ’产生于时效过程中,而2.75wt.%Li合金的δ’产生于时效的前期阶段。前者的表现体积分数明显大于根据相图估算的数伍,真实体积分数则与此值接近;后者的体积分数低于根据相图估算的数值,这可能归咎于δ’固相线的位置、统计学误差及Li更易在时效过程中贫化。 相似文献