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1.
Dr. Kyung-Seok Kang Dr. Krishnan A. Iyer Prof. Dr. Jeffrey Pyun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(35):e202200115
In this concept review, the fundamental and polymerization chemistry of inverse vulcanization for the preparation of statistical and segmented sulfur copolymers, which have been actively developed and advanced in various applications over the past decade is discussed. This concept review delves into a discussion of step-growth polymerization constructs to describe the inverse vulcanization process and discuss prepolymer approaches for the synthesis of segmented sulfur polyurethanes. Furthermore, this concept review discusses the advantages of inverse vulcanization in conjunction with dynamic covalent polymerization and post-polymerization modifications to prepare segmented block copolymers with enhanced thermomechanical and flame retardant properties of these materials. 相似文献
2.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
3.
Selvaraj Vishnuprasad Morri Bindusai Nair Lakshmi M. Krishnan Haribabu 《Journal of Thermal Analysis and Calorimetry》2019,137(5):1527-1536
Journal of Thermal Analysis and Calorimetry - Low thermal conductivity is a primary issue in the development of efficient heat transfer fluids and materials required for the thermal management of... 相似文献
4.
Uplink scheduling in wireless systems is gaining importance due to arising uplink intensive data services (ftp, image uploads
etc.), which could be hampered by the currently in-built asymmetry in favor of the downlink. In this work, we propose and
study algorithms for efficient uplink packet-data scheduling in a CDMA cell. The algorithms attempt to maximize system throughput
under transmit power limitations on the mobiles assuming instantaneous knowledge of user queues and channels. However no channel
statistics or traffic characterization is necessary. Apart from increasing throughput, the algorithms also improve fairness
of service among users, hence reducing chances of buffer overflows for poorly located users.
The major observation arising from our analysis is that it is advantageous on the uplink to schedule “strong” users one-at-a-time,
and “weak” users in larger groups. This contrasts with the downlink where one-at-a-time transmission for all users has shown
to be the preferred mode in much previous work. Based on the optimal schedules, we propose less complex and more practical
approximate methods, both of which offer significant performance improvement compared to one-at-a-time transmission, and the
widely acclaimed Proportional Fair (PF) algorithm, in simulations. When queue content cannot be fed back, we propose a simple modification of PF, Uplink PF (UPF), that offers similar improvement.
Hereafter, we refer to users with low recieved power at the base even when transmitting at peak transmit power as “weak” users,
and the strongly recieved users at the base as “strong” users.
Krishnan Kumaran is currently a member of the Complex Systems Modeling section in the Corporate Strategic Research of ExxonMobil Corp., Clinton,
NJ. Formerly, he was a Member of Technical Staff in the Mathematics of Networks and Systems Research Department at Bell Labs
in Murray Hill, NJ, where his research interests were in modeling, analysis and simulation of design, resource management
and scheduling issues in telecommunication networks.
Lijun Qian is an assistant professor in the Department of Electrical Engineering at Prairie View A&M University. He received his B.S.
from Tsinghua University in Beijing, M.S. from Technion-Israel Institute of Technology, and Ph.D. from WINLAB, Rutgers University,
all in electrical engineering. Before joining PVAMU, he was a researcher at Networks and Systems Research Department of Bell
Labs in Murray Hill, NJ. His major research interests are in wireless communications and networking technologies, especially
in radio resource management, protocol design, TCP/RLP optimization and MPLS traffic engineering. 相似文献
5.
We present all-atom molecular dynamics simulations ofn-hexane on the basal plane of graphite at monolayer and multilayer coverages. In keeping with experimental data, we find the
presence of ordered adsorbed layers both at single monolayer coverage and when the adsorbed layer coexists with excess liquid
adsorbate. Using a simulation method that does not impose any particular periodicity on the adsorbed layer, we quantitatively
compare our results to the results of neutron diffraction experiments and find a structural transition from a uniaxially incommensurate
lattice to a fully commensurate structure on increasing the coverage from a monolayer to a multilayer. The zig-zag backbone
planes of all the alkane molecules lie parallel to the graphite surface at the multilayer coverage, while a few molecules
are observed to attain the perpendicular orientation at monolayer coverage.
Dedicated to Professor C N R Rao on his 70th birthday 相似文献
6.
E. V. McCloskey A. Dey R. M. Parr N. Aras A. Balogh J. Bostock A. Borell S. Krishnan G. Lobo L. L. Qin Y. Zhang S. Cvijetic V. Zaichick M. Lim-Abraham K. Bose S. Wynchank G. V. Iyengar 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(2):341-345
In 1994, the International Atomic Energy Agency (IAEA) initiated a 5-year Co-ordinated Research Project (CRP) to determine
geographical and racial differences in peak bone mineral density (BMD) in men and women aged 15-49 years. The study demonstrates
that there are distinct global differences in BMD at the hip and spine in both men and women approximating to one population
standard deviation between populations with the highest and lowest BMD. These differences persist following adjustments for
age, sex and body size. Such information is valuable in understanding the reasons for global differences in fracture rate
and predicting future trends in fracture incidence.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
7.
P. Santhana Gopala Krishnan Chaobin He Christine Tay Shang Shang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):4036-4046
Two ladder‐like polysilsesquioxanes (LPS) containing side‐chain maleimide groups have been synthesized successfully by reacting N‐(4‐hydroxyphenyl)maleimide (HPM) with LPS containing 100 mol % of chloropropyl groups (Ladder A ) and 50 mol % of each methyl and chloropropyl group (Ladder B ). HPM was synthesized by reacting maleic anhydride with 4‐aminophenol, and the resulting amic acid was imidized using p‐toluenesulfonic acid as a catalyst (Scheme 1 ). The LPSs were characterized by Fourier transform infrared (FTIR), 1H nuclear magnetic resonance (NMR), proton‐decoupled 13C NMR, 29Si NMR, wide‐angle X‐ray diffraction (WAXD), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Characterization indicated that these polymers had ordered ladder‐like structures with possible defects. These polymers were soluble in common solvents at ambient temperature, which suggested that they were not crosslinked. Both the polymers and the HPM were cured, and their kinetics were followed by dynamic DSC. The Ozawa and Kissinger methods were used to calculate activation energies for curing. Curing increased the temperature at which both 5% weight loss and maximum rate of weight loss were observed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4036–4046, 2004 相似文献
8.
Beeranahally H Doreswamy Madegowda Mahendra Hirihally C Devarajegowda Venkatesh B Devaru Sridhar M Anandalwar Javaregowda S Prasad 《Analytical sciences》2004,20(2):407-408
The title compound was extracted from a natural product and its structure was characterized by an X-ray diffraction method. It crystallizes in the tetragonal space group P41 with cell parameters a = 15.832(10)A, c = 11.622(10)A, Z = 4; the final residual factor is R1 = 0.0769. The structure has both intra and intermolecular hydrogen bonds. 相似文献
9.
Additive-subtractive phase modulated speckle interferometry (ASPMSI) is a technique that minimizes the susceptibility of speckle methods to environmental noise while providing fringes of good visibility. The method requires the acquisition of two consecutive video frames of additive-speckle images of the same two deformed states of an object at a rapid enough rate such that ambient noise is not a problem. The additive-speckle images as expected are of very poor visibility due to the presence of the self-interference term. An interframe phase-modulation is introduced and the two additive-speckle images are digitally subtracted to improve the fringe visibility by removing the self-interference term. The ASPM-SI method works with in-plane and out-of-plane deformation sensitive ESPI as well as with displacement-gradient sensitive speckle-shearing interferometry. It is shown that the ASPM-SI scheme has higher visibility than conventional additive-SI and performs consistently better than subtractive-SI schemes in the presence of partial interframe speckle decorrelating optical noise. Furthermore, it is shown that the fringe visibility of the out-of-plane displacement sensitive interferometer which uses a protected reference beam separate from the object beam can be made to be essentially unity even at complete interframe decorrelation. 相似文献
10.
B. Sridhar H.R.D. Sunak B.R. Strauss S.P. Bastien 《Photonics Technology Letters, IEEE》1996,8(2):215-217
In this letter, we report an efficient single-mode Er/sup 3+/ doped fluoride fiber amplifier (EDFFA) in the 850 mn signal band. The Ti-sapphire laser was used to pump the EDFFA at 792 mm with an estimated absorbed pump power of 35 mW. The EDFFA used a 4.2 meter long NA=0.39, /spl lambda//sub c/=850 nm fluoride fiber as the active medium. A peak gain of 25 dB was observed at 852 mm. The gain was measured for a 10 nm region between 847.5 mn and 857.5 nm. The 3 dB gain bandwidth is less than 3 nm. However, the gain exceeded 20 dB over wavelength region of at least 7.5 nm. The gain and the gain bandwidth can be further increased by optimizing the length of the active fiber. 相似文献