Teaching the Chemistry of Platinum

Following colonisation of South America by the Spanish, many new naturally occurring substances were sent to Europe. One of these was the silvery, unreactive metal, platinum, discovered in New Grenada in the mid-eighteenth century. It was often found in granular form, associated with gold, and the challenge to chemists was to refine it, produce it as wire or sheet, and determine its chemical properties. This interested the professor of chemistry at the University of Edinburgh, Joseph Black, who was able to obtain samples from London-based Spanish contacts, particularly Ignacio Luzuriaga. This paper examines how Black transmitted his knowledge of the metal to large numbers of students attending his annual course.     

Physical aging in amorphous poly(ethylene furanoate): Enthalpic recovery,density, and oxygen transport considerations

The current work utilizes three separate techniques to study the physical aging process in amorphous poly(ethylene furanoate) (PEF), which is a recently introduced engineering thermoplastic with enhanced properties compared to petroleum‐sourced poly(ethylene terephthalate). Differential scanning calorimetry aging experiments were conducted at multiple aging temperatures and times, and the resultant enthalpic recovery values compared to the theoretical maximum enthalpy loss evaluated from calculations involving extrapolation of the equilibrium liquid line. Density measurements reveal densification of the matrix for the aged versus unaged samples, and provide an estimate for the reduction in free volume for the aged samples. Complementary oxygen permeation and pressure‐decay sorption experiments provide independent verification of the free volume reduction mechanism for physical aging in glassy polymers. The current work provides the first detailed aging study for PEF. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 389–399     

Et2Zn-mediated stoichiometric C(sp)-H silylation of 1-alkynes and chlorosilanes

A first example of an Et₂Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis.     

Capacity Efficiency and Restorability of Path Protection and Rerouting in WDM Networks Subject to Dual Failures

Resilient optical networks are predominately designed to protect against single failures of fiber links. But in larger networks, operators also see dual failures. As the capacity was planned for single failures, disconnections can occur by dual failures even if enough topological connectivity is provided. In our approach the design of the network minimizes the average loss caused by dual failures, while single failures are still fully survived. High dual failure restorability is the primary aim, capacity is optimized in a second step. For WDM networks with full wavelength conversion, we formulate mixed integer linear programming models for dedicated path protection, shared (backup) path protection, and path rerouting with and without stub-release. For larger problem instances in path rerouting, we propose two heuristics. Computational results indicate that the connectivity is of much more importance for high restorability values than the overall protection capacity. Shared protection has similar restorability levels as dedicated protection while the capacity is comparable to rerouting. Rerouting surpasses the protection mechanisms in restorability and comes close to 100% dual failure survivability. Compared to single failure planning, both shared path protection and rerouting need significantly more capacity in dual failure planning.     

Publication list

The helium atom in its ground state, subject to strong magnetic fields, is treated using a variational method. Trial functions consisting of Gaussians with nonlinear parameters variationally optimized are used. The form of these functions is a generalized s-symmetry-state properly modified to admit spatial deformation along the direction on which the magnetic field is applied. © 1994 John Wiley & Sons, Inc.