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排序方式: 共有126条查询结果,搜索用时 234 毫秒
1.
H Yurtseven I E Caglar 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(1):55-65
We calculate here the Brillouin frequencies of the L-mode [010], [001] and [100] of NaNO2 for the phase transitions from the paraelectric phase to the sinusoidal anti-ferroelectric phase near the Neel temperature (TN = 437.7 K) and to the ferroelectric phase near the critical temperature (TC = 436.3 K) in this crystalline system. For calculating the frequencies. we use the thermal expansivity data for the phase regions considered, under the assumption that the mode Gruneisen parameter determined for each mode remains constant across the phase transitions. Our calculated frequencies agree well with the observed frequencies for the modes studied in NaNO2. 相似文献
2.
The surface area of kaolinite-benzamide (K-Bz)6.62 m2 g–1, whichis noticeably lower than that of kaolinite-dimethyl sulphoxide (K-DMSO) 14.61m2 g–1, the co-perturbationof the inner-surface hydroxyl features at 3697 and 3650 cm–1,and the increase of d(001) value by 7.44 Å are all related to the benzamidespecies inserted into the kaolinite structure through the replacement of theK-DMSO composites. Disappearance of the DMSO reflections and emergence ofwell-defined features at 6.04(2θ) and 11.16(2θ), 001 and 002 reflectionswith d values of 14.62 and 7.92 Å, respectively point out that the DMSOspecies were substituted efficiently by benzamide molecules. The thermal stabilityof the K-Bz derivative up to 300°C can be attributed to the slightly tiltedaromatic ring keying into the gibbsitic sheets via the –NH2groups. 相似文献
3.
Ab initio calculations on the different associated structures of 2-pyrrolidinone with water and with itself were carried out using 3-21G and 6-31G* basis sets at the Hartree–Fock level, including electron correlation using second-order Møller–Plesset perturbation theory. The calculated free energy changes for the intermolecular hydrogen bonded dimer and hydrated species indicated that the molecular systems with cyclic dimerization and association with two water molecules are dominant. The results are compared to the available experimental data in the literature. 相似文献
4.
Anthracene Substituted Co (II) and Cu (II) phthalocyanines; Preparations,Investigation of Catalytical and Electrochemical Behaviors
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An approach to investigation of catalytical behaviors of Co (II) and Cu (II) phthalocyanines is reported that is based on changing any parameter to effect these behaviors. Towards this end, new anthracene substituted Co (II) and Cu (II) phthalocyanines were prepared and characterized spectroscopic methods. New cobalt (II) and copper (II) phthalocyanines were used as catalyst for oxidation of different phenolic compounds (such as 2,3‐dichlorophenol, 4‐methoxyphenol, 4‐nitrophenol, 2,3,6‐trimethylphenol) with different oxidants. Then, electrochemical characterization of cobalt (II) and copper (II) phthallocyanines were determined by using cyclic voltammetry (CV) and square wave voltammetry (SWV) techniques. Although copper (II) phthalocyanine showed similar Pc based electron transfer processes, cobalt (II) phthalocyanine showed metal and ligand based reduction reactions as expected. 相似文献
5.
Shashank Shekhar Hamzah Abdel-Aziz Michael Walker Faruk Caglar Aniruddha Gokhale Xenofon Koutsoukos 《电信纪事》2016,71(3-4):93-108
Many seemingly simple questions that individual users face in their daily lives may actually require substantial number of computing resources to identify the right answers. For example, a user may want to determine the right thermostat settings for different rooms of a house based on a tolerance range such that the energy consumption and costs can be maximally reduced while still offering comfortable temperatures in the house. Such answers can be determined through simulations. However, some simulation models as in this example are stochastic, which require the execution of a large number of simulation tasks and aggregation of results to ascertain if the outcomes lie within specified confidence intervals. Some other simulation models, such as the study of traffic conditions using simulations may need multiple instances to be executed for a number of different parameters. Cloud computing has opened up new avenues for individuals and organizations with limited resources to obtain answers to problems that hitherto required expensive and computationally-intensive resources. This paper presents SIMaaS, which is a cloud-based Simulation-as-a-Service to address these challenges. We demonstrate how lightweight solutions using Linux containers (e.g., Docker) are better suited to support such services instead of heavyweight hypervisor-based solutions, which are shown to incur substantial overhead in provisioning virtual machines on-demand. Empirical results validating our claims are presented in the context of two case studies. 相似文献
6.
At present, CNT supported catalysts were prepared by two different methods as NaBH4 reduction and dendrimer templated NaBH4 reduction method to observe the effect of preparation method on the sensitivity and activity of H2O2 reduction. Then, CNT supported PdxAuy bimetallic nanocatalysts having various atomic ratio were synthesized via novel dendrimer templated NaBH4 reduction method. The resulting materials were characterized employing XRD and TEM. Crystallite size of 10 %Pd0.7Au0.3/CNTdendrimer was obtained from XRD 17.1 nm and mean particle size obtained from TEM is about 15 nm. Moreover, the electrochemical behavior of these catalysts was characterized by cyclic voltammetry (CV) and chronoamperometry (CA) techniques. PdxAuy bimetallic nanocatalysts have excellent electrocatalytic properties and great potential for applications in electrochemical detection. The sensitivity and the limit of detection values for the prepared sensor with monometallic 10 % Pd/CNTdendrimer catalysts are 219.78 μA mM?1cm?2 and 2.6 μM, respectively. However, the sensor constructed with 10 %Pd0.7Au0.3/CNTdendrimer modified electrode has a very high sensitivity of 316.89 μA mM?1 cm?2 with a quick response time of 2 s and a wide linear range of 0.001–19.0 mM. In addition, the interference experiment indicated that the 10 % Pd0.7Au0.3/CNTdendrimer nanoparticles have good selectivity toward H2O2. 相似文献
7.
In this article we investigate the impacts of interspacing and source polling policies on the cell‐loss rates in transmission
of variable bit rate video sources over Asynchronous Transfer Mode networks. We present a mathematical model that finds the
approximate optimal starting times of the video sources that minimize the congestion at the multiplexer. Combined with the
approximate optimal source starting times, we propose a source ordering and polling policy for reducing the cell‐loss rates.
The proposed policy is tested against alternative policies using simulation of pre‐recorded video data.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
8.
Yasemin Caglar Saliha Ilican Mujdat Caglar Fahrettin Yakuphanoglu 《Journal of Sol-Gel Science and Technology》2010,53(2):372-377
Undoped and manganese doped ZnO (ZnO:Mn) films were prepared by sol gel method using spin coating technique. The effect of
Mn incorporation on the structural and optical properties of the ZnO film has been investigated. The crystalline structure
and orientation of the films have been investigated by using their X-ray diffraction spectra. The films exhibit a polycrystalline
structure. Mn incorporation led to substantial changes in the structural characteristics of the ZnO film. The scanning electron
microscopy (SEM) images of the films showed that the surface morphology of the ZnO film was affected by the Mn incorporation.
The transparency of the ZnO film decreased with the Mn incorporation. The optical band gap and Urbach energy values of the
ZnO and ZnO:Mn films were found to be 3.22, 3.19 eV and 0.10, 0.23 eV, respectively. The optical constants of these films,
such as refractive index, extinction coefficient and optical dielectric constants were determined using transmittance and
reflectance spectra. The refractive index dispersion curve of the films obeys the single oscillator model with dispersion
parameters. The oscillator energy, E
o
, and dispersion energy, E
d, of the films were determined 5.30 and 16.26 eV for ZnO film and 5.80 and 12.14 eV for ZnO:Mn film, respectively. 相似文献
9.
A fully integrated polydimethylsiloxane (PDMS)/modified PDMS membrane/SU-8/quartz hybrid chip was developed for protein separation using isoelectric focusing (IEF) mechanism coupled with whole-channel imaging detection (WCID) method. This microfluidic chip integrates three components into one single chip: (i) modified PDMS membranes for separating electrolytes in the reservoirs from the sample in the microchannel and thus reducing pressure disturbance, (ii) SU-8 optical slit to block UV light (below 300?nm) outside the channel aiming to increase detection sensitivity, and (iii) injection and discharge capillaries for continuous operation. Integration of all these components on a single chip is challenging because it requires fabrication techniques for perfect bonding between different materials and is prone to leakage and blockage. This study has addressed all the challenges and presented a fully integrated chip, which is more robust with higher sensitivity than the previously developed IEF chips. This chip was tested by performing protein and pI marker separation. The separation results obtained in this chip were compared with that obtained in commercial cartridges. Side-by-side comparison validated the developed chip and fabrication techniques. 相似文献
10.
The monitoring of the quality of service in digital television networks needs instruments to assess automatically the perceived quality of audio and video components of an MPEG2 signal. In order to improve the knowledge of the impact of the impairments on the final service, and to validate the algorithms that will be implemented in the quality evaluation instruments, a general simulation chain has been designed and developed. This paper presents the simulations performed as well as the analysis and the synthesis of the obtained results 相似文献