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排序方式: 共有141条查询结果,搜索用时 9 毫秒
1.
Palladium-containing zeolites catalyze the cycloisomerization of diethyl diallylmalonate to dimethylcyclopentenes. When the reaction is carried out in toluene, the performance of the palladium catalyst depends on the pore size of the zeolites. At 60 °C, palladium adsorbed on large pore size Beta zeolite (pore size ∼7.4 Å) is more active than medium pore size ZSM-5 (pore size ∼5.4 Å). This lower activity of ZSM-5 compared to Beta is attributable to the restricted diffusion of reagent and products through the ZSM-5 channels as compared to Beta zeolite. However, due to the gas-like diffusion characteristic of the supercritical state, the activity of ZSM-5 increases and becomes identical to that of Beta zeolite using supercritical CO2 as medium. 相似文献
2.
Spariosu K. Leyva V. Reeder R.A. Klotz M.J. 《Quantum Electronics, IEEE Journal of》2006,42(2):182-186
A 1534-nm fiber laser pumped Er:YAG laser action at room temperature has been demonstrated with high efficiency at two emission wavelengths: 1645 and 1617 nm. Multiwatt continuous-wave power was demonstrated at both wavelengths and active electrooptic Q-switch operation with >90% Q-switch efficiency was achieved at 1645 nm. Etalon tuned wavelength selection showed excellent agreement with theoretical analysis. 相似文献
3.
J. A. Munoz Leyva M. Callejón Mochón N. Moreno Diaz A. Sánchez Misiego 《Mikrochimica acta》1984,84(3-4):295-302
Summary Dimedone bisthiosemicarbazone monohydrochloride has been examined to evaluate its usefulness as a reagent for rapid and sensitive Spectrophotometric determination of chlorate (0.5–5.0 ppm) by oxidation of the reagent in 70% perchloric acid medium and measurement of the yellow product. The molar absorptivity at 417 nm is 1.86×104 l·mole–1·cm–1. The relative standard deviation is 1.6% for 2.5 ppm of chlorate.
Spektropbotometrische Bestimmung von Chlorat mit Dimedonbisthiosemicarbazon-monocblorhydrat (I)
Zusammenfassung Die Verwendbarkeit von I als Reagens für die rasche und empfindliche spektrophotometrische Bestimmung von 0,5–5,0 ppm Chlorat durch Oxydation von I in 70%iger Perchlorsäure und Messung des gelben Reaktionsproduktes wurde untersucht. Die molare Absorptivität bei 417 nm beträgt 1,86×104 l·mol–1·cm–1. Die relative Standardabweichung beträgt 1,6% für 2,5 ppm Chlorat.相似文献
4.
Jose R. Cabrero‐Antonino Dr. Antonio Leyva‐Pérez Prof. Dr. Avelino Corma 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(35):11107-11114
The triflimide iron(III) salt [Fe(NTf2)3] promotes the direct hydration of terminal and internal alkynes with very good Markovnikov regioselectivities and high yields. The enhanced carbophilic Lewis acidity of the FeIII cation mediated by the weakly‐coordinating triflimide anion is crucial for the catalytic activity. The iron(III) metal salt can be recycled in the form of the OPPh3/[Fe(NTf2)3] system with similar activity and selectivity. However, spectroscopic and kinetic studies show that [Fe(NTf2)3] hydrolyzes under the reaction conditions and that catalytically less active Brønsted species are formed, which points to a Lewis/Brønsted co‐catalysis. This triflimide‐based catalytic system is regioselective for the hydration of internal aryl‐alkynes and opens the door to a new synthetic route to alkyl ketophenones. As a proof of concept, the synthesis of two antipsychotics Haloperidol and Melperone, with general butyrophenone‐like structure, is shown. 相似文献
5.
Multisite Organic–Inorganic Hybrid Catalysts for the Direct Sustainable Synthesis of GABAergic Drugs 下载免费PDF全文
Dr. Antonio Leyva‐Pérez Dr. Pilar García‐García Prof. Dr. Avelino Corma 《Angewandte Chemie (International ed. in English)》2014,53(33):8687-8690
Multisite organic–inorganic hybrid catalysts have been prepared and applied in a new general, practical, and sustainable synthetic procedure toward industrially relevant GABA derivatives. The domino sequence is composed of seven chemical transformations which are performed in two one‐pot reactions. The method produces both enantiomeric forms of the product in high enantiopurity as well as the racemate in good yields after a single column purification step. This protocol highlights major process intensification, catalyst recyclability, and low waste generation. 相似文献
6.
Marji Baumann Phill Celaya 《今日电子》2006,(10):46-46
随着欧洲的RoHS和WEEE指令已于2006年7月1日开始执行,许多元件供应商面临着使其产品符合无铅环境的挑战。两个指令都要解决将铅从元件中去除的问题。半导体公司必须选择高性价比、与含铅焊料逆向兼容,并与无铅焊料前向兼容的无铅镀层策略。逆向兼容表示无铅元件能够用锡铅(SnPb)焊料回流工艺安放在PCB上。前向兼容表示目前的锡铅工艺能够在面板组装中,与无铅焊料一起使用。 相似文献
7.
Luis D. Vargas Gustavo A. Chapela Orlando Guzmán Pedro Díaz Leyva Rodrigo Sánchez 《Molecular physics》2020,118(9-10)
We analyse by discrete molecular dynamics the self-assembly of SW trimer particles that contain a different number of attractive and repulsive spheres. They also have different geometries: linear, obtuse, rectangular and equilateral. We identify that some of these molecules exhibit liquid–vapour equilibria while others do not. For all of them, we show the morphological phase diagram built up from the different supra-molecular structures formed by each type of trimer. We simulated 14 different systems with a total of 321 states. The main features of the supra-molecular structures depend only on the composition and geometry of the trimer: triple SW trimers do not form supra-structures, double SW trimers and single SW trimers form monolayers, bilayers and worm-like micelles. The liquid–vapour coexistence properties are also exhibited. These trimers can be used to model complex amphiphiles beyond the standard ones, such as the Gemini and the Bola surfactants as well as colloidal particles. 相似文献
8.
虽然单绕线双极步进电机比较贵,但它们能在额定物理尺寸下提供很强的转矩.但是.进步电机两个绕组的每一个都需要8个驱动晶体管,并在H桥路结构中连接成4个一组.每个晶体管都必须承受过载和短路状况并迅速从中恢复,因此驱动器必须包含复杂庞大的分立元件保护电路. 相似文献
9.
Im Deok Jung Min Kook Cho Kong Myeong Bae Sang Min Lee Phill Gu Jung Ho Kyung Kim Sung Sik Kim Jong Soo Ko 《ETRI Journal》2008,30(5):747-749
We introduce a pixel‐structured scintillator realized on a flexible polymeric substrate and demonstrate its feasibility as an X‐ray converter when it is coupled to photosensitive elements. The sample was prepared by filling Gd2O2S:Tb scintillation material into a square‐pore‐shape cavity array fabricated with polyethylene. For comparison, a sample with the conventional continuous geometry was also prepared. Although the pixelated geometry showed X‐ray sensitivity of about 58% compared with the conventional geometry, the resolving power was improved by about 70% above a spatial frequency of 3 mm?1. The spatial frequency at 10% of the modulation‐transfer function was about 6 mm?1. 相似文献
10.